Chemical environments of submarine hydrothermal systems

Perhaps because black-smoker chimneys make tremendous subjects for magazine covers, the proposal that submarine hydrothermal systems were involved in the origin of life has caused many investigators to focus on the eye-catching hydrothermal vents. In much the same way that tourists rush to watch the spectacular eruptions of Old Faithful geyser with little regard for the hydrology of the Yellowstone basin, attention is focused on the spectacular, high-temperature hydrothermal vents to the near exclusion of the enormous underlying hydrothermal systems. Nevertheless, the magnitude and complexity of geologic structures, heat flow, and hydrologic parameters which characterize the geyser basins at Yellowstone also characterize submarine hydrothermal systems. However, in the submarine systems the scale can be considerably more vast. Like Old Faithful, submarine hydrothermal vents have a spectacular quality, but they are only one fascinating aspect of enormous geologic systems operating at seafloor spreading centers throughout all of the ocean basins. A critical study of the possible role of hydrothermal processes in the origin of life should include the full spectrum of probable environments. The goals of this chapter are to synthesize diverse information about the inorganic geochemistry of submarine hydrothermal systems, assemble a description of the fundamental physical and chemical attributes of these systems, and consider the implications of high-temperature, fluid-driven processes for organic synthesis. Information about submarine hydrothermal systems comes from many directions. Measurements made directly on venting fluids provide useful, but remarkably limited, clues about processes operating at depth. The oceanic crust has been drilled to approximately 2.0 km depth providing many other pieces of information, but drilling technology has not allowed the bore holes and core samples to reach the maximum depths to which aqueous fluids circulate in oceanic crust. Such determinations rely on studies of pieces of deep oceanic crust uplifted by tectonic forces such as along the Southwest Indian Ridge, or more complete sections of oceanic crust called ophiolite sequences which are presently exposed on continents owing to tectonic emplacement. Much of what is thought to happen in submarine hydrothermal systems is inferred from studies of ophiolite sequences, and especially from the better-exposed ophiolites in Oman, Cyprus and North America. The focus of much that follows is on a few general features: pressure, temperature, oxidation states, fluid composition and mineral alteration, because these features will control whether organic synthesis can occur in hydrothermal systems

Hydrothermal organic synthesis experiments

The serious scientific debate about spontaneous generation which raged for centuries reached a climax in the nineteenth century with the work of Spallanzani, Schwann, Tyndall, and Pasteur. These investigators demonstrated that spontaneous generation from dead organic matter does not occur. Although no aspects of these experiments addressed the issue of whether organic compounds could be synthesized abiotically, the impact of the experiments was great enough to cause many investigators to assume that life and its organic compounds were somehow fundamentally different than inorganic compounds. Meanwhile, other nineteenth-century investigators were showing that organic compounds could indeed be synthesized from inorganic compounds. In 1828 Friedrich Wohler synthesized urea in an attempt to form ammonium cyanate by heating a solution containing ammonia and cyanic acid. This experiment is generally recognized to be the first to bridge the artificial gap between organic and inorganic chemistry, but it also showed the usefulness of heat in organic synthesis. Not only does an increase in temperature enhance the rate of urea synthesis, but Walker and Hambly showed that equilibrium between urea and ammonium cyanate was attainable and reversible at 100 C. Wohler's synthesis of urea, and subsequent syntheses of organic compounds from inorganic compounds over the next several decades dealt serious blows to the 'vital force' concept which held that: (1) organic compounds owe their formation to the action of a special force in living organisms; and (2) forces which determine the behavior of inorganic compounds play no part in living systems. Nevertheless, such progress was overshadowed by Pasteur's refutation of spontaneous generation which nearly extinguished experimental investigations into the origins of life for several decades. Vitalism was dealt a deadly blow in the 1950's with Miller's famous spark-discharge experiments which were undertaken in the framework of the Oparin and Haldane hypotheses concerning the origin of life. These hypotheses were constructed on some basic assumptions which included a reduced atmosphere, and a low surface temperature for the early Earth. These ideas meshed well with the prevailing hypothesis of the 1940's and 50's that the Earth had formed through heterogeneous accretion of dust from a condensing solar nebula. Miller's experiments were extremely successful, and were followed by numerous other experiments by various investigators who employed a wide variety of energy sources for abiotic synthesis including spark discharges, ultra-violet radiation, heat, shock waves, plasmas, gamma rays, and other forms of energy. The conclusion reached from this body of work is that energy inputs can drive organic synthesis from a variety of inorganic starting materials

The Constitutional Convention and Court Merger in New York State

In November 2017, voters in New York, for the first time in twenty years, will be asked to decide whether there “[s]hall be a convention to revise the constitution and amend the same?” If it is decided by the electorate to call a convention, “delegates will be elected in November 2018, and the convention will convene in April 2019.” One of the significant goals of a convention would be the achievement of court merger in the Empire State. The purpose of this perspective is to discuss the pros and cons of a constitutional convention with an emphasis on court merger

The Information Metric on the moduli space of instantons with global symmetries

In this note we revisit Hitchin's prescription \cite{Hitchin} of the Fisher metric as a natural measure on the moduli space of instantons that encodes the space-time symmetries of a classical field theory. Motivated by the idea of the moduli space of supersymmetric instantons as an emergent space in the sense of the gauge/gravity duality, we extend the prescription to encode also global symmetries of the underlying theory. We exemplify our construction with the instanton solution of the $\mathbb{CP}^{N}$ sigma model on $\mathbb{R}^{2}$.Comment: 5 pages, no figures, sorr

A Neural Network Method for Land Use Change Classification, with Application to the Nile River Delta

Detecting and monitoring changes in conditions at the Earth's surface are essential for understanding human impact on the environment and for assessing the sustainability of development. In the next decade, NASA will gather high-resolution multi-spectral and multi-temporal data, which could be used for analyzing long-term changes, provided that available methods can keep pace with the accelerating flow of information. This paper introduces an automated technique for change identification, based on the ARTMAP neural network. This system overcomes some of the limitations of traditional change detection methods, and also produces a measure of confidence in classification accuracy. Landsat thematic mapper (TM) imagery of the Nile River delta provides a testbed for land use change classification methods. This dataset consists of a sequence of ten images acquired between 1984 and 1993 at various times of year. Field observations and photo interpretations have identified 358 sites as belonging to eight classes, three of which represent changes in land use over the ten-year period. Aparticular challenge posed by this database is the unequal representation of various land use categories: three classes, urban, agriculture in delta, and other, comprise 95% of pixels in labeled sites. A two-step sampling method enables unbiased training of the neural network system across sites.National Science Foundation (SBR 95-13889); Office of Naval Research (N00014-95-1-409, N00014-95-0657); Air Force Office of Scientific Research (F49620-01-1-0397, F49620-01-1-042