Comparison of Mixed H 2 H∞ with Regional Pole Placement Control and H 2 Optimal Control for the Design of Steam Condenser

This paper investigates the comparison between mixed H 2 /H∞ with regional pole placement control and H 2 optimal control for the design of steam condenser. The comparison have been made for a step change in the steam condenser pressure set point for a step change of 10 & 23 seconds using MATLAB/Simulink environment for the steam condenser with mixed H 2 /H∞ with regional pole placement controller, steam condenser with H 2 optimal controller and steam condenser without controller. The steam condenser with mixed H 2 /H∞ with regional pole placement controller presented excellent and superior dynamic performance in response to the two step changes and an improvement in settling time. The overall simulation results demonstrated that the steam condenser with mixed H 2 /H∞ with regional pole placement controller can be an efficient alternative to the steam condenser with H 2 optimal controller for the steam condenser

Heavy oil production with energy effective steam-assisted gravity drainage

In reservoirs with extra heavy oil and bitumen, thermal methods are used to reduce the viscosity, in order to extract the oil. Steam-assisted gravity drainage (SAGD) is a thermal method where continuous steam injection is used. In this method, two horizontal wells are placed in parallel. The upper well injects steam and the lower well produces oil and condensed water. The continuous steam injection creates a chamber with uniform temperature. Heavy oil and bitumen reserves in Western Canada, which exceed 175 billion barrels, are becoming increasingly important petroleum sources due to the technical success of the SAGD processes. This study includes Computational fluid dynamics (CFD) modelling and simulations of a horizontal oil well with SAGD. The simulations are performed with inflow control devices (ICD) and autonomous inflow control valves (AICV) completion. In the SAGD processes, it is important that the residence time for steam in the reservoir is high enough to ensure that all the injected steam condenses in the reservoir to reduce the amount of steam injection and thereby making the SAGD process more energy effective. The simulations are carried out with ICD completion to delay the steam breakthrough and with AICV completion to prevent breakthrough of steam and water to the well. The numerical results showed that a most of the steam was produced together with the oil when ICD completion was used. AICV was able to close for steam and water, and the steam was thereby forced to condense in the reservoir, resulting in better utilization of the condensation energy

Optimal operations and resilient investments in steam networks

Steam is a key energy vector for industrial sites, most commonly used for process heating and cooling, cogeneration of heat and mechanical power as a motive fluid or for stripping. Steam networks are used to carry steam from producers to consumers and between pressure levels through letdowns and steam turbines. The steam producers (boilers, heat and power cogeneration units, heat exchangers, chemical reactors) should be sized to supply the consumers at nominal operating conditions as well as peak demand. First, this paper proposes an Mixed Integer Linear Programing formulation to optimize the operations of steam networks in normal operating conditions and exceptional demand (when operating reserves fall to zero), through the introduction of load shedding. Optimization of investments based on operational and investment costs are included in the formulation. Though rare, boiler failures can have a heavy impact on steam network operations and costs, leading to undercapacity and unit shutdowns. A method is therefore proposed to simulate steam network operations when facing boiler failures. Key performance indicators are introduced to quantify the network’s resilience. The proposed methods are applied and demonstrated in an industrial case study using industrial data. The results indicate the importance of oversizing key steam producing equipments and the value of industrial symbiosis to increase industrial site resilience

Effect of steam addition on the flow field and NOx emissions for Jet-A in an aircraft combustor

The steam injection technology for aircraft engines is gaining rising importance because of the strong limitations imposed by the legislation for NOx reduction in airports. In order to investigate the impact of steam addition on combustion and NOx emissions, an integrated performance-CFD-chemical reactor network (CRN) methodology was developed. The CFD results showed steam addition reduced the high temperature size and the radical pool moved downstream. Then different post-processing techniques are employed and CRN is generated to predict NOx emissions. This network consists of 14 chemical reactor elements and the results were in close agreement with the ICAO databank. The established CRN model was then used for steam addition study and the results showed under air/steam mixture atmosphere, high steam content could push the NOx formation region to the post-flame zone and a large amount of the NOx emission could be reduced when the steam mass fraction is quite high

The potential of fractional order distributed MPC applied to steam/water loop in large scale ships

The steam/water loop is a crucial part of a steam power plant. However, satisfying control performance is difficult to obtain due to the frequent disturbance and load fluctuation. A fractional order model predictive control was studied in this paper to improve the control performance of the steam/water loop. Firstly, the dynamic of the steam/water loop was introduced in large-scale ships. Then, the model predictive control with an extended prediction self adaptive controller framework was designed for the steam/water loop with a distributed scheme. Instead of an integer cost function, a fractional order cost function was applied in the model predictive control optimization step. The superiority of the fractional order model predictive control was validated with reference tracking and load fluctuation experiments

Development of a New Method of Storage and Maximum Separation of Chlorophils From Chlorophylcontaining Vegetables at Reception of Healthfull Nanoproducts

The aim of the work is the development of a new way of deep processing of chlorophyll-containing vegetables that gives a possibility not only to preserve chlorophylls a and b and other biologically active substances (BAS) of raw materials, but also to transform hidden bound (inactive) forms of chlorophyll in the free easy-digestible form at getting steam-thermally processed semi-products and healthy food products in the nanoform.For achieving the aim, the complex effect of steam-thermal processing and mechanolysis at fine-dyspersed comminution using the new equipment was applied as an innovation for thermal processing and comminution.There was developed the new method of getting healthy products of chlorophyll-containing vegetables (broccoli, spinach, Brussels cabbage, green leguminous haricot bean), steam-thermally processed (by hot steam) in the steam-convectional stove and fine-dyspersed with high contents of chlorophylls and other BAS and prebiotics. The method is based on the complex effect of processes of thermodestruction, mechanodestruction and non-enzymatic catalysis on raw materials at fine-dyspersed comminution. It was demonstrated, that at steam thermal processing of chlorophyll-containing vegetables (CCV) in the steam-convectomat during 5 minutes, there takes place not only preservation of chlorophylls a and b, but more full separation (in 1,33…1,4 times) from the hidden (bound) form, comparing with fresh vegetables. There was elucidated the mechanism of this process. The more full extraction of hidden forms of β-carotene (2 times more than in fresh CCV) takes place in parallel.The essentially more effect of transforming hidden forms was revealed at fine-dyspersed comminution of steam-thermally processed CCV. It was demonstrated, that thermally processed nanoproducts of CCV contain 2…2,1 more chlorophylls a and b, 2,0…3,3 times more carotenoids in the bound form than fresh vegetables.The quality of obtained new types of fine-dyspersated steam-thermally processed green products as puree and soups-purees of CCV exceeds one of known analogues by contents of chlorophylls a and b, β-carotene and other BAS, which are in nanosize easy-digestible form.Using new types of fine-dyspersated purees of CCV, there was developed the new green line of healthy nanoproducts: soups-purees, nanodrinks, nanosorbets, sauces-dressings, sauces-deeps, ice-cream, snacks and so on. It was demonstrated, that new products exceed existing analogues by BAS content (chlorophylls, β-carotene, L-ascorbic acid, phenol compounds)

Gasification of Pine Wood Chips with Air-Steam in Fluidized Bed

Tato práce studovala vliv použití vzduchu a páry jako zplynovacího činidla ve zkapalňovacím generátoru plynu na vlastnosti vyprodukovaného plynu (oxid uhelnatý, vodík, obsah dehtu a nízká výhřevnost). Tato studie byla založena na experimentech které byly provedeny ve fluidním generátoru plynu Biofluid 100 v laboratoři Energetického ústavu technologické univerzity Brno s použitím páry jako zplynovacího činidla a borovicového dřeva jako výchozí suroviny. Cílem této dizertační práce je stanovit nejlepší provozní parametry systému při užití vodní páry a vzduchu ve zplynovacím zařízení biofluid 100, při kterých se dosáhne nejvyšší kvality plynu. K dosažení tohoto cíle bylo provedeno mnoho experimentů studujících účinky teploty reaktoru(T101), poměru páry a biomasy (S/B) poměru páry a vzduchu (S/A), teploty dodávané páry (Tf1), ekvivalentního poměru ER,ve složení vyprodukovaném plynu, výhřevnost, výtěžnost plynu, efektivnost přeměny uhlíku a účinnost zplynovače. Výsledky experimentů ukázaly, že zvýšení teploty reaktoru vede ke zvýšení obsahu vodíku a oxidu uhelnatého, výhřevnosti, výtěžnosti plynu, efektivnosti přeměny uhlíku, efektivnosti zplynovače a ke snížení obsahu dehtu. Příliš vysoká teplota reaktoru ale snižuje výhřevnost plynu. Dodáváním páry se zvýšila kvalita plynu, vyšší H_2,LHV a nižší obsah dehtu. Přesto ale nadměrné množství páry snižuje zplyňovací teplotu a tím i kvalitu plynu. Poměr páry a biomasy při kterém se dosáhne nejlepší kvality plynu se zvýší s teplotou reaktoru. Bylo zjištěno, že kdykoli byla teplota páry (Tf1) vyšší, byl plyn více kvalitní, ale zvyšování teploty páry také zvyšuje ekonomické náklady na vyprodukovaný plyn což se při masové produkci plynu musí brát v úvahu. Efekt ekvivalentního poměru ER, byl studován postupným zvyšováním, bylo zjištěno, že nejlepší ekvivalentní poměr pro dosažení nejvyšší kvality plynu byl kolem 0.29, při ER > 0.29 byl obsah hořlavého plynu snížen a to vedlo ke snížení kvality plynu. Obsah dehtu se snižuje jak zvýšením teploty reaktoru tak poměrem páry k biomase. Podle výsledků experimentů a diskuze, bylo zjištěno, že při použití směsi páry a vzduchu se kvalita plynu zvýší, parametry pro dosažení nejvyšší kvality vyprodukovaného plynu při experimentálních podmínkách jsou: T101 =829 S/B=0.67((kg steam)/(kg biomass)) ,S/A=0.67((kg steam)/(kg air)) , ER= 0.29 and a Tf1 je nejvyšší možná teplota,při které se vodík zvýší z 10.48 na 19,68% a výhřevnost z 3.99 na 5.52(MJ/m^3 ) a obsah dehtu z 1964(mg/m^3 ) na 1046(mg/m^3 ) zvýšením z 0 na 0.67 při T101=829 .This work has been studied the impact of using of air-steam as gasification agent in fluidized bed gasifier on produced gas properties (Carbon monoxide, Hydrogen,tar content and low heating value . This study has been based on the experiments which have been done in fluidized bed gasifier called Biofluid 100, where exists in lab of the Institute of Power Engineering, Brno University of Technology, by using air-steam as agent of gasifier and pine wood chips as the feedstock. The aim of this thesis is to determine the best operating parameters of system air- steam gasification in biofloud 100 which achive the best gas quality. To accomplish this task , many experiments have been performed to studied the effect of reactor temperature(T101), steam to biomass ratio (S/B), steam to air ratio (S/A) , temperature of provided steam (Tf1) and equivalence ratio (ER)on produced gas composition , low heating value(LHV),gas yield ,carbon conversion efficiency and gasifier efficiency. The results of experiments have been shown , that the increase the temperature of reactor (T101) lead to increase hydrogen content , carbon monoxide content ,low heating value,gas yield , carbon conversion efficiency ,gasifier efficiency and reduce the tar content, but too high reactor temperature lowered low heating value of gas. By providing steam,the gas quality (H_2,LHVand tar content) has been imroved ,however excessive steam has been lowered gasification temperature and thus reduced gas quality. The ratio of steam to biomass, which achieve the best gas quality has been increased by reactor temperature. It has been found, that whenever steam temperature (Tf1)was higher , whenever the gas produced more quality, but the increase of steam temperature will increase the economic cost of the product gas,which must take into account when gas production widely. The effect of equivalence ratio(ER) has been studied with increase S/B , it has been found that the best value of equivalence ratio was around 0.29 which achieved the best quality of produced gas , where when ER > 0.29 the combustible gases content have been decreased so it led to lower the gas quality . Tar content decreases by increasing each of reactor temperature (T101) and steam to biomass ratio . According to the results of the experiments and discussion, it has been found, that by using the mixture of steam and air ,the gas quality will be improved ,and the parameters, which will achieve the best quality of the produced gas at experimental conditions are: T101 =829 S/B=0.67((kg steam)/(kg biomass)) ,S/A=0.57((kg steam)/(kg air)) , ER= 0.29 and Tf1 is the highest possible temperature, where hydrogen increased from 10.48 to 19,68 % and Low heating value from 3.99 to 5.52(MJ/m^3 ) and tar decreased from 1964 to 1046 (mg/m^3 ) by increasing S/B from 0 to 0.67 at T101=829 .

THERMODYNAMIC ANALYSIS OF SYNTHESIS GAS AND HIGHER HYDROCARBONS PRODUCTION FROM METHANE

This chapter focused on thermodynamic chemical equilibrium analysis using method of direct minimization of Gibbs free energy for all possible methane reactions with oxygen (partial oxidation of methane), carbon dioxide (CO2 reforming of methane), steam (steam reforming of methane), and autothermal reforming. Effects of feed ratios (methane to oxygen, carbon dioxide, and/or steam feed ratio), reaction temperature, and system pressure on equilibrium composition, conversion, and yield were studied. In addition, operating regions of carbon and no carbon formation were also considered at various reaction temperatures and feed ratios in the equilibrium system. It was found that the reaction temperature above 1100 K and CH4/CO2 ratio unity were favorable for synthesis gas production for methane – carbon dioxide reaction. The Carbon Dioxide Oxidative Coupling of Methane reaction to produce ethane and ethylene is less favorable thermodynamically. In addition, steam reforming of methane is the most suitable for hydrogen production from methane with low coke formation from thermodynamic point of view