Direct observation via in situ heated stage EBSD analysis of recrystallization of phosphorous deoxidised copper in unstrained and strained conditions

Recrystallization of phosphorous deoxidised copper used for strength critical applications at elevated temperatures was investigated by means of in situ heated stage EBSD analysis using a Gatan Murano heated stage mounted within a Carl Zeiss Sigma FEGSEM electron microscope. The influence of applied strain as the result of deformation within a Nakajima test as an analogue for industrial forming on the recrystallization temperature was investigated, the impact of increased heating rates on microstructural evolution was also investigated. Inverse pole figure plots combined with regions of reduction in local misorientations and variations in geometrically necessary dislocations were used to establish the point of recrystallization and the recrystallized fraction of the material. Recrystallization was observed to occur at temperatures as low as 130 °C in highly strained samples compared to around 300 °C within the annealed samples dependent upon heating rate. Increased heating rates were observed to produce a finer final grain structure but had little effect on presence of 60° grain twins, which was influenced more by initial material condition

A continuum model accounting for the effect of the initial and evolving microstructure on the evolution of dynamic recrystallization

Laser assisted forming is a process which is increasingly being adopted by the industry. Application of heat by a laser to austenitic stainless steel (ASS) sheet provides local control over formability and strength of the material. The hot forming behavior of ASS is characterized by significant dynamic recovery and dynamic recrystallization. These two processes lead to a softening stress-strain response and have a significant impact on the microstructure of the material. Most of the research performed on hot forming of ASS focuses on dynamic recrystallization and then specifically on the behavior of the annealed state, consisting of relatively large equiaxed austenite grains. However, in industry it is common to use cold rolled ASS sheet which is a mixture of austenite and martensite. Application of a laser heat treatment to the cold rolled grades of ASS induces a socalled ‘reverse’ transformation of martensite to austenite which, depending on the exact time-temperature combinations, leads to an austenite grain size in the range of nanoto micrometer. It is known from experiments that the effect of initial grain size on dynamic recrystallization is significant, especially on the initial stages of recrystallization. Therefore any continuum model capable of describing hot forming of cold rolled ASS should include the effect of the initial grain size. In this work a physically based continuum model for dynamic recrystallization is presented which accounts for the effect of the initial and evolving grain size on the evolution of dynamic recrystallization. It is shown that the initial grain size can be accounted for by incorporating its effect on the availability of preferred nucleation sites, i.e. grain edges. The new model is compared to experimental results and it is shown that the model correctly predicts accelerated recrystallization with decrease in grain size and that there is a weak dependence of the dynamically recrystallized grain size on the initial grain size. Furthermore predicted recrystallized grain sizes are in good agreement with the experimentally measured values

Characterization of the austenite recrystallization by comparing double deformation and stress relaxation tests

A high amount of deformation below the non-recrystallization temperature (T-nr) is a common industrial practice to achieve a good combination of toughness and strength in microalloyed steels. To combine the industrially relevant optimum combination of high productivity and product quality, an accurate knowledge of T-nr and the recrystallization kinetics is required. Although a lot of literature data is available on the recrystallization behaviour of microalloyed steels, correlations are often difficult to be made due to the effect of different experimental setups, types of analysis and test schedules that are used to obtain this data. Although this would significantly improve the knowledge about these steels, so far, no systematic comparison has been presented in literature to correlate the different techniques and methods. In this study, different hot rolling simulation techniques, testing schedules and types of analysis were used to determine the recrystallization kinetics of a microalloyed steel. On the one hand, good agreement was found between the results from different test equipment for the double deformations tests. On the other hand, stress relaxation tests showed accelerated kinetics and appeared to be less effective

Control of the Austenite recrystallization in Niobium Microalloyed steels

The use of heavy gauge steel sheets for structural applications very often requires a combination of high yield strength and adequate toughness. The most cost effective way to realize a high yield strength and a high ductility in a low alloyed steel is grain refinement. In industrial practice, this refinement is realized by controlled processing. This process consists of controlling the slab reheating temperature, applying a large amount of hot deformation below the nonrecrystallization temperature (T-nr) and accelerated cooling. A better knowledge of T-nr could optimize the process and the best mechanical properties could be reached against the lowest cost. T-nr can be raised by the addition of microalloying elements such as Nb. Nb can retard the static recrystallization of austenite at low temperatures either by solute drag or by precipitation pinning. In this study, the recrystallization behavior of five Nb-microalloyed model alloys with various Nb contents, was evaluated by double hit compression tests. Further, the precipitation state of the materials was investigated experimentally by Inductively Couples Mass Spectroscopy and X-ray Diffraction. The construction of recrystallization-time-temperature diagrams and precipitation-time-temperature diagrams showed that both mechanisms, i.e. recrystallization and precipitation, strongly influence each other

Testing the impact of diagenesis on the delta O-18 and delta C-13 of benthic foraminiferal calcite from a sediment burial depth transect in the equatorial Pacific

Stable oxygen and carbon isotope (δ18O and δ13C) values measured in foraminiferal calcite are one of the primary tools used in paleoceanography. Diagenetic recrystallisation of foraminiferal calcite can act to reset primary isotopic values but its effects are typically poorly quantified. Here we test the impact of early stage diagenesis on stable isotope records generated from a suite of drill sites in the equatorial Pacific Ocean recovered during Ocean Drilling Program (ODP) Leg 199 and Integrated Ocean Drilling Program (IODP) Expedition 320. Our selected sites form paleowater- and burial-depth transects, with excellent stratigraphic control allowing us to confidently correlate our records. We observe large inter-site differences in the preservation state of benthic foraminiferal calcite, implying very different recrystallisation histories, but negligible inter-site offsets in benthic δ18O and δ13C values. We infer that diagenetic alteration of benthic foraminiferal calcite (in sedimentary oozes) must predominantly occur at shallow burial depths (<100 m) where offsets in both the temperature and isotopic composition of waters in which the foraminifera calcified and pore-waters in which diagenesis occurs are small. Our results suggest that even extensive recrystallisation of benthic foraminiferal calcite results in minimal shifts from primary δ18O and δ13C values. This finding supports the long-held suspicion that diagenetic alteration of foraminiferal calcite is less problematic in benthic than in planktic foraminifera and that in deep–sea sediments routinely employed for palaeoceanographic studies benthic foraminifera are robust recorders of stable isotope values in the fossil record

Monte Carlo simulation of recrystallization

A Monte Carlo computer simulation technique, in which a continuum system is modeled employing a discrete lattice, has been applied to the problem of recrystallization. Primary recrystallization is modeled under conditions where the degree of stored energy is varied and nucleation occurs homogeneously (without regard for position in the microstructure). The nucleation rate is chosen as site saturated. Temporal evolution of the simulated microstructures is analyzed to provide the time dependence of the recrystallized volume fraction and grain sizes. The recrystallized volume fraction shows sigmoidal variations with time. The data are approximately fit by the Johnson-Mehl-Avrami equation with the expected exponents, however significant deviations are observed for both small and large recrystallized volume fractions. Under constant rate nucleation conditions, the propensity for irregular grain shapes is decreased and the density of two sided grains increases