3 research outputs found
Examining electron-boson coupling using time-resolved spectroscopy
Nonequilibrium pump-probe time domain spectroscopies can become an important
tool to disentangle degrees of freedom whose coupling leads to broad structures
in the frequency domain. Here, using the time-resolved solution of a model
photoexcited electron-phonon system we show that the relaxational dynamics are
directly governed by the equilibrium self-energy so that the phonon frequency
sets a window for "slow" versus "fast" recovery. The overall temporal structure
of this relaxation spectroscopy allows for a reliable and quantitative
extraction of the electron-phonon coupling strength without requiring an
effective temperature model or making strong assumptions about the underlying
bare electronic band dispersion.Comment: 23 pages, 4 figures + Supplementary Material and movies, to appear in
PR
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Photoluminescence of Diamondoid Crystals
The photoluminescence of diamondoids in the solid state is examined. All of the diamondoids are found to photoluminesce readily with initial excitation wavelengths ranging from 233 nm to 240 nm (5.3 eV). These excitation energies are more than 1 eV lower than any previously studied saturated hydrocarbon material. The emission is found to be heavily shifted from the absorption, with emission wavelengths of roughly 295 nm (4.2 eV) in all cases. In the dissolved state, however, no uorescence is observed for excitation wavelengths as short as 200 nm. We also discuss predictions and measurements of the quantum yield. Our predictions indicate that the maximum yield may be as high as 25%. Our measurement of one species, diamantane, gives a yield of 11%, the highest ever reported for a saturated hydrocarbon, even though it was likely not at the optimal excitation wavelength
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