Picosecond Laser Ablation of Polyhydroxyalkanoates (PHAs): Comparative Study of Neat and Blended Material Response

Polyhydroxyalkanoates (PHAs) have emerged as a promising biodegradable and biocompatible material for scaffold manufacturing in the tissue engineering field and food packaging. Surface modification is usually required to improve cell biocompatibility and/or reduce bacteria proliferation. Picosecond laser ablation was applied for surface micro structuring of short- and medium-chain length-PHAs and its blend. The response of each material as a function of laser energy and wavelength was analyzed. Picosecond pulsed laser modified the surface topography without affecting the material properties. UV wavelength irradiation showed halved ablation thresholds compared to visible (VIS) wavelength, revealing a greater photochemical nature of the ablation process at ultraviolet (UV) wavelength. Nevertheless, the ablation rate and, therefore, ablation efficiency did not show a clear dependence on beam wavelength. The different mechanical behavior of the considered PHAs did not lead to different ablation thresholds on each polymer at a constant wavelength, suggesting the interplay of the material mechanical parameters to equalize ablation thresholds. Blended-PHA showed a significant reduction in the ablation threshold under VIS irradiation respect to the neat PHAs. Picosecond ablation was proved to be a convenient technique for micro structuring of PHAs to generate surface microfeatures appropriate to influence cell behavior and improve the biocompatibility of scaffolds in tissue engineerin

Nutrients and Hydrology Indicate the Driving Mechanisms of Peatland Surface Patterning

Peatland surface patterning motivates studies that identify underlying structuring mechanisms. Theoretical studies so far suggest that different mechanisms may drive similar types of patterning. The long time span associated with peatland surface pattern formation, however, limits possibilities for empirically testing model predictions by field manipulations. Here, we present a model that describes spatial interactions between vegetation, nutrients, hydrology, and peat. We used this model to study pattern formation as driven by three different mechanisms: peat accumulation, water ponding, and nutrient accumulation. By on-and-off switching of each mechanism, we created a full-factorial design to see how these mechanisms affected surface patterning (pattern of vegetation and peat height) and underlying patterns in nutrients and hydrology. Results revealed that different combinations of structuring mechanisms lead to similar types of peatland surface patterning but contrasting underlying patterns in nutrients and hydrology. These contrasting underlying patterns suggest that the presence or absence of the structuring mechanisms can be identified by relatively simple short-term field measurements of nutrients and hydrology, meaning that longer-term field manipulations can be circumvented. Therefore, this study provides promising avenues for future empirical studies on peatland patternin

Optimization of the secondary electron yield of laser-structured copper surfaces at room and cryogenic temperature

Electron cloud (e-cloud) mitigation is an essential requirement for proton circular accelerators in order to guarantee beam stability at a high intensity and limit the heat load on cryogenic sections. Laser-engineered surface structuring is considered a credible process to reduce the secondary electron yield (SEY) of the surfaces facing the beam, thus suppressing the e-cloud phenomenon within the high luminosity upgrade of the LHC collider at CERN (HL-LHC). In this study, the SEY of Cu samples with different oxidation states, obtained either through laser treatment in air or in different gas atmospheres or via thermal annealing, has been measured at room and cryogenic temperatures and correlated with the surface composition measured by x-ray photoelectron spectroscopy. It was observed that samples treated in nitrogen display the lowest and more stable SEY values, correlated with the lower surface oxidation. In addition, the surface oxide layer of air-treated samples charges upon electron exposure at a low temperature, leading to fluctuations in the SEY

Efficiently Storing Well-Composed Polyhedral Complexes Computed Over 3D Binary Images

A 3D binary image I can be naturally represented by a combinatorial-algebraic structure called cubical complex and denoted by Q(I ), whose basic building blocks are vertices, edges, square faces and cubes. In Gonzalez-Diaz et al. (Discret Appl Math 183:59–77, 2015), we presented a method to “locally repair” Q(I ) to obtain a polyhedral complex P(I ) (whose basic building blocks are vertices, edges, specific polygons and polyhedra), homotopy equivalent to Q(I ), satisfying that its boundary surface is a 2D manifold. P(I ) is called a well-composed polyhedral complex over the picture I . Besides, we developed a new codification system for P(I ), encoding geometric information of the cells of P(I ) under the form of a 3D grayscale image, and the boundary face relations of the cells of P(I ) under the form of a set of structuring elements. In this paper, we build upon (Gonzalez-Diaz et al. 2015) and prove that, to retrieve topological and geometric information of P(I ), it is enough to store just one 3D point per polyhedron and hence neither grayscale image nor set of structuring elements are needed. From this “minimal” codification of P(I ), we finally present a method to compute the 2-cells in the boundary surface of P(I ).Ministerio de Economía y Competitividad MTM2015-67072-

Light driven structuring of glasses

Theoretical and experimental evidence of light driven structuring of glasses is presented. We show that light overcomes Coulomb repulsion and effective electron-electron interaction in glasses under strong light pumping becomes attractive. As the result homogenious distribution of trapped electrons gets unstable and macroscopic electron bunches are grown. At different conditions ordered structures with period about 2 microns determined by internal properties of the material are formed These structures were observed in ablation: surface profile after laser treatment reveals ordered pattern corresponding to the light induced electron domains.Comment: 7 pages, 6 figure

“I’d Rather Be in Afghanistan”: Antinomies of \u3cem\u3eBattle: Los Angeles\u3c/em\u3e

This article reads Battle: Los Angeles (2011) against the grain to argue that the film possesses an antiwar undertow running unexpectedly counter to its surface-level pro-military politics. The article uses the antinomy structuring Battle: Los Angeles as the opportunity to explore the pro- and anti-war politics of science fiction alien invasion film more generally, as well as consider the role of cooperation with the military in Hollywood blockbusters. The article closes with a Jamesonian reading of “the army”: as a kind of utopia as registered by mainstream cultural texts like Battle: Los Angeles

3D Well-composed Polyhedral Complexes

A binary three-dimensional (3D) image $I$ is well-composed if the boundary surface of its continuous analog is a 2D manifold. Since 3D images are not often well-composed, there are several voxel-based methods ("repairing" algorithms) for turning them into well-composed ones but these methods either do not guarantee the topological equivalence between the original image and its corresponding well-composed one or involve sub-sampling the whole image. In this paper, we present a method to locally "repair" the cubical complex $Q(I)$ (embedded in $\mathbb{R}^3$) associated to $I$ to obtain a polyhedral complex $P(I)$ homotopy equivalent to $Q(I)$ such that the boundary of every connected component of $P(I)$ is a 2D manifold. The reparation is performed via a new codification system for $P(I)$ under the form of a 3D grayscale image that allows an efficient access to cells and their faces

Lamination And Microstructuring Technology for a Bio-Cell Multiwell array

Microtechnology becomes a versatile tool for biological and biomedical applications. Microwells have been established long but remained non-intelligent up to now. Merging new fabrication techniques and handling concepts with microelectronics enables to realize intelligent microwells suitable for future improved cancer treatment. The described technology depicts the basis for the fabrication of a elecronically enhanced microwell. Thin aluminium sheets are structured by laser micro machining and laminated successively to obtain registration tolerances of the respective layers of 5..10\^A$\mu$m. The microwells lasermachined into the laminate are with 50..80\^A$\mu$m diameter, allowing to hold individual cells within the well. The individual process steps are described and results on the microstructuring are given.Comment: Submitted on behalf of EDA Publishing Association (http://irevues.inist.fr/EDA-Publishing