Theoretical and Experimental Studies of Schottky Diodes That Use Aligned Arrays of Single Walled Carbon Nanotubes

We present theoretical and experimental studies of Schottky diodes that use aligned arrays of single walled carbon nanotubes. A simple physical model, taking into account the basic physics of current rectification, can adequately describe the single-tube and array devices. We show that for as grown array diodes, the rectification ratio, defined by the maximum-to-minimum-current-ratio, is low due to the presence of m-SWNT shunts. These tubes can be eliminated in a single voltage sweep resulting in a high rectification array device. Further analysis also shows that the channel resistance, and not the intrinsic nanotube diode properties, limits the rectification in devices with channel length up to ten micrometer.Comment: Nano Research, 2010, accepte

Thermal Rectification In Asymmetric Graphene Ribbons

In this paper, heat flux in graphene nano ribbons has been studied by using molecular dynamics simulations. It is found that the heat flux runs preferentially along the direction of decreasing width, which demonstrates significant thermal rectification effect in the asymmetric graphene ribbons. The dependence of rectification ratio on the vertex angle and the length are also discussed. Compared to the carbon nanotube based one-dimensional thermal rectifier, graphene nano ribbons have much higher rectification ratio even in large scale. Our results demonstrate that asymmetric graphene ribbon might be a promising structure for practical thermal (phononics) device

Switching and Rectification of a Single Light-sensitive Diarylethene Molecule Sandwiched between Graphene Nanoribbons

The 'open' and 'closed' isomers of the diarylethene molecule that can be converted between each other upon photo-excitation are found to have drastically different current-voltage characteristics when sandwiched between two graphene nanoribbons (GNRs). More importantly, when one GNR is metallic and another one is semiconducting, strong rectification behavior of the 'closed' diarylethene isomer with the rectification ratio >10^3 is observed. The surprisingly high rectification ratio originates from the band gap of GNR and the bias-dependent variation of the lowest unoccupied molecular orbital (LUMO) of the diarylethene molecule, the combination of which completely shuts off the current at positive biases. Results presented in this paper may form the basis for a new class of molecular electronic devices.Comment: The Journal of Chemical Physics 135 (2011

Current rectification by asymmetric molecules: An ab initio study

We study current rectification effect in an asymmetric molecule HOOC-C$_6$H$_4$-(CH$_2$)$_n$ sandwiched between two Aluminum electrodes using an {\sl ab initio} nonequilibrium Green function method. The conductance of the system decreases exponentially with the increasing number $n$ of CH$_2$. The phenomenon of current rectification is observed such that a very small current appears at negative bias and a sharp negative differential resistance at a critical positive bias when $n\ge 2$. The rectification effect arises from the asymmetric structure of the molecule and the molecule-electrode couplings. A significant rectification ratio of $\sim$38 can be achieved when $n=5$.Comment: to appear in J. Chem. Phy

Heat conduction in graphene flakes with inhomogeneous mass interface

Using nonequilibrium molecular dynamics simulations, we study the heat conduction in graphene flakes composed by two regions. One region is mass-loaded and the other one is intact. It is found that the mass interface between the two regions greatly decreases the thermal conductivity, but it would not bring thermal rectification effect. The dependence of thermal conductivity upon the heat flux and the mass difference ratio are studied to confirm the generality of the result. The interfacial scattering of solitons is studied to explain the absence of rectification effect.Comment: 5 pages, 4 figure

A simple radiative thermal diode

We present a thermal rectification device concept based on far-field radiative exchange between two selective emitters. Rectification is achieved due to the fact that one of the selective emitters radiative properties are independent on temperature whereas the other emitter properties are strongly temperature dependent. A simple device constituted by two multilayer samples made of metallic (Au) and semiconductor (Si and HDSi) thin films is proposed. This device shows a rectification up to 70% with a temperature difference \Delta T = 200 K, a rectification ratio that has never been achieved so far with radiation-based rectifiers. Further optimization would allow larger rectification values. Presented results might be useful for energy conversion devices, smart radiative coolers / insulators engineering and thermal modulators development.Comment: 14 pages, 4 figure

Radiative thermal rectification using superconducting materials

Thermal rectification phenomenon is a manifestation of an asymmetry in the heat flux when the temperature difference between two interacting thermal reservoirs is reversed. In this letter, we present a far-field radiative thermal rectifier based on high temperature superconducting materials with a rectification ratio up to $80$. This value is among the highest reported in literature. Two configurations are examined : a superconductor (Tl$_2$Ba$_2$CaCu$_2$O$_8$) exchanging heat with 1) a black body and 2) another superconductor, YBa$_2$Cu$_3$O$_7$ in this case. The first configuration shows a higher maximal rectification ratio. Besides, we show that the two superconductors rectifier exhibits different rectification regimes depending on the choice of the reference temperature, i.e the temperature of the thermostat. Presented results might be useful for energy conversion devices, efficient cryogenic radiative insulators engineering and thermal logical circuits development.Comment: 5 pages, 4 figures, submitted to Applied Physics Letter