Copper‐Catalyzed Enantio‐ and Diastereoselective Addition of Silicon Nucleophiles to 3,3‐Disubstituted Cyclopropenes

A highly stereocontrolled syn‐addition of silicon nucleophiles across cyclopropenes with two different geminal substituents at C3 is reported. Diastereomeric ratios are excellent throughout (d.r.≥98:2) and enantiomeric excesses usually higher than 90 %, even reaching 99 %. This copper‐catalyzed C−Si bond formation closes the gap of the direct synthesis of α‐chiral cyclopropylsilanes.TU Berlin, Open-Access-Mittel - 201

Pair production of 125 GeV Higgs boson in the SM extension with color-octet scalars at the LHC

Although the Higgs boson mass and single production rate have been determined more or less precisely, its other properties may deviate significantly from its predictions in the standard model (SM) due to the uncertainty of Higgs data. In this work we study the Higgs pair production at the LHC in the Manohar-Wise model, which extends the SM by one family of color-octet and isospin-doublet scalars. We first scanned over the parameter space of the Manohar-Wise model considering exprimental constraints and performed fits in the model to the latest Higgs data by using the ATLAS and CMS data separately. Then we calculated the Higgs pair production rate and investigated the potential of its discovery at the LHC14. We conclude that: (i) Under current constrains including Higgs data after Run I of the LHC, the cross section of Higgs pair production in the Manohar-Wise model can be enhanced up to even $10^3$ times prediction in the SM. (ii) Moreover, the sizable enhancement comes from the contributions of the CP-odd color-octet scalar $S^A_I$. For lighter scalar $S^A_I$ and larger values of $|\lambda_I|$, the cross section of Higgs pair production can be much larger. (iii) After running again of LHC at 14 TeV, most of the parameter spaces in the Manohar-Wise model can be test. For an integrated luminosity of 100 fb$^{-1}$ at the LHC14, when the normalized ratio $R=10$, the process of Higgs pair production can be detected.Comment: 13 pages, 4 figure

Explanation of the ATLAS Z-peaked excess by squark pair production in the NMSSM

The ATLAS collaboration recently reported a $3\sigma$ excess in the leptonic-$Z+jets+E_{T}^{miss}$ channel. We intend to interpret this excess by squark pair production in the Next-to-Minimal Supersymmetric Standard Model (NMSSM). The decay chain we employ is $\tilde{q} \to q \tilde{\chi}_2^0 \to q \tilde{\chi}_1^0 Z$, where $\tilde{\chi}_1^0$ and $\tilde{\chi}_2^0$ denote the lightest and the next-to-lightest neutralinos with singlino and bino as their dominant components respectively. Our simulations indicate that after considering the constraints from the ATLAS searches for $jets + E_{T}^{miss}$ signal the central value of the excess can be obtained for $m_{\tilde{q}} \lesssim 1.2 {\rm TeV}$, and if the constraint from the CMS on-$Z$ search is further considered, more than 10 signal events are still attainable for $m_{\tilde{q}} \lesssim 750 {\rm GeV}$. Compared with the interpretation by gluino pair production, the squark explanation allows for a significantly wider range of $m_{\tilde{q}}$ as well as a less compressed SUSY mass spectrum. We also show that the squark explanation will be readily tested at the initial stage of the 14 TeV LHC.Comment: 19 pages, 4 figure

Interpreting the galactic center gamma-ray excess in the NMSSM

In the Next-to-Minimal Supersymmetric Standard Model (NMSSM), all singlet-dominated particles including one neutralino, one CP-odd Higgs boson and one CP-even Higgs boson can be simultaneously lighter than about 100 GeV. Consequently, dark matter (DM) in the NMSSM can annihilate into multiple final states to explain the galactic center gamma-ray excess (GCE). In this work we take into account the foreground and background uncertainties for the GCE and investigate these explanations. We carry out a sophisticated scan over the NMSSM parameter space by considering various experimental constraints such as the Higgs data, $B$-physics observables, DM relic desnity, LUX experiment and the dSphs constraints. Then for each surviving parameter point we perform a fit to the GCE spectrum by using the correlation matrix that incorporates both the statistical and systematic uncertainties of the measured excess. After examining the properties of the obtained GCE solutions, we conclude that the GCE can be well explained by the pure annihilations $\tilde{\chi}_1^0 \tilde{\chi}_1^0 \to b \bar{b}$ and $\tilde{\chi}_1^0 \tilde{\chi}_1^0 \to A_1 H_i$ with $A_1$ being the lighter singlet-dominated CP-odd Higgs boson and $H_i$ denoting the singlet-dominated CP-even Higgs boson or SM-like Higgs boson, and it can also be explained by the mixed annihilation $\tilde{\chi}_1^0 \tilde{\chi}_1^0 \to W^+ W^-, A_1 H_1$. Among these annihilation channels, $\tilde{\chi}_1^0 \tilde{\chi}_1^0 \to A_1 H_i$ can provide the best interpretation with the corresponding $p$-value reaching 0.55. We also discuss to what extent the future DM direct detection experiments can explore the GCE solutions and conclude that the XENON-1T experiment is very promising in testing nearly all the solutions.Comment: 31 pages, 7 figure