Analysis of wear mechanism in TPU-steel contact pair by means of long stroke tribometer tests

A complete wear characterisation of a thermoplastic polyurethane (TPU) sliding against steel is presented. Wear tests were performed using a long stroke tribometer under sliding reciprocating movement and dry conditions. The dependence of some of the most significant parameters was studied. Before and after wear tests, complementary observations, analyses and measurements were also performed on both contacting materials. These various characterisations involved weight loss of TPU, physico-chemical and thermo- mechanical analyses of TPU, included topographical measurements and morphological observations of worn surfaces of contacting pairs and calculations of the temperature rise generated by friction

Nanocellular Polymers with a Gradient Cellular Structure Based on Poly(methyl methacrylate)/Thermoplastic Polyurethane Blends Produced by Gas Dissolution Foaming

Graded structures and nanocellular polymers are two examples of advanced cellular morphologies. In this work, a methodology to obtain low-density graded nanocellular polymers based on poly(methyl methacrylate) (PMMA)/ thermoplastic polyurethane (TPU) blends produced by gas dissolution foaming is reported. A systematic study of the effect of the processing condition is presented. Results show that the melt-blending results in a solid nanostructured material formed by nanometric TPU domains. The PMMA/ TPU foamed samples show a gradient cellular structure, with a homogeneous nanocellular core. In the core, the TPU domains act as nucleating sites, enhancing nucleation compared to pure PMMA and allowing the change from a microcellular to a nanocellular structure. Nonetheless, the outer region shows a gradient of cell sizes from nano- to micron-sized cells. This gradient structure is attributed to a non-constant pressure profile in the samples due to gas desorption before foaming. The nucleation in the PMMA/ TPU increases as the saturation pressure increases. Regarding the effect of the foaming conditions, it is proved that it is necessary to have a fine control to avoid degeneration of the cellular materials. Graded nanocellular polymers with relative densities of 0.16–0.30 and cell sizes ranging 310–480 nm (in the nanocellular core) are obtained

Segmented phase of ultraviolet (UV) curable thermoset polyurethanes-graphite (TPU-G) composites

Segmented thermoset polymeric materials properties mainly classified through its carbonyl hydrogen bonding. The addition of graphite particle loading in polymeric materials tailored the functional characteristic of the composites. Therefore, the carbonyl hydrogen bonding in the hard segments of the synthesized segmented ultraviolet (UV) curable thermoset polyurethanes-graphite (TPU-G) composites was identified. This composites based green polymer incorporated with varying graphite particles loading were prepared through slip casting method which cure upon UV light. These result in an enhancement of the carbonyl hydrogen bonding which tribute to degree of phase separation (DPS %) in the TPU-G composites ranged from 10-20%, as compared to that in the pure TPU. In addition, the spectroscopy detects the formation of carbonyl hydrogen groups within the TPU-G composites although they are prone to chain scission and undergo photo oxidation subjected to ultraviolet (UV) curing. Upon UV curing, higher graphite weight loading (TPU-G20, TPU-G25 and TPU-G30 composites), shows higher and stable DPS% value, attribute to soft segment- soft segment and hard segment- hard segment establishment. Therefore, the graphite particles dominantly absorb the incident radiation instead of thermoset polyurethane without changing its based

Persistence analysis of velocity and temperature fluctuations in convective surface layer turbulence

Persistence is defined as the probability that the local value of a fluctuating field remains at a particular state for a certain amount of time, before being switched to another state. The concept of persistence has been found to have many diverse practical applications, ranging from non-equilibrium statistical mechanics to financial dynamics to distribution of time scales in turbulent flows and many more. In this study, we carry out a detailed analysis of the statistical characteristics of the persistence probability density functions (PDFs) of velocity and temperature fluctuations in the surface layer of a convective boundary layer, using a field-experimental dataset. Our results demonstrate that for the time scales smaller than the integral scales, the persistence PDFs of turbulent velocity and temperature fluctuations display a clear power-law behaviour, associated with self-similar eddy cascading mechanism. Moreover, we also show that the effects of non-Gaussian temperature fluctuations act only at those scales which are larger than the integral scales, where the persistence PDFs deviate from the power-law and drop exponentially. Furthermore, the mean time scales of the negative temperature fluctuation events persisting longer than the integral scales are found to be approximately equal to twice the integral scale in highly convective conditions. However, with stability this mean time scale gradually decreases to almost being equal to the integral scale in the near neutral conditions. Contrarily, for the long positive temperature fluctuation events, the mean time scales remain roughly equal to the integral scales, irrespective of stability

Controlling the dynamic percolation of carbon nanotube based conductive polymer composites by addition of secondary nanofillers: The effect on electrical conductivity and tuneable sensing behaviour

In this paper, the electrical properties of ternary nanocomposites based on thermoplastic polyurethane (TPU) and multi-walled carbon nanotubes (MWCNTs) are studied. In particular two nanofillers - differing in shape and electrical properties - are used in conjunction with MWCNTs: an electrically conductive CB and an insulating needle-like nanoclay, sepiolite. The ternary nanocomposites were manufactured in a number of forms (extruded pellets, filaments and compression moulded films) and their morphological and electrical properties characterised as function of time and temperature. The presence of both secondary nanofillers is found to affect the formation of a percolating network of MWCNTs in TPU, inducing a reduced percolation threshold and tuneable strain sensing ability. These ternary nanocomposites can find application as conductive and multi-functional materials for flexible electronics, sensing films and fibres in smart textiles. (c) 2012 Elsevier Ltd. All rights reserved

Water Content and Thermoplastic Polyurethane Effects on Thrombosis Clotting

One of the main factors that can increase the chance of heart disease is unwanted blood clotting, or thrombosis. In addition, implantable biomaterials and/or medical devices are likely to trigger a series of adverse reactions that can lead to unwanted blood clotting. Herein, we study a thromboresistant polymeric material, specifically thermoplastic polyurethanes (TPUs), on their physical properties and anticoagulation performance. Their hydrophobic nature and superior mechanical properties make them an ideal candidate for coating materials on implantable medical devices, such as vascular stents. Our results show that hydrophobic TPUs absorbed minimal to negligible water content and provided excellent thromboresistant properties against human plasma.Cockrell School of Engineerin