Superconductivity in higher titanium oxides

Recent renewal of the highest transition temperature in a conventional superconductor of the sulfer hydride attracts much attention to exploring simple compounds with the lighter elements, situated in unconventional conditions. We report the discovery of superconductivity in simple oxides of Ti4O7 and g-Ti3O5 in a thin-film form having deliberately tuned epitaxial structures and off-stoichiometry. These higher titanium oxides join in a class of simple-oxide superconductors, and g-Ti3O5 now holds the highest superconducting transition temperature of 7.1 kelvin among them. The mechanism behind the superconductivity is discussed on the basis of electrical measurements and theoretical predictions. We conclude that superconductivity arises from unstabilized bipolaronic insulating states.Comment: 25 pages, 4 figures in main text, 14 pages, 11 figures in supplemental informatio

Magnesium-zinc reduction is effective in preparation of metals

Uranium, thorium, and plutonium are effectively prepared by magnesium-zinc reduction, using uranium oxides, thorium dioxide, and plutonium dioxide as starting materials. This technique is also useful in performing reduction of metals such as zirconium and titanium

Formation of coloring complexes in glass colored with cerium and titanium oxides

The valence state of cerium and titanium ions in barium-strontium aluminosilicate glass with a different ratio of cerium and titanium oxides was investigated and the possible composition of the cerium-titanium complexes formed in silicate glass was analyzed. It was found that an active separate reaction between cerium and titanium oxides with the appearance of complex color centers takes place in synthesis of the glass. It is hypothesized that color centers primarily form between tetravalent cerium and tetravalent titanium in glass-forming melts

Method for producing oxygen from lunar materials

This invention is related to producing oxygen from lunar or Martian materials, particularly from lunar ilmenite in situ. The process includes producing a slurry of the minerals and hot sulfuric acid, the acid and minerals reacting to form sulfates of the metal. Water is added to the slurry to dissolve the minerals into an aqueous solution, the first aqueous solution is separated from unreacted minerals from the slurry, and the aqueous solution is electrolyzed to produce the metal and oxygen

Microstructural Characterization of Shrouded Plasma-Sprayed Titanium Coatings

Titanium and its alloys are often used for corrosion protection because they are able to offer high chemical resistance against various corrosive media. In this paper, shrouded plasma spray technology was applied to produce titanium coatings. A solid shroud with an external shrouding gas was used to plasma spray titanium powder feedstock with aim of reducing the oxide content in the as-sprayed coatings. The titanium coatings were assessed by optical microscope, scanning electron microscopy, X-ray diffraction, LECO combustion method and Vickers microhardness testing. The results showed that the presence of the shroud and the external shrouding gas led to a dense microstructure with a low porosity in the plasma-sprayed titanium coatings. The oxygen and nitrogen contents in the titanium coating were kept at a low level due to the shielding effect of the shroud attachment and the external shrouding gas. The dominant phase in the shrouded titanium coatings was mainly composed of α-Ti phase, which was very similar to the titanium feedstock powders. The shrouded plasma-sprayed titanium coatings had a Vickers microhardness of 404.2 ± 103.2 HV

European mineral statistics 2002-06 : a product of the World Mineral Statistics database

European Mineral Statistics has over 300 pages of tables on minerals production and trade. Thirty two countries are covered including all the EU members, EU applicants, Norway and Switzerland. In the first section there are tables by country, followed by commodity tables with selected graphics and bullet points with information on use and prices

Improved photocatalytic properties of doped titanium-based nanometric oxides

Photocatalysis is considered one of the most promising technologies for applications in the environmental field especially in the abatement of water-soluble organic pollutants. In this field, titanium dioxide nanoparticles have drawn much attention recently; however, the use of this oxide presents some limitation since it allows to obtain high photoresponse and degradation efficiency only under UV light irradiation, that represents the 3 to 4% of the solar radiation, so preventing its environmental large-scale applications under diffuse daylight. In this work the photocatalytic efficiencyoftitanium-based oxides systems containing alkaline earth metals such as barium and strontium, prepared by a simple sol-gel method was investigated, evaluating the degradation of methylene blue as model compound under UV and visible light irradiation. The results were compared with those obtained with Degussa P25 titanium dioxide. The achieved degradation percentage of methylene blue are very promising showing that under visible light irradiation it is possible to obtain a maximum dye removal percentage ~ 50 % higher than that obtained with the Degussa P25

From art to engineering

This paper describes work which emerged through a need to understand more about the potential of laser surface engineering for use in the creative industries. The method of creation of contemporary jewellery pieces and the resultant ‘Ocular’ jewellery series are described from the points of view of an artist and an engineer. The work demonstrates how laser controlled oxide growth on commercially pure titanium under ambient conditions can be used as an artistic tool by producing even, defined colours or by reproducing a simulation of freehand drawings on a titanium surface. It also asks the question: how different are artists from scientists and engineers

Features of medical implant passivation using anodic oxide films

The passivation ability of metals from groups IV and V of the Periodic Table is considered. Anodic treatment is able to neutralize the increase of metal hardening when comminuting grains to nanometre sizes. The deposition of metal oxide film coatings on a cobalt–chromium alloy surface results in substantial passivation of its surface and prevents cobalt and chromium accumulation in bone tissues. The decrease of surface activity of titanium implants can be achieved both by cleaning the surface during vacuum annealing before oxidation and by the increase of the anodic oxide film thickness, which limits mass and charge transfer through the implant surface. Recommended titanium implant treatment regimens are vacuum annealing at 650 °C and anodic oxidation to attain an oxide thickness less or equal to 300 nm