Ligand Substitution Dynamics

Substitution of a ligand in an inner sphere complex by an outside group is the most fundamental reaction in metal ion chemistr

Black Hole Formation in Fuzzy Sphere Collapse

We study the collapse of a fuzzy sphere, that is a spherical membrane built out of D0-branes, in the BFSS model. At weak coupling, as the sphere shrinks, open strings are produced. If the initial radius is large then open string production is not important and the sphere behaves classically. At intermediate initial radius the back-reaction from open string production is important but the fuzzy sphere retains its identity. At small initial radius the sphere collapses to form a black hole. The crossover between the later two regimes is smooth and occurs at the correspondence point of Horowitz and Polchinski.Comment: 27 pages, LaTeX, 2 figures. v2: additional reference

Transition from rotating waves to modulated rotating waves on the sphere

We study non-resonant and resonant Hopf bifurcation of a rotating wave in SO(3)-equivariant reaction-diffusion systems on a sphere. We obtained reduced differential equations on so(3), the characterization of modulated rotating waves obtained by Hopf bifurcation of a rotating wave, as well as results regarding the resonant case. Our main tools are the equivariant center manifold reduction and the theory of Lie groups and Lie algebras, especially for the group SO(3) of all rigid rotations on a sphere

Forced Symmetry Breaking from SO(3) to SO(2) for Rotating Waves on the Sphere

We consider a small SO(2)-equivariant perturbation of a reaction-diffusion system on the sphere, which is equivariant with respect to the group SO(3) of all rigid rotations. We consider a normally hyperbolic SO(3)-group orbit of a rotating wave on the sphere that persists to a normally hyperbolic SO(2)-invariant manifold $M(\epsilon)$. We investigate the effects of this forced symmetry breaking by studying the perturbed dynamics induced on $M(\epsilon)$ by the above reaction-diffusion system. We prove that depending on the frequency vectors of the rotating waves that form the relative equilibrium SO(3)u_{0}, these rotating waves will give SO(2)-orbits of rotating waves or SO(2)-orbits of modulated rotating waves (if some transversality conditions hold). The orbital stability of these solutions is established as well. Our main tools are the orbit space reduction, Poincare map and implicit function theorem

Swimming of a uniform deformable sphere in a viscous incompressible fluid with inertia

The swimming of a deformable uniform sphere is studied in second order perturbation theory in the amplitude of the stroke. The effect of the first order reaction force on the first order center of mass velocity is calculated in linear response theory by use of Newton's equation of motion. The response is characterized by a dipolar admittance, which is shown to be proportional to the translational admittance. As a consequence the mean swimming velocity, calculated in second order perturbation theory, depends on the added mass of the sphere. The mean swimming velocity and the mean rate of dissipation are calculated for several selected strokes.Comment: 20 pages, 15 figure