Apparatus for Dielectric Constant Measurements and Measurements for Water-Methanol Mixtures

A system for measuring dielectric constants has been constructed using a Sargent Oscillometer and an air bath for temperature control. The design and construction of the air bath as well as the temperature control achieved with it are described. The overall performance of the system including a computer program for forming the calculations is described. The system is one that requires calibration using two or more standard solvents and is good for both conducting and non-conducting liquids. Data are presented for water-methanol mixtures at 25 degrees with several points near pure methanol and also near pure wate

Rapid Electroosmosis Measurements

A cell has been designed and built that allows for rapid measurement of volume moved in a definite time by electroosmosis. The cell is simple to use and is not very elaborate. Using a water jacket, the cell temperature can be controlled to ± 0.1° C. Measurements are presented for acetonitrile, dimethylformamide, and nitrobenzene at 25° C for applied voltages of 25, 50, 75, and 100 volts

The development of spectro-signature indicators of root disease on large forest areas Annual progress report

Visible and near infrared spectrometric tests of selected black and white film-filter combinations for descriminating between healthy and diseased Douglas fir tree

Chemistry Departments in Predominantly Black Institutions

Chemistry programs in 87 predominantly Black institutions were compared by questionnaire survey. Advanced undergraduate courses were offered for chemistry majors by 86% of these schools, but only 28% offered research and independent study for undergraduates. Although there were extremes, most of the faculty taught 15 to 18 contact hours and their median salaries were below the national median. Library support seemed adequate with 1 to 1.5% of the total library materials being chemistry books, texts and reference, and the libraries of most schools had holdings of 15 principal chemistry-related journals. More than 90% of the schools were well-equipped with laboratory instrumentation for the undergraduate program. One-third of the schools were recipients of current grants, but less than 50% of these grants were for research. At the time of the survey there was a median of 13 chemistry majors in the schools, but this has been increasing since. On the basis of 45% response from individual faculty members of these schools, all faculty members had post-baccalaureate degrees, with 2/3 holding the doctoral degree. Only about 2/3 of the respondents indicated professional activity via scientific meeting attendance and/or recent publication. Most respondents (92%) were members of the American Chemical Society, but membership in other professional societies was much less common. Responses by these faculty members indicated that up-to-date instructional methods were generally being used

Wheel material wear mechanisms and transitions

In order to develop more durable wheel materials to cope with the new specifications being imposed on wheel wear, a greater understanding is needed of the wear mechanisms and transitions occurring in wheel steels, particularly at higher load and slip conditions. In this work wear assessment of wheel materials is discussed as well as wear rates, regimes and transitions. Twin disc wear testing, used extensively for studying wear of wheel and rail materials, has indicated that three wear regimes exist for wheel materials; mild, severe and catastrophic. These have been classified in terms of wear rate and features. Wear rates are seen to increase steadily initially, then level off, before increasingly rapidly as the severity of the contact conditions is increased. Analysis of the contact conditions in terms of friction and slip has indicated that the levelling off of the wear rate observed at the first wear transition is caused by the change from partial slip to full slip conditions at the disc interface. Temperature calculations for the contact showed that the large increase in wear rates seen at the second wear transition may result from a thermally induced reduction in yield strength and other material properties. Wear maps have been produced using the test results to study how individual contact parameters such as load and sliding speed influence wear rates and transitions. The maps are also correlated to expected wheel/rail contact conditions. This improved understanding of wheel wear mechanisms and transitions and will help in the aim of eventually attaining a wear modelling methodology reliant on material properties rather than wear constants derived from testing

Abrasive wear behaviour of 27MnB5 steel used in agricultural tines

Understanding the wear mechanisms in wear parts is a crucial element of tribological investigation, particularly in agricultural applications where the knowledge about abrasive micro-mechanisms of soil engaging tools are limited. In the current research, symmetrical skew wedge cultivator tines of 27MnB5 steel were wear tested to investigate the change in mass, linear dimensions, hardness and microstructure, aiming at prolonging the lifetime of these parts through design and material. The wear mechanisms were identified and characterized by non-contact 3D optical profilometry. Test results clearly shows a zone specific wear micro-mechanism based on the tine geometry. The cutting edge of the tine can be segmented into micro-cutting and micro-ploughing zone. Vickers hardness and microstructural analysis were performed on the cross-section of the sliding interface. Tribolayer was observed on the worn surface. Degree of penetration from the wear scratches was calculated to justify the wear micro-mechanisms. A Discrete Element Method (DEM) model was developed to investigate the soil flow during the tillage process. The model results and field test wear scars are in good agreement with each other with respect to the wear patterns

Integrating Dynamics and Wear Modelling to Predict Railway Wheel Profile Evolution

The aim of the work described was to predict wheel profile evolution by integrating multi-body dynamics simulations of a wheelset with a wear model. The wear modelling approach is based on a wear index commonly used in rail wear predictions. This assumes wear is proportional to Tγ, where T is tractive force and γ is slip at the wheel/rail interface. Twin disc testing of rail and wheel materials was carried out to generate wear coefficients for use in the model. The modelling code is interfaced with ADAMS/Rail, which produces multi-body dynamics simulations of a railway wheelset and contact conditions at the wheel/rail interface. Simplified theory of rolling contact is used to discretise the contact patches produced by ADAMS/Rail and calculate traction and slip within each. The wear model combines the simplified theory of rolling contact, ADAMS/Rail output and the wear coefficients to predict the wear and hence the change of wheel profile for given track layouts

Wear maps for TiC composite based coatings deposited on 303 stainless steel

Dry sliding wear (pin-on-disc) tests were carried out under ambient conditions at room temperature for TiC coated and uncoated 303 stainless steel, using alumina as a counterface. The composite coating which was developed by Tungsten Inert Gas (TIG) methods increased the surface hardness of the substrate and the sliding wear resistance of the substrate. Wear maps for both uncoated and coated materials were developed on the basis of tests results. The results indicated that the role of oxidative wear differed significantly for both coated and uncoated materials on the wear map. In addition, it was found that TiC composite coatings not only increased the wear resistance but also expanded the mild wear region towards higher loads and sliding speeds

Wear rates in urban rail systems

A significant part of maintenance costs in urban rail systems (metro, tram, light rapid transit/light metro) is due to wheel-rail wear. Wear rates - measured for example as depth of wear per kilometre run (rolling stock) or per train passage (rails) - depend in a complex manner on several influence factors. Among the most important are key design factors of the rolling stock (wheel profiles, suspension characteristics), of the track (distribution of curve radii, characteristics of switches and crossings, rail profiles), of the wheel-rail interface (lubrication, materials in contact, ambient characteristics), and of operations (frequency of traction and braking, trainset inversion policy, maintenance policy etc.). When designing an urban rail system, all of these factors have to be under control in order to limit the costs due to wheel/rail reprofiling/grinding and replacement. The state of the art allows the calculation of wear rates given quantitative input regarding the above factors. However, it is difficult to find in the literature experimental values for calibration of wear models and indications on what is a reasonable state-of-the-art wear rate for any given type of urban rail system. In this paper we present a structured analysis of flange wear rates found in the literature and derived from the experience of the authors, for a variety of cases, including metros and mainline rail systems. We compare the wear rates and explain their relationship with the influence factors. We then relate the wear rates with the needs in terms of wheel reprofiling/replacement. We estimate ranges for the calibration coefficients of wear models. We present the results in a way as to allow the designer of urban rail systems to derive values for target wear rates according to their specific conditions without the need for complex simulations

An energy description of wear mechanisms and its applications to oscillating sliding contacts

To quantify wear rates, the Archard approach is classically applied. It relates the wear volume to the product of the sliding distance and the normal load. A wear coefficient is then extrapolated and is supposed to establish the wear resistance of the studied material. This synthesis shows that this approach does not work when the friction coefficient is not constant. It appears to be much more relevant to consider the interfacial shear work as a significant wear parameter. This approach is applied to study the wear response of different steels and then extended to different hard TiN, TiC coatings under reciprocating sliding conditions. By identifying wear energy coefficients the wear quantification can be rationalized and the wear resistance of the studied tribosystems can be classified. This also appears to be a convenient approach to interpret the different wear mechanisms. Metallic materials involving plastic strain are analyzed from FEM computations. The energy balance confirms that a minor part of the dissipated energy is consumed by plasticity, whereas the major part participates in the heat and debris flow through the interface. When a load energy approach is introduced an accumulated density of the dissipated energy variable is considered to quantify the TTS (Tribologically Transformed Structure) formation. A wear ”scenario” of metallic structures is then discussed. This energy wear approach is applied to analyze hard coating wear mechanisms focusing on abrasion and oxidation phenomena. The local wear energy analysis is transposed, thus allowing the lifetime of hard coatings to be quantified