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    ์ถ•๊ตฌ์ธ์žฌ์œก์„ฑํ™˜๊ฒฝ์ด ์œ ์†Œ๋…„์ถ•๊ตฌ์„ ์ˆ˜๋“ค์˜ ์ถ•๊ตฌ๋งŒ์กฑ๋„์— ๋ฏธ์น˜๋Š” ์˜ํ–ฅ: ์ค‘ํ•™๊ต ์ถ•๊ตฌ์„ ์ˆ˜๋“ค์„ ์ค‘์‹ฌ์œผ๋กœ

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    ํ•™์œ„๋…ผ๋ฌธ (์„์‚ฌ)-- ์„œ์šธ๋Œ€ํ•™๊ต ๋Œ€ํ•™์› : ์‚ฌ๋ฒ”๋Œ€ํ•™ ์ฒด์œก๊ต์œก๊ณผ,๊ธ€๋กœ๋ฒŒ์Šคํฌ์ธ ๋งค๋‹ˆ์ง€๋จผํŠธ์ „๊ณต, 2019. 2. ๊ฐ•์ค€ํ˜ธ.In todays talent development in soccer industry is one of the most crucial responsibilities for its industrys growth and strengthening their youth soccer players performance for future competitions as their core investment. The environment of talent development supports youth soccer players to perform better and think more creative during competitions by learning from their coaches and continuous training. Since youth soccer players mentality affects their performance in playing soccer, there are lack of studies in South Korea regarding youth soccer players satisfaction in talent development environment. This study is based on youth soccer players satisfaction for playing soccer in South Korea, an attempt to provide insight how much the players satisfy with current environment and the relationship with their coaches. The study looked youth soccer players satisfaction in South Korean talent development environment by applying seven environmental factors: Long-Term Development Focus, Quality Preparation, Communication, Understanding the Athlete, Support Network, Challenge and Supportive Environment, and Long-Term Development Fundamentals. More specifically, this study looked to identify the influence of the environmental factors towards the satisfaction of playing soccer in South Korea. The difference of satisfaction towards the talent development environment in each grade of middle school soccer players was also compared through this study. Results showed that the players overall satisfaction in playing soccer increases as they satisfy their 5 environmental factors of talent development which are Long-Term Development Focus, Communication, Support Network, Challenging and Supportive Environment, and Long-Term Development Fundamentals. Finally, there were significant difference of satisfaction towards the talent development environment between grade 1, grade 2, and grade 3 in South Korea.Abstract โ…ฐ Table of Contents iii List of Tables โ…ด Chapter 1. Introduction 1 1.1. Research Background 1 1.2. Purpose of Research 3 1.3. Significance of Research 5 1.4. Definition of Terms 8 Chapter 2. Theoretical Background 10 2.1. Theory of Deliberate Practice and Talent Development Environment Questionnaire (TDEQ) 11 2.2. Self-Determination Theory 14 2.3. Attachment Theory 16 2.4. Hypotheses 21 Chapter 3. Methodology 23 3.1. Participants 23 3.2. Procedure 24 3.3. Instruments 25 Chapter 4. Results 31 4.1. Descriptive Statistics 31 4.2. Hypotheses Testing 33 4.3. Summary of Findings 53 Chapter 5. Discussions and Conclusion 62 5.1. Theoretical Implications 62 5.2. Managerial Implications 65 5.3. Limitations and Future Research 67 5.4. Conclusion 68 References 71 Appendix 78 List of Tables Table 1. Descriptive Statistics 23 Table 2. Assessing the Reliability of Scales, Cronbachs ฮฑ 32 Table 3. The Results of Regression between Youth Soccer Players Satisfaction and Each Factor of Talent Development Environment 38 Table 3.1. The Results of Regression between the First Grade Youth Soccer Players Satisfaction and Each Factor of Talent Development Environment 39 Table 3.2. The Results of Regression between the Second Grade Youth Soccer Players Satisfaction and Each Factor of Talent Development Environment 40 Table 3.3. The Results of Regression between the Third Grade Youth Soccer Players Satisfaction and Each Factor of Talent Development Environment 41 Table 4. The Results of Shapiro-Wilks Test of Normality 42 Table 5. Levenes Test for Equality of Variance 44 Table 6. Brown-Forsythe Robust Tests of Equality of Means 45 Table 7. The Results of ANOVA for Youth Soccer Players Satisfaction 50 Table 8. The Results of Post Hoc Tests - Tukey 51 Table 9. The Summary of Regression for All Youth Soccer Players Satisfaction 53 Table 10. The Summary of ANOVA for All Youth Soccer Players Satisfaction 60Maste

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    Multifunctional Nanomaterials for Biomedical Nanomotor

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    Doctor์ž๊ฐ€์ถ”์ง„์„ ํ•  ์ˆ˜ ์žˆ๋Š” ๋งˆ์ดํฌ๋กœ/๋‚˜๋…ธ ์ž…์ž ์ฆ‰, ๋งˆ์ดํฌ๋กœ/๋‚˜๋…ธ๋ชจํ„ฐ ์‹œ์Šคํ…œ์€ ๋‹ค์–‘ํ•œ ์†Œ์Šค์˜ ์—๋„ˆ์ง€ (๋น›, ์—ด, ์ดˆ์ŒํŒŒ, ์ž๊ธฐ์žฅ, ํ™”ํ•™์  ์—๋„ˆ์ง€)๋ฅผ ๋ชจํ„ฐ์˜ ์›€์ง์ž„์œผ๋กœ ๋ณ€ํ™˜ํ•˜์—ฌ ๋งˆ์ดํฌ๋กœ/๋‚˜๋…ธ ์Šค์ผ€์ผ์—์„œ ๊ณผ์—…์„ ์ˆ˜ํ–‰ํ•  ์ˆ˜ ์žˆ๋Š” ์‹œ์Šคํ…œ ์ž…๋‹ˆ๋‹ค. ์ง€๋‚œ ์‹ญ ๋…„๊ฐ„ ๋งˆ์ดํฌ๋กœ/๋‚˜๋…ธ๋ชจํ„ฐ๋Š” ๋ชจํ„ฐ์˜ ํ•ฉ์„ฑ, ๋””์ž์ธ ์—์„œ๋ถ€ํ„ฐ, ๋งŒ๋“ค์–ด์ง„ ๋ชจํ„ฐ์˜ ์ ์šฉ์— ์ด๋ฅด๊ธฐ๊นŒ์ง€ ๊ด‘๋ฒ”์œ„ํ•˜๊ฒŒ ์—ฐ๊ตฌ๊ฐ€ ์ง„ํ–‰๋˜์—ˆ์Šต๋‹ˆ๋‹ค. ํŠนํžˆ, ๋ฐ˜๋“œ์‹œ ์†Œํ˜•ํ™”๊ฐ€ ํ•„์š”ํ•œ ์ƒ์ฒด์˜ํ•™์  ์ ์šฉ์„ ์œ„ํ•ด ํ™œ๋ฐœํ•œ ์—ฐ๊ตฌ๊ฐ€ ์ง„ํ–‰๋˜๊ณ  ์žˆ์Šต๋‹ˆ๋‹ค. ๋งˆ์ดํฌ๋กœ/๋‚˜๋…ธ๋ชจํ„ฐ๋Š” ์ถ”์ง„์„ ํ†ตํ•ด ์„ผ์„œ์™€ ํ”ผ๋ถ„์„๋ฌผ๊ณผ์˜ ์ ‘์ด‰๊ธฐํšŒ๋ฅผ ๋Š˜๋ ค ๋ฏผ๊ฐ๋„๋ฅผ ๋น„์•ฝ์ ์œผ๋กœ ๋Š˜๋ฆด ์ˆ˜ ์žˆ๊ณ  (์Šคํ„ฐ๋ง ํšจ๊ณผ), ์ถ”์ง„๋ ฅ์„ ํ†ตํ•ด ๊ธฐ์กด ์ž…์ž๋“ค์ด ์นจํˆฌํ•˜๊ธฐ ์–ด๋ ค์šด ์ƒ์ฒด๋ง‰ (์„ธํฌ๋ง‰, ํ˜ˆ๊ด€๋ฒฝ) ์ด๋‚˜ ๊นŠ์€ ์กฐ์ง๊นŒ์ง€ ๋„๋‹ฌํ•  ์ˆ˜ ์žˆ์–ด ์น˜๋ฃŒํšจ๋Šฅ๋„ ์ฆ๋Œ€์‹œํ‚ค๊ณ  ์žˆ์–ด ์•ฝ๋ฌผ์ „๋‹ฌ ์‹œ์Šคํ…œ, ๋ฐ”์ด์˜ค ์„ผ์„œ ๋“ฑ์— ์ ์šฉํ•œ ๋…ผ๋ฌธ๋“ค์ด ๋ฐœํ‘œ๋˜๊ณ  ์žˆ์Šต๋‹ˆ๋‹ค. ์ €๋Š” ๋ฐ•์‚ฌํ•™์œ„ ๋™์•ˆ ์ƒ์ฒด ์ ํ•ฉํ•œ ์†Œ์žฌ๋ฅผ ์ด์šฉํ•˜์—ฌ ๋งˆ์ดํฌ๋กœ/๋‚˜๋…ธ๋ชจํ„ฐ๋ฅผ ํ•ฉ์„ฑ, ๋””์ž์ธ ํ•˜์˜€์œผ๋ฉฐ ์ƒ์ฒด์— ์ ์šฉํ•˜๊ธฐ ์œ„ํ•œ ์—ฐ๊ตฌ๋ฅผ ์ง„ํ–‰ํ•˜์˜€์Šต๋‹ˆ๋‹ค. ๋จผ์ €, ๋‚˜๋…ธ๋ชจํ„ฐ์˜ ํ™”ํ•™์ฃผ์„ฑ์„ ์ด์šฉํ•˜์—ฌ ์•”์„ธํฌ๋กœ ํƒ€๊ฒŸํŒ…ํ•˜๊ณ  ๋น›์„ ์ด์šฉํ•ด ๋‚˜๋…ธ๋ชจํ„ฐ์˜ ์›€์ง์ž„์„ ์ œ์–ดํ•˜๊ณ  ๋˜ํ•œ, ๊ด‘์—ดํšจ๊ณผ๋กœ ์•”์„ธํฌ๋ฅผ ์ฃฝ์ด๋Š” ์—ฐ๊ตฌ๋ฅผ ํ•˜์˜€์Šต๋‹ˆ๋‹ค. ์ถ”์ง„์ฒด๋ฅผ ๋งŒ๋“ค๊ธฐ ์œ„ํ•ด ํด๋ฆฌ์Šคํƒ€์ด๋ Œ-ํด๋ฆฌ์—ํ‹ธ๋ Œ๊ธ€๋ผ์ด์ฝœ ๋ธ”๋ก๊ณต์ค‘ํ•ฉ์ฒด๋ฅผ ์œ ๊ธฐ์šฉ๋งค์— ๋…น์ธ ํ›„ ๋ฌผ์„ ์ฒจ๊ฐ€ํ•จ์œผ๋กœ์จ ์‚ผํˆฌ์••์— ์˜ํ•ด ํ•ญ์•„๋ฆฌ ํ˜•ํƒœ (์Šคํ† ๋งˆํ† ์‚ฌ์ดํŠธ)์˜ ๋ชธ์ฒด๋ฅผ ๋งŒ๋“  ํ›„ ๋ชธ์ฒด ์•ˆ์— ๋ฐฑ๊ธˆ ๋‚˜๋…ธ์ž…์ž๋ฅผ ๋‹ด์ง€ ํ•˜์˜€์Šต๋‹ˆ๋‹ค. ์ด ๋‚˜๋…ธ๋ชจํ„ฐ๋Š” ๊ณผ์‚ฐํ™”์ˆ˜์†Œ๊ฐ€ ์žˆ๋Š” ํ™˜๊ฒฝ์—์„œ ๋ฐฑ๊ธˆ ๋‚˜๋…ธ์ž…์ž์™€ ๊ณผ์‚ฐํ™”์ˆ˜์†Œ์˜ ํญ๋ฐœ์ ์ธ ๋ฐ˜์‘์— ์˜ํ•ด ์‚ฐ์†Œ๊ฐ€ ๋ฐœ์ƒ๋˜๊ณ , ๋ฐœ์ƒ๋œ ์‚ฐ์†Œ๊ฐ€ ํ•ญ์•„๋ฆฌ ํ˜•ํƒœ์˜ ์ž…๊ตฌ๋ฅผ ๋น ์ ธ๋‚˜์˜ค๋ฉด์„œ ์›€์ง์ด๊ฒŒ ๋ฉ๋‹ˆ๋‹ค. ์•”์„ธํฌ๊ฐ€ ๊ณผ์‚ฐํ™”์ˆ˜์†Œ๋ฅผ ๋‚ด๋Š” ์„ฑ์งˆ์„ ์ด์šฉํ•˜์—ฌ ๋‚˜๋…ธ๋ชจํ„ฐ๊ฐ€ ์•”์„ธํฌ๋กœ ๋Œ๋ฆฌ๋Š” ํ™”ํ•™์ฃผ์„ฑ์„ ํ™•์ธํ•˜์˜€์Šต๋‹ˆ๋‹ค. ๋˜ํ•œ, ์•”์„ธํฌ๋กœ ์ด๋™ํ•œ ๋‚˜๋…ธ๋ชจํ„ฐ์— ๊ทผ์ ์™ธ์„ ์„ ์ฌ์–ด์ฃผ์—ˆ์„ ๋•Œ ๋‚˜๋…ธ๋ชจํ„ฐ๋“ค์ด ์‘์ง‘๋˜๊ณ  ๋ฉˆ์ถฐ์„œ ๊ด‘์—ดํšจ๊ณผ๋ฅผ ๋‚˜ํƒ€๋‚ด๋Š” ๊ฒƒ์„ ํ™•์ธํ•˜์˜€์Šต๋‹ˆ๋‹ค. ์ด ์—ฐ๊ตฌ๋ฅผ ํ†ตํ•ด ์•” ์น˜๋ฃŒ์— ์žˆ์–ด ๋‚˜๋…ธ๋ชจํ„ฐ์˜ ์šฐ์ˆ˜์„ฑ์„ ์ž…์ฆํ•˜๊ณ  ์‘์šฉ ๊ฐ€๋Šฅ์„ฑ์„ ๊ฒ€์ฆํ•˜์˜€์Šต๋‹ˆ๋‹ค. ๋‘๋ฒˆ์งธ ์—ฐ๊ตฌ๋Š” ๋‚˜๋…ธ๋ชจํ„ฐ๋ฅผ ์ด์šฉํ•˜์—ฌ ์•ฝ๋ฌผ์ „๋‹ฌ์‹œ์Šคํ…œ์— ์ ์šฉํ•˜๊ณ ์ž ํ•˜์˜€์Šต๋‹ˆ๋‹ค. ์•ž์„œ ์„ค๋ช…ํ–ˆ๋“ฏ์ด ๋งˆ์ดํฌ๋กœ/๋‚˜๋…ธ๋ชจํ„ฐ๋Š” ๊ธฐ์กด์˜ ์•ฝ๋ฌผ์ „๋‹ฌ์‹œ์Šคํ…œ์— ๋น„ํ•ด ์ƒ์ฒด๋ง‰์ด๋‚˜ ๊นŠ์€ ์กฐ์ง์œผ๋กœ ๋„๋‹ฌํ•  ์ˆ˜ ์žˆ๋Š” ์ถ”์ง„๋ ฅ์„ ๊ฐ€์ง€๊ณ  ์žˆ์–ด ์•ฝ๋ฌผ์ „๋‹ฌ ํšจ์œจ์„ ๊ทน๋Œ€ํ™” ์‹œํ‚ฌ ์ˆ˜ ์žˆ์Šต๋‹ˆ๋‹ค. ํ•˜์ง€๋งŒ ๊ทธ๋Ÿฌํ•œ ์ถ”์ง„๋ ฅ์„ ๊ฐ€์ง€๊ณ  ์žˆ์Œ์—๋„ ๋ถˆ๊ตฌํ•˜๊ณ  ์„ธํฌ ๋‚ด๋กœ ์œ ์ž…๋˜๊ธฐ์—” ๋‹ค์†Œ ํฐ ํฌ๊ธฐ์™€ ์•”์„ธํฌ๋ฅผ ํƒ€๊ฒŸํŒ… ํ•  ์ˆ˜ ์žˆ๋Š” ๋ถ€๋ถ„์ด ์—†์–ด ์„ธํฌ ๋‚ด ์•ฝ๋ฌผ์ „๋‹ฌ ํšจ์œจ์ด ์—ฌ์ „ํžˆ ์ข‹์ง€ ๋ชปํ•ฉ๋‹ˆ๋‹ค. ํƒ„์‚ฐ์นผ์Š˜ ์ž…์ž ์•ˆ์— ํžˆ์•Œ๋ฃจ๋ก ์‚ฐ-์ฟ ์ปค๋น„ํŠธ๋ฆด ์ ‘ํ•ฉ์ฒด๋ฅผ ๋‹ด์ง€ ํ•œ ํ›„ ๋ณตํ•ฉ์ฒด๋ฅผ ๋งŒ๋“ค์—ˆ์Šต๋‹ˆ๋‹ค. ๊ทธ ํ›„, ์ž…์ž์˜ ํ•œ์ชฝ ๋ฉด์— ๋ฐฑ๊ธˆ์„ ์ฝ”ํŒ…ํ•˜์—ฌ ๋‚˜๋…ธ๋ชจํ„ฐ๋ฅผ ๋งŒ๋“ค์—ˆ์Šต๋‹ˆ๋‹ค. ์ด ๋ชจํ„ฐ๋Š” ๊ณผ์‚ฐํ™”์ˆ˜์†Œ ํ™˜๊ฒฝ์—์„œ ๋ฐฑ๊ธˆ์ฝ”ํŒ…์— ์˜ํ•ด ์ถ”์ง„ํ•˜๊ฒŒ ๋˜๊ณ  ์•” ์กฐ์ง์— ๋„๋‹ฌํ•˜๊ฒŒ๋ฉ๋‹ˆ๋‹ค. ์ด๋•Œ ๋ชจํ„ฐ๋ฅผ ์ด๋ฃจ๊ณ  ์žˆ๋Š” ํƒ„์‚ฐ์นผ์Š˜์€ ์•” ์กฐ์ง ํ™˜๊ฒฝ (๋‚ฎ์€ pH)์— ๋ถ„ํ•ด๋˜๊ณ  ๋‹ด์ง€ ๋˜์–ด์žˆ๋˜ ํžˆ์•Œ๋ฃจ๋ก ์‚ฐ-์ฟ ์ปค๋น„ํŠธ๋ฆด ์ ‘ํ•ฉ์ฒด๊ฐ€ ๋‚˜์˜ค๊ฒŒ ๋ฉ๋‹ˆ๋‹ค. ์•” ์„ธํฌ๋Š” ํžˆ์•Œ๋ฃจ๋ก ์‚ฐ ์ˆ˜์šฉ์ฒด (CD 44)๊ฐ€ ์„ธํฌํ‘œ๋ฉด์— ๋งŽ๊ธฐ ๋•Œ๋ฌธ์— ํžˆ์•Œ๋ฃจ๋ก ์‚ฐ๊ณผ ํŠน์ด์ ์œผ๋กœ ๊ฒฐํ•ฉํ•˜๊ณ  ์„ธํฌ์œ ์ž…์ด ๋ฉ๋‹ˆ๋‹ค. ์ด๋•Œ, ์ฟ ์ปค๋น„ํŠธ๋ฆด์ด๋ผ๋Š” ์ดˆ๋ถ„์ž๋Š” ๋””์•„๋ฏธ๋…ธํ—ฅ์‚ฐ ๋ถ„์ž์™€ ํฐ ๊ฒฐํ•ฉ๋ ฅ์„ ๊ฐ€์ง€๊ณ  ๊ฒฐํ•ฉํ•˜๋Š” ์„ฑ์งˆ์„ ๊ฐ€์ง€๋Š”๋ฐ ๋ชจ๋ธ์•ฝ๋ฌผ์— ์ด ๋ถ„์ž๋ฅผ ๊ฒฐํ•ฉํ•˜์—ฌ ๋ชจ๋ธ์•ฝ๋ฌผ์ด ์•” ์„ธํฌ ๋‚ด๋กœ ์œ ์ž…๋˜๊ธฐ ์ „์— ์ƒˆ๋Š” ๋น„์œจ์„ ์ตœ์†Œํ™” ํ•˜์˜€์Šต๋‹ˆ๋‹ค. ๋‚˜๋…ธ๋ชจํ„ฐ๊ฐ€ ์•” ์„ธํฌ์ฃผ๋ณ€์—์„œ ๋ถ„ํ•ด๋จ์„ ํ™•์ธํ•˜์˜€๊ณ  ๋‹ด์ง€ ๋˜์–ด ์žˆ๋˜ ํžˆ์•Œ๋ฃจ๋ก ์‚ฐ-์ฟ ์ปค๋น„ํŠธ๋ฆด ์ ‘ํ•ฉ์ฒด๊ฐ€ ์„ธํฌ ๋‚ด๋กœ ์œ ์ž…๋˜๋Š” ๊ฒƒ์„ ํ™•์ธํ•˜์˜€์Šต๋‹ˆ๋‹ค. ๋˜ํ•œ, ๊ธฐ์กด์˜ ๋งˆ์ดํฌ๋กœ/๋‚˜๋…ธ๋ชจํ„ฐ์— ๋น„ํ•ด ์„ธํฌ ๋‚ด ์•ฝ๋ฌผ์ „๋‹ฌ ํšจ์œจ์ด ์ฆ๋Œ€๋จ์„ ํ™•์ธ ํ•˜์˜€์Šต๋‹ˆ๋‹ค. ์„ธ๋ฒˆ์งธ ์—ฐ๊ตฌ๋Š” ์•ž์„œ ํ–ˆ๋˜ ์„ ํ–‰ ์—ฐ๊ตฌ๋ฅผ ๋ฐ”ํƒ•์œผ๋กœ ์ข€๋” ์ƒ์ฒด ์ ํ•ฉํ•œ ๋‚˜๋…ธ๋ชจํ„ฐ๋ฅผ ์ œ์ž‘ํ•˜๊ณ  ์ด๋ฅผ ์‹ค์ œ ๋™๋ฌผ ์‹คํ—˜์„ ํ†ตํ•ด ์ž…์ฆํ•˜์˜€์Šต๋‹ˆ๋‹ค. ๊ธฐ์กด์˜ ๋ฐฉ๊ด‘์•”, ๋ฐฉ๊ด‘์—ผ, ๋ฏผ๊ฐ„์„ฑ ๋ฐฉ๊ด‘์น˜๋ฃŒ์— ๋ฐฉ๊ด‘ ๋‚ด๋กœ ์นดํ…Œํ„ฐ๋ฅผ ์ด์šฉํ•˜์—ฌ ์•ฝ๋ฌผ์„ ์ฃผ์ž…ํ•˜๊ฒŒ ๋˜๋Š”๋ฐ ์ด๋Ÿฌํ•œ ์•ฝ๋ฌผ์€ ๋ฐฉ๊ด‘๋ฒฝ์— ์ž˜ ๋ถ™์ง€ ๋ชปํ•˜๊ณ  ๋นˆ๋ฒˆํ•œ ๋ฐฐ๋‡จ์ž‘์šฉ์— ์˜ํ•ด ์”ป๊ฒจ ๋‚ด๋ ค๊ฐ€ ์•ฝํšจ๊ฐ€ ๋–จ์–ด์ง‘๋‹ˆ๋‹ค. ์ด๋Ÿฌํ•œ ๋ฌธ์ œ์ ์„ ๋‚˜๋…ธ๋ชจํ„ฐ๋ฅผ ์ด์šฉํ•˜์—ฌ ํ•ด๊ฒฐํ•˜๊ณ ์ž ํ•˜์˜€์Šต๋‹ˆ๋‹ค. ์ƒ์ฒด์ ํ•ฉํ•œ ๊ณ ๋ถ„์ž์ธ ํด๋ฆฌ๋„ํŒŒ๋ฏผ ๋‚˜๋…ธ์ž…์ž๋ฅผ ํ•ฉ์„ฑํ•˜์˜€๊ณ  ์ž…์ž ํ‘œ๋ฉด์— ์šฐ๋ ˆ์•„์ œ๋ผ๋Š” ์š”์†Œ๋ถ„ํ•ดํšจ์†Œ๋ฅผ ์ ‘ํ•ฉํ•˜์˜€์Šต๋‹ˆ๋‹ค. ์„ ํ–‰ ์—ฐ๊ตฌ์—์„œ ๋ฐฑ๊ธˆ๊ณผ ๊ฐ™์€ ๊ธˆ์†์ด ์ถ”์ง„ ๋ฉ”์ปค๋‹ˆ์ฆ˜์— ๊ด€์—ฌ๋˜๊ธฐ ๋•Œ๋ฌธ์— ์—ฌ์ „ํžˆ ์ƒ์ฒด ๋‚ด์— ์‚ฌ์šฉํ•˜๋Š”๋ฐ ์–ด๋ ค์›€์ด ์žˆ์—ˆ์Šต๋‹ˆ๋‹ค. ์ถ”์ง„๋ฉ”์ปค๋‹ˆ์ฆ˜์„ ๋ฐ”๊พธ๊ณ  ์ƒ์ฒด ์ ํ•ฉ์„ฑ์„ ๋†’์ด๊ธฐ ์œ„ํ•ด ์šฐ๋ ˆ์•„์ œ๋ฅผ ์‚ฌ์šฉํ•˜์˜€์Šต๋‹ˆ๋‹ค. ์šฐ๋ ˆ์•„์ œ๋Š” ์š”์†Œ ํ™˜๊ฒฝ์—์„œ ๋…์„ฑ์ด ์žˆ๋Š” ์š”์†Œ๋ฅผ ๋ถ„ํ•ดํ•˜์—ฌ ํƒ„์†Œ๋ฅผ ๋ฐœ์ƒ์‹œํ‚ค๊ฒŒ ๋˜๋Š”๋ฐ ๋ฐœ์ƒ๋œ ํƒ„์†Œ์— ์˜ํ•ด ๋‚˜๋…ธ๋ชจํ„ฐ๊ฐ€ ์ถ”์ง„๋ฉ๋‹ˆ๋‹ค. ํ•ฉ์„ฑ๋œ ๋‚˜๋…ธ๋ชจํ„ฐ๋ฅผ ๋ฐฉ๊ด‘ ๋‚ด๋กœ ์นดํ…Œํ„ฐ๋ฅผ ํ†ตํ•ด ์ฃผ์ž…ํ•˜๋ฉด ๋ฐฉ๊ด‘ ๋‚ด ๋†’์€ ์š”์†Œ๋†๋„์— ์˜ํ•ด ๋‚˜๋…ธ๋ชจํ„ฐ๊ฐ€ ์ถ”์ง„๋˜๊ฒŒ ๋˜๊ณ  ๋ฐฉ๊ด‘๋ฒฝ์˜ ์ ๋ง‰ ์ธต์„ ํšจ์œจ์ ์œผ๋กœ ํˆฌ๊ณผํ•จ์„ ํ™•์ธํ•˜์˜€์Šต๋‹ˆ๋‹ค. ๋˜ํ•œ, ๋ฐฉ๊ด‘๋ฒฝ ๋‚ด์— ๋ฐฐ๋‡จ์ž‘์šฉ ํ›„์—๋„ ๊ธฐ์กด ์ž…์ž๋“ค์— ๋น„ํ•ด ๋” ์˜ค๋ž˜๋„๋ก ๋งŽ์ด ์กด์žฌํ•˜๊ณ  ์žˆ์Œ์„ ํ™•์ธํ•˜์˜€์Šต๋‹ˆ๋‹ค. ํ˜„์žฌ๊นŒ์ง€ ๋‚˜๋…ธ๋ชจํ„ฐ๋ฅผ ๋™๋ฌผ ์‹คํ—˜์— ์ ์šฉํ•œ ์˜ˆ๊ฐ€ ๋งŽ์ง€ ์•Š์€๋ฐ ์ด ์—ฐ๊ตฌ๋ฅผ ํ†ตํ•ด ๋ฐฉ๊ด‘์งˆ๋ณ‘์น˜๋ฃŒ์— ์ƒˆ๋กœ์šด ๊ฐ€๋Šฅ์„ฑ์„ ์ œ์‹œํ•˜์˜€์Šต๋‹ˆ๋‹ค. ์ข…ํ•ฉํ•˜์—ฌ, ๋‹ค์–‘ํ•œ ๋ฉ”์ปค๋‹ˆ์ฆ˜, ๋ฌผ์งˆ์„ ์ด์šฉํ•˜์—ฌ ๋งˆ์ดํฌ๋กœ/๋‚˜๋…ธ๋ชจํ„ฐ๋ฅผ ํ•ฉ์„ฑํ•˜๊ณ  ์ด๋Ÿฌํ•œ ํ•ฉ์„ฑ๋ชจํ„ฐ๊ฐ€ ์ž„์ƒ์— ์ ์šฉ๋  ์ˆ˜ ์žˆ๋„๋ก ํ•˜์˜€์Šต๋‹ˆ๋‹ค. ์ฒซ์งธ, ๊ณ ๋ถ„์ž๋ฅผ ์ด์šฉํ•˜์—ฌ ๋‚˜๋…ธ๋ชจํ„ฐ๋ฅผ ํ•ฉ์„ฑํ•˜์˜€์Šต๋‹ˆ๋‹ค. ๊ทธ ๊ฒฐ๊ณผ, ์ƒ์ฒด ์ ํ•ฉํ•œ ๋‚˜๋…ธ๋ชจํ„ฐ๋ฅผ ์ œ์ž‘ํ• ์ˆ˜ ์žˆ์—ˆ์Šต๋‹ˆ๋‹ค. ๋˜ํ•œ, ๋‚˜๋…ธ๋ชจํ„ฐ๋ฅผ ์ด์šฉํ•˜์—ฌ ๊ด‘์—ด์น˜๋ฃŒ์— ์„ฑ๊ณต์ ์œผ๋กœ ์ ์šฉํ•  ์ˆ˜ ์žˆ์—ˆ์Šต๋‹ˆ๋‹ค. ๋‘˜์งธ, ์ƒ๋ถ„ํ•ด์„ฑ์˜ ๋‚˜๋…ธ๋ชจํ„ฐ๋ฅผ ์ œ์ž‘ํ•˜์—ฌ ์•ฝ๋ฌผ์‹œ์Šคํ…œ์— ์ ์šฉํ•˜์˜€์Šต๋‹ˆ๋‹ค. ๊ทธ ๊ฒฐ๊ณผ, ์•”์กฐ์ง์ฃผ๋ณ€์—์„œ ๋‚˜๋…ธ๋ชจํ„ฐ๊ฐ€ ์ƒ๋ถ„ํ•ด๋˜๊ณ  ์•ฝ์„ ์ „๋‹ฌํ•˜๋Š” ๊ฒƒ์„ ํ™•์ธํ•˜์˜€์Šต๋‹ˆ๋‹ค. ์…‹์งธ, ์ด๋Ÿฌํ•œ ์—ฐ๊ตฌ๋“ค์„ ๋ฐ”ํƒ•์œผ๋กœ ์ƒ์ฒด์ ํ•ฉํ•œ ๋ชจํ„ฐ๋ฅผ ์ œ์ž‘ํ•˜์˜€๊ณ  ๋ฐฉ๊ด‘์— ์ ์šฉํ•˜์—ฌ ๋ฐฉ๊ด‘ ์งˆํ™˜์„ ์น˜๋ฃŒํ• ์ˆ˜ ์žˆ๋Š” ๋ชจํ„ฐ ์‹œ์Šคํ…œ์„ ๊ฐœ๋ฐœํ•˜์˜€์Šต๋‹ˆ๋‹ค.Self-propelled micro/nanomotors (MNMs) convert various energy source (light, heat, ultrasound, magnet, chemical substrate) into mechanical force to conduct complex tasks at micro/nanoscale. Over the past dacades, MNMs have been widely studied for biomedical applications due to the need for miniaturization of machines and smart materials for complex and precise operations in the body. Since MNMs can actively transport drugs, penetrate deep tissues for drug delivery and improve sensitivity of analytes for sensing, MNMs were considered as new micro/nanoplatforms to biomedical field with maximization of therapeutic efficacy and minimization of side effect. During the Ph.D course, functional nanomotors were developed with different propelsion mechanisms for biomedical applications. In part I, light responsive nanomotor was developed for active photothermal cancer therapy. The nanomotor was synthesis with polyethylene-polystyrene block copolymer (PEG-b-PS) for bowl-shaped polymersome (stomatocyte). After that, platinum nanoparticles were entrapped selectively within the nanocavity of the stomatocyte for self-propulsion by the platinum-catalysed degradation of hydrogen peroxide. In addition, naphtalocyanine derivative (NC), a strong NIR light absorber, was also encapsulated in the membrane of stomatocyte. Under NIR light, conformational change of stomatocyte was occured due to the temperature increase of NC in the membrane of stomatocyte, resulting in reversible aggregation of the nanomotor around 55ยฐC. After that, the aggregated nanomotors stopped and showed photothermal effect. This nanomotor system was successfully utilized for for photothermal cancer therapy. In part II, degradable nanomotor was firstly developed for targeted drug delivery. To give biodegradability and biocompatibility of the nanomotor, calcium carbonate (CaCO3) nanoparticle and hyaluronates (HA) were used. The platinum deposited janus-type nanomotors showed an autonomous motion in the presence of hydrogen peroxide. After reaching tumor sites, CaCO3 of the nanomotor was degraded in the acidic tumor environment and drug loaded HA were released and uptaken into cancer cells. The delivery efficiency of the nanomotors was significantly increased due to the dual targeting capability: the pH-responsive degradation of CaCO3 in the acidic tumor environment and the cancer cell targeting capability of HA. This degradable nanomotor system might pave the way for active drug delivery. In part III, on the basis of preliminary research data, biocompatible and bioavailable enzyme-powered nanomotor was developed for in vivo application. The nanomotor can penetrate the bladder wall and show enhanced retention in bladder under in vivo condition. Urease was choosed for propulsion of nanomotor due to their bioavailability and urea, converted by urease into carbon dioxide, is present in considerable amount in the urinary bladder. Urease immobilized nanomotor become active in bladder by conversion of urea. After injection in bladder, the nanomotors showed enhnaced penetration to bladder wall and retention in bladder even after urination. This enzyme-powered nanomotor successfully utilized for the therapy of bladder diseases. Taken together, micro/nanomotors were synthesized and developed with different propulsion mechanisms and successfully applied for various biomedical applications. Firstly, polymeric nanomotor, which responsive to light was developed for active photothermal cancer therapy. Second, degradable nanomotor was firstly developed for targeted drug delivery. Third, bioavailable enzyme-powered nanomotor was developed for therapy of bladder disease. Based on those researches, I could confirm the possibility and feasibility of nanomotor systems for various functional biomedical applications

    A Reliability Study on MOSFETs with High-k dielectrics using Low-Frequency Noise Measurements

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    DoctorThis thesis describes the reliability study of MOSFETs with high-k dielectrics using low-frequency noise measurements. For La-incorporated high-k dielectrics, the oxide breakdown characteristics are verified using low-frequency noise measurements. For SiGe channel p-MOSFETs with high-k dielectrics, the oxide breakdown, the negative bias temperature instability (NBTI), and hot carrier instability (HCI) are observed using low-frequency noise and charge pumping measurements. The n-MOSFET with La-incorporated high-k dielectrics is measured before and after channel oxide breakdown. Low frequency noise (LFN) after channel soft oxide breakdown (SBD) of n-MOSFETs with a HfLaSiO gate dielectric and TaN metal gate shows a Lorentzian-like spectrum, which is not observed in HfSiO gate dielectric devices after channel SBD. This is related to the spatial location of the SBD spot. Because the La weakens atomic bonding in the interface layer, the SBD spot is generated close to the Si/SiO2 interface. This is verified using the time domain analysis. The reliability of SiGe channel p-MOSFETs with high-k dielectrics is studied. Si0.75Ge0.25 p-MOSFETs with HfSiO gate dielectrics show the higher breakdown voltage than the Si channel p-MOSFETs in TZDB measurements. At the first instant after TZDB, the increase of hole current is larger than the increase of electron current in Si0.75Ge0.25 p-MOSFETs, which is opposite to the Si channel p-MOSFETs. This supports that the breakdown in Si0.75Ge0.25 p-MOSFETs are occurred at interfacial layer (IL) and that in Si p-MOSFETs are occurred at bulk layer. These characteristics are also observed in BD measurements. Low-frequency noise (LFN) after BD of Si0.75Ge0.25 p-MOSFETs shows a small Lorentzian hump and that of Si p-MOSFETs shows an only increase for all measured frequency. This is evidence that the IL of Si0.75Ge0.25 p-MOSFETs is more fragile than that of Si p-MOSFETs because of the Ge induced trap generation.Finally, the NBTI and HCI of SiGe channel p-MOSFETs are studied. The short gate-length devices are more degraded by NBTI in respect of the threshold voltage shift (ฮ”Vth) than the long gate-length devices in Si0.75Ge0.25 channel p-MOSFETs. This supports that the short gate-length devices contain more fragile bond than the long gate-length devices do. Under channel hot carrier (CHC) stress, the drain currents are severely degraded and the kink effect in subthreshold region is observed in Si0.75Ge0.25 channel p-MOSFETs

    MEDUSA'97: An Active Multimedia System for the Tele-Education Environment

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    Maste

    A Comparative Study of Homeless Angel and Tower of Migaheri

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