Light-Emitting Diode Degradation and Low-Frequency Noise Characteristics

Comprehensive investigation of phosphide-based red and nitride-based blue light-emitting diodes characteristics and physical processes that take place in device structure during aging has been carried out. Analysis of noise characteristics (the emitting-light power and the LED voltage fluctuations, also their cross-correlation factor) shows that investigated LEDs degradation is caused by defects that lead to the leakage current and non-radiating recombination increase in the active region or its interfaces. Appearance of the defects first of all manifests in noise characteristics: intensive and strongly correlated $1//f^{α}$ type optical and electrical fluctuations come out

Optical and Electrical Noise Characteristics of Side Emitting LEDs

Low frequency noise characteristics of nitride based blue side emitting diodes have been investigated. It is shown that investigated devices distinguish by $1//f^α$-type optical and electrical fluctuations caused by various generation-recombination processes through defects formed generation-recombination centers. At higher frequencies optical shot noise due to random photon emission prevails $1//f^α$-type spectrum. The results have shown that low frequency optical and electrical noises are strongly correlated at small current region, but at higher forward current not correlated noise components dominate. Lenses and secondary optics of the investigated devices do not influence output light

Particulate-facilitated leaching of glyphosate and phosphorus from a marine clay soil via tile drains

Losses of commonly used chemical pesticides from agricultural land may cause serious problems in recipient waters in a similar way to phosphorus (P). Due to analytical challenges concerning determination of glyphosate (Gly), transport behaviour of this widely used herbicide is still not well-known. The objective of the present study was to quantify and evaluate leaching of Gly in parallel with P. Leaching losses of autumn-applied Gly (1.06 kg ha-1) via drainage water were examined by flow-proportional sampling of discharge from 20 drained plots in a field experiment in eastern Sweden. Samples were analysed for Gly in particulate-bound (PGly) and dissolved (DGly) form. The first 10 mm water discharge contained no detectable Gly, but the following 70 mm had total Gly (TotGly) concentrations of up to 6 µg L-1, with 62% occurring as PGly. On average, 0.7 g TotGly ha-1 was leached from conventionally ploughed plots, compared with 1.7 g TotGly ha-1 from shallow-tilled plots (cultivator to 12 cm working depth). Higher Gly losses occurred in snowmelt periods in spring, but then with the majority (60%) as DGly. All autumn concentrations of PGly in drainage water were significantly correlated (p<0.001) to the concentrations of particulate-bound phosphorus (PP) lost from the different plots (Pearson correlation coefficient 0.84), while PP concentrations were in turn significantly correlated to water turbidity (Pearson correlation coefficient 0.81). Leaching losses of TotGly were significantly lower (by 1.3 g ha-1; p<0.01) from plots that had been structure-limed three years previously and ploughed thereafter than from shallow-tilled plots. Turbidity and PP concentration also tended to be lowest in discharge from structure-limed plots and highest from shallow-tilled plots. This difference in TotGly leaching between soil management regimes could not be explained by differences in measured pH in drainage water or amount of discharge. However, previously structure-limed plots had significantly better aggregate stability, measured as readily dispersed clay (RDC), than unlimed plots. The effects of building up good soil structure, with strong soil aggregates and an appropriate pore system in the topsoil, on mitigating Gly and P losses in particulate and dissolved form should be further investigated