Selenium and molybdenum enrichment in uranium roll-front deposits of Wyoming and Colorado, USA

Acknowledgements The authors wish to thank Cal VanHolland, Jim Bonner and John Cooper of Ur-Energy (Casper, Wyoming) for their assistance with sampling, data provision and feedback. We are grateful to Adrian Boyce and Alison McDonald of the Isotope Community Support Facility at SUERC for technical support with isotope sample preparation and analyses. Critical comments that greatly improved the manuscript from Samuel Spinks and Marat Abzalov are gratefully acknowledged. Funding This research was supported by a grant from the Natural Environment Research Council (NERC) (NE/M010953/1).Peer reviewedPublisher PD

Leaching behaviour and the solution consumption of uranium-vanadium ore in alkali carbonate–bicarbonate column leaching

This is the author accepted manuscript. The final version is available from the publisher via the DOI in this record.Although heap leaching using sulfuric acid was introduced to the uranium industry in the 1950s, sodium carbonate–bicarbonate (alkaline) heap leaching of low-grade Ca-carbonate-rich uranium ores has recently gained popularity. This study presents the results of two column tests on a calcrete-type uranium–vanadium (carnotite) ore using a mixture of sodium carbonate and bicarbonate (Na2CO3/NaHCO3) as the leach solution. This data was kindly supplied by Toro Energy Ltd. The experimental data comprised physical–chemical leach information and two different irrigation rates (10 and 20 L/h·m2). The experimental data indicated that the carnotite ore with high calcium carbonate (CaCO3) can be leached effectively using the alkaline leach solution. The increase in the irrigation rate increased the uranium and vanadium extraction and decreased their concentration in the effluent. The column leach data was therefore fitted to a simplified first-order kinetic model using two approaches, a general form and a second based on the reagent consumption per unit mass of the initial valuable species (U and V). As reagent consumption is a key economic factor in the heap leaching process, having a kinetic leaching model incorporating reagent consumption would provide useful techno-economic information. In this regards a new leaching index of (β) is also introduced. Both approaches of the first order kinetic model provide a good agreement with the column testing data

Vanadium ore resources of the African continent: State of the Art

As part of the critical metals group, vanadium is an essential commodity for the low- and zero-CO2 energy generation, storage and transport. This contribution aims to carry out a review of the known vanadium ore sources and mineralizations located in Africa, which are highly diversified in their geological and mineralogical characteristics, and can be classified in: 1. Vanadiferous (titano)magnetite deposits; 2. Sandstone-hosted (U)-vanadium deposits; 3. Calcrete-hosted (U)-vanadium deposits; 4. Vanadate deposits; 5. Graphite-associated vanadium deposits; 6. Vanadium occurrences associated with laterite, bauxite, and phosphate ores. The economically most significant vanadium sources in Africa are associated with titanomagnetite layers in mafic–ultramafic layered magmatic intrusions (e.g., the Bushveld Complex in South Africa and the Great Dyke in Zimbabwe). Vanadium has been historically mined also in vanadate deposits deriving from the supergene alteration of Pb-Zn-Cu sulfide ores in Namibia and Zambia. Several areas in these countries, where potentially re-processable old tailings and slags have been accumulated, still have economic potential. Vanadium mineralizations are associated with graphite bodies in the Mozambique Metamorphic Belt. Vanadium is also enriched in uranium ores occurring in the Upper Paleozoic-Mesozoic Karoo continental sediments: typical examples are found in Botswana, South Africa, and Zimbabwe. Significant uranium-vanadium concentrations (where carnotite prevails) occur in relatively recent (Tertiary-Quaternary) calcrete duricrusts in paleo-fluviatile beds, which are widespread throughout the African continent. These derive from the weathering of U-(V)-fertile source rocks, which under favorable paleoclimatic conditions resulted in the vanadium precipitation in the critical zone. Variable vanadium amounts have been also recorded in iron ore deposits, phosphorites, and laterites, even though the phosphate deposits seem to have the most favorable characteristics for potentially economic vanadium concentrations. On the whole, South Africa holds the most significant vanadium ore resources globally. However, also many other African countries, where this metal could be profitably extracted as a by-product from other economic ores, will probably be at the forefront of vanadium production in the near future

Sandstone-Hosted Uranium Deposits as a Possible Source for Critical Elements: The Eureka Mine Case, Castell-Estaó, Catalonia

The Eureka deposit in Castell-estaó in the Catalan Pyrenees is a Cu-U-V deposit, hosted by Triassic red-bed sandstones, and classified here as a low-temperature, sandstone-hosted stratabound metamorphite U deposit. The main mineralisation is stratabound, related to coal-bearing units and produced during the Alpine deformation by migration of hydrothermal fluids. In this stage, the original sedimentary and diagenetic components (quartz and calcite, micas, hematite and locally apatite) were replaced by a complex sequence of roscoelite, fine-grained REE phosphates, sulphides and Ni-Co arsenides and sulpharsenides, Ag-Pb selenides, bismuth phases, sulphosalts and uraninite. The black shales of the Silurian sediments underlying the deposit and the nearby Carboniferous volcanoclastic rocks are interpreted as the source of the redox-sensitive elements concentrated in Eureka. The sulphur source is related to leaching of the evaporitic Keuper facies. The REE transport would be facilitated by SO4-rich solutions. The reduction of these solutions by interaction with organic matter resulted in the widespread precipitation of REE and redox-sensitive elements, including many critical metals (V, Bi, Sb, Co), whereas barite precipitated in the oxidized domains. The occurrence of similar enrichments in critical elements can be expected in other similar large uranium deposits, which could be a source of these elements as by-products. © 2019 by the authors. Licensee MDPI, Basel, Switzerland

Metal flux from dissolution of iron oxide grain coatings in sandstones

Acknowledgements Sandstone samples were kindly contributed by the Geological Survey of Northern Ireland, D. Halbert, R. Starkey, and L. Bullock. This work was partly supported by NERC grant NE/M010953/1. Electron Microscopy was performed with the help of J. Still in the ACEMAC Facility at the University of Aberdeen.Peer reviewedPublisher PD

The concept of grade in mineral deposits

The grade of a mineral deposit is determined by the effectiveness of a geological ore forming process, which is the result of the interaction between an ore forming mechanism and the environment in which it operates. Properties of a mineral deposit controlled by ore forming processes include the distribution, density and nature of ore minerals and gangue, and the metal content and impurities of the ore minerals. More efficient ore forming processes tend to develop in the larger mineralizing systems giving rise to richer deposits. As the geological environment within which a mineral deposit evolves becomes more complex a greater number of variables interact to determine the grade of the deposit. This is reflected in the greater variability of the grade distribution, resulting in greater difficulties in obtaining reliable estimates of the recoverable grade, and increased difficulties in the processing of ores. In response to economic fluctuations the working grade of heterogeneous orebodies, that form in geologically complex environments, can often be altered to ensure the continued viability of a mining venture. In contrast the evenly mineralized orebodies that tend to develop in geologically simple environments do not have this flexibility. All the important decisions in the mining industry, such as feasibility studies, choice of ~ining and processing methods, selection and planning, are made on the basis of, or are related to, grade estimates. If the geological controls of grade are fully understood, then it is possible to optimize the selection of the various mining alternatives, leading to the efficient exploitation of ore deposits

The Paleozoic Sedimentary Rocks of the Ouachita Mountains and their Genetic Relationship to the Mississippi Valley-Type Mineralization in the Southern Ozark Region: Insights from Radiogenic Pb Isotopes and Trace Elements Studies

Cluster of Pb and/or Zn deposits of the well-known Tri-State and Northern Arkansas Mississippi Valley Type (MVT) districts located north of the Arkoma basin and the Ouachita fold-thrust belt in north America are genetically connected to the Pennsylvanian-Permian Ouachita orogeny which triggered a South-North topographic gradient flow of basinal brines, leaching metal rich sediments en route. The objective of the research is twofold. First, to ascertain whether the organic-rich shales and sandstones from the study area provided metals during the mineralization event, which was coeval with the Ouachita orogeny. Second, to assess the depositional environment of the potential source rocks, which will shed light on their ability to sequester metals. The Pb isotope compositions of the ores (sphalerite) have been compared to their associated sedimentary rocks (Collier, Mazarn, and Polk Creek, Womble, Fayetteville, Stanley and Chattanooga shales and Jackfork Sandstone) and metal sources have been evaluated. In addition, the role of depositional redox of sedimentary rocks to sequester adequate amounts of metals has been appraised using redox sensitive trace elements (U, V, Mo, Cr, etc.). The Pb isotope compositions of the ores (sphalerite) have been compared to those of the sedimentary rocks of the Ouachita Mountains (Cambrian Collier Shale, Early Ordovician Mazarn Shale, Middle Ordovician Womble Shale, Late Ordovician Polk Creek Shale, Mississippian Stanley Shale, and Pennsylvanian Jackfork Sandstone) and the Ozark Plateau (Devonian/Mississippian Chattanooga Shale and Mississippian Fayetteville Shale).Metal sources evaluation indicate a mixing model of fluids sourced from high and less radiogenic rocks shown by a broad and linear trend of Pb isotope composition, with the Chattanooga rock and the Jackfork sandstone samples being the most prominent source rocks. Paleoredox proxies indicate deposition under anoxic and Euxinic conditions, which are favorable for metal enrichment. How-ever, oxic-suboxic conditions are also indicated by other geochemical proxies, suggesting the possible first order control of primary production that has resulted in increased flux of organic matter. Additional factors such as the basin geometry, the rates of sediment accumulation, the post depositional alteration processes associated with diagenesis and low-grade metamorphism during the Ouachita orogeny might have overprinted the depositional signatures

CHPM2030 Deliverable D1.1: EGS-relevant review of metallogenesis

This document provides a review of metallogenic provinces in Europe. The ore-forming processes, the structure and the metal content of the ore deposits are discussed. Special focus is put on the mineral potential in the depth and temperature zones that are currently the target of EGS