Preliminary validation of an indirect method for discharge evaluation of Pertuso Spring (Central Italy)

This paper deals with the results of the first year of the Environmental Monitoring Plan, related to the catchment project of Pertuso Spring, which is going to be exploited to supply an important water network in the South part of Roma district. The study area is located in the Upper Valley of the Aniene River (Latium, Central Italy), in the outcrop of Triassic-Cenozoic carbonate rocks, and belong to an important karst aquifer. Pertuso Spring is the main outlet of this karst aquifer and is the one of the most important water resource in the southeast part of Latium Region, used for drinking, agriculture and hydroelectric supplies. Karst aquifer feeding Pertuso Spring is an open hydrogeological system aquifer characterized by complex interactions and exchanges between groundwater and surface water which influence the aquifer water budget. Thus, evaluation of groundwater discharge from this karst spring can be affected by difficulties in performing measurements because of the insufficient knowledge about water transfer processes in the hydrological cycle and geometry of drainage conduits. The aim of this paper is to assess the interactions between karst aquifer feeding Pertuso Spring and Aniene River based on stream discharge measurements and water geochemical tracer data in order to validate an indirect method for karst spring discharge evaluation. As a matter of fact, in this paper, there are presented the results of the application of Magnesium as a reliable tracer of karst spring discharge. This indirect method is based on the elaboration of surface water discharge measurements in relationship with Mg2+ concentration values, determined as for groundwater, coming from Pertuso Spring, as for surface water sample, collected upstream and downstream of Pertuso Spring, along Aniene River streamflow. The application of Magnesium as an environmental tracer provides a means to evaluate discharge of Pertuso Spring, as it came up to be a marker of the mixing of surface water and groundwater. On the other hand, the Magnesium ion concentration provides information for the identification of groundwater flow systems and the main hydrogeochemical processes affecting the composition of water within the karst aquifers

Determining Pesticide and Nitrate Levels in Spring Water in Northwest Arkansas

Occurrences of pesticides in our nations ground water are on the rise. As states become aware of this problem and begin monitoring programs, incidence of contamination will probably increase. Since the problem of pesticides in groundwater is relatively new, little research has centered on the fate of pesticides after they reach the groundwater environment. In Northwest Arkansas efforts to monitor groundwater for pesticides have been small. Twenty-five springs in Northwest Arkansas were sampled in the fall of 1988, and spring of 1989. Analysis for atrazine, alachlor, metolachlor, diuron, and simazine in spring water was preformed using gas liquid chromatography and high performance liquid chromatography. No detectable residues of any of the selected pesticides were found. Northwest Arkansas is a leader in poultry production. Much of the manure from poultry houses is spread on the sourounding pastures. As this litter decomposes nitrates and phosphates are released. Nitrate and phosphate concentrations were also determined on water from the spring samples. No spring exceeded the EPA\u27s limit of 45 mg/L for nitrate in drinking water. The highest concentration for phosphate in any spring was 1.05 mg/L

Mutagenic impact on fish of runoff events in agricultural areas in south-west France

When heavy rainfall follows herbicide application, the intense surface runoff causes stream water contamination. Aquatic organisms are then briefly exposed to a complex mixture of contaminants. The aim of the present study is to investigate the genotoxic impact of such events on fish. A model fish, the Crucian carp (Carassius carassius) was exposed in controlled conditions, for 4 days, to water sampled daily in the Save River (France). The watershed of this stream is representative of agricultural areas in southwest France. Three hydrological conditions were compared: basal flow, winter flood, and spring flood. Chemical analysis of the water samples confirmed the higher contamination of the spring flood water,mainly explained by a peak of metolachlor. Genotoxicity was evaluated by micronucleus (MN) test and comet assay in peripheral erythrocytes. A significant increase in DNA breakdowns compared to controls was detected by the comet assay for all conditions. Exposure to spring flood water resulted in the highest damage induction. Moreover, induced chromosomal damage was only detected in this condition. In addition, fish were exposed, for 4 days, to an experimental mixture of 5 herbicides representative of the spring flood water contamination. Fish exhibited moderate DNA damage induction and no significant chromosomal damage. The mutagenicity induced by field-collected water is then suspected to be the result of numerous interactions between contaminants themselves and environmental factors, stressing the use of realistic exposure conditions. The results revealed a mutagenic impact of water contamination during the spring flood, emphasizing the need to consider these transient events in water quality monitoring programs

Lithology and palynology of cave floor sediment cores from Wakulla Spring, Wakulla County, Florida

Five short bottom sediment cores taken in Wakulla Spring Wakulla County, Florida, were described lithologically and sampled for palynological study. Four of the cores were recoveredfrom sediments at the spring cave entrance (130 feet water depth). One core was taken in a fossil vertebrate bone bed, 280 feet distance into the main spring cave at a water depth of 240 feet. Sediments in the cores are composed of alternating intervals of quartz sand and calcilitite, containing freshwater diatoms, freshwater mollusk shells and plant remains. The predominant pollen present in all cores consists of a periporate variety typical of the herb families Chenopodiaceae and Amaranthaceae. Arboreal flora, typical of the area surrounding the spring today, represent a very low percentage of thle pollen assemblage in the cores. Clustered Chenopod-Amaranth type pollen observed in one core suggest minimal transport prior to deposition, and indicate that the bottom sediments in the cave may be essentially In situ. An absence of exotic flora suggests a Quaternary age for the sediments. (PDF contains 11 pages.

Tillage Radish Seeding Rate Trial

Tillage radishes are being utilized by farmers as a new cover crop for their unique characteristics. Tillage radishes are quick at scavenging nitrogen, provide good ground cover, and break down very quickly in the spring to make way for spring planting and provide available nitrogen to the next crop. The plants winter kill, but the dead frozen plant material can still supress the earliest spring weeds from establishing. The holes left by decomposed roots allow more water to infiltrate the soil. Growing tillage radish as a cover crop in the northeast is new and best practices for success have yet to be established. Proper seeding rates must be determined to enable the crop to proivde quick ground cover and substantial root growth while minimizing planting costs

Tillage Radish Planting Date Trial Dr.

Farmers are interested in growing tillage radishes as they may potentially offer many environmental and economic benefits. Tillage radishes are quick at scavenging excess nitrogen, provide good ground cover, and break down very quickly in the spring to make way for spring planting. The plants winter kill, but the dead frozen plant material can still supress the earliest spring weeds from establishing. The roots themselves are known to drill through compacted soil layers as they grow and the holes left by decomposed roots the next spring may also allow more water to infiltrate into the soil. Although tillage radish may have many benefits, it must be planted earlier than our other cereal grain cover crops commonly used following corn silage. The goal of this project was to identify optimum planting dates for tillage radish in Vermont

Geochemistry of As-, F- and B-bearing waters in and around San Antonio de los Cobres, Argentina, and implications for drinking and irrigation water quality

Spring, stream and tap waters from in and around San Antonio de los Cobres, Salta, Argentina, were sampled to characterize their geochemical signatures, and to determine whether they pose a threat to human health and crops. The spring waters are typical of geothermal areas world-wide, in that they are Na-Cl waters with high concentrations of Astot, As(III), Li, B, HCO3, F and SiO2 (up to 9.49, 8.92, 13.1, 56.6, 1250, 7.30 and 57.2 mg L-1, respectively), and result from mixing of deep Na-Cl brines and meteoric HCO3-rich waters. Springs close to the town of San Antonio have higher concentrations of all elements, and are generally cooler, than springs in the Baños de Agua Caliente. Spring water chemistry is a result of mixing of deep Na-Cl brines and meteoric HCO3 waters. Stream waters are also Na-Cl type, and receive large inputs of all elements from the springs near San Antonio, but concentrations decrease downstream through the town of San Antonio due to mineral precipitation. The spring that is used as a drinking water source, and other springs in the area, have As, F and B concentrations in excess of WHO and Argentinian drinking water guidelines. Evaluation of the waters for irrigation purposes suggests that their high salinities and B concentrations may adversely affect crops. The waters may be improved for drinking and irrigation by dilution with cleaner meteoric waters, mineral precipitation or by use of commercial filters. Such recommendations could also be followed by other settlements that draw drinking and irrigation waters from geothermal sources

A computer simulation of the Volga River hydrological regime: a problem of water-retaining dam optimal location

We investigate of a special dam optimal location at the Volga river in area of the Akhtuba left sleeve beginning (7 \, km to the south of the Volga Hydroelectric Power Station dam). We claim that a new water-retaining dam can resolve the key problem of the Volga-Akhtuba floodplain related to insufficient water amount during the spring flooding due to the overregulation of the Lower Volga. By using a numerical integration of Saint-Vacant equations we study the water dynamics across the northern part of the Volga-Akhtuba floodplain with taking into account its actual topography. As the result we found an amount of water $V_A$ passing to the Akhtuba during spring period for a given water flow through the Volga Hydroelectric Power Station (so-called hydrograph which characterises the water flow per unit of time). By varying the location of the water-retaining dam $x_d, y_d$ we obtained various values of $V_A (x_d, y_d)$ as well as various flow spatial structure on the territory during the flood period. Gradient descent method provide us the dam coordinated with the maximum value of ${V_A}$. Such approach to the dam location choice let us to find the best solution, that the value $V_A$ increases by a factor of 2. Our analysis demonstrate a good potential of the numerical simulations in the field of hydraulic works.Comment: 7 pages, 3 figure

Water ice in the dark dune spots of Richardson crater on Mars

In this study we assess the presence, nature and properties of ices - in particular water ice - that occur within these spots using HIRISE and CRISM observations, as well as the LMD Global Climate Model. Our studies focus on Richardson crater (72{\deg}S, 179{\deg}E) and cover southern spring and summer (LS 175{\deg} - 17 341{\deg}). Three units have been identified of these spots: dark core, gray ring and bright halo. Each unit show characteristic changes as the season progress. In winter, the whole area is covered by CO2 ice with H2O ice contamination. Dark spots form during late winter and early spring. During spring, the dark spots are located in a 10 cm thick depression compared to the surrounding bright ice-rich layer. They are spectrally characterized by weak CO2 ice signatures that probably result from spatial mixing of CO2 ice rich and ice free regions within pixels, and from mixing of surface signatures due to aerosols scattering. The bright halo shaped by winds shows stronger CO2 absorptions than the average ice covered terrain, which is consistent with a formation process involving CO2 re-condensation. According to spectral, morphological and modeling considerations, the gray ring is composed of a thin layer of a few tens of {\mu}m of water ice. Two sources/processes could participate to the enrichment of water ice in the gray ring unit: (i) water ice condensation at the surface in early fall (prior to the condensation of a CO2 rich winter layer) or during winter time (due to cold trapping of the CO2 layer); (ii) ejection of dust grains surrounded by water ice by the geyser activity responsible for the dark spot. In any case, water ice remains longer in the gray ring unit after the complete sublimation of the CO2. Finally, we also looked for liquid water in the near-IR CRISM spectra using linear unmixing modeling but found no conclusive evidence for it