A study of Pt-/alpha-Fe2O3 nanocomposites by XPS

alpha-Fe2O3 matrices were deposited on Fluorine-doped Tin Oxide (FTO) substrates by Plasma Enhanced- Chemical Vapor Deposition (PE-CVD) from Fe(hfa)_2TMEDA (hfa = 1,1,1,5,5,5-hexafluoro-2,4-pentanedionate; TMEDA = N,N,N’,N’-tetramethylethylenediamine). The obtained nanosystems were subsequently functionalized by platinum nanoparticles (NPs) via Radio Frequency (RF)-sputtering, exposing samples either to a pre- or post-sputtering thermal treatment at 650°C for one hour in air. Interestingly, Pt oxidation state in the final composite systems strongly depended on the adopted processing conditions. In this work, a detailed X-ray Photoelectron Spectroscopy (XPS) analysis was carried out in order to investigate the material chemical composition, with particular regard to the relative Pt(0)/Pt(II)/Pt(IV) content. The obtained results evidenced that, when annealing is performed prior to sputtering, only PtO and PtO2 are revealed in the final Pt/alpha-Fe2O3 nanocomposite. In a different way, annealing after sputtering results in the co-presence of Pt(0), Pt(II) and Pt(IV) species, the former arising from the thermal decomposition of PtO2 to metallic platinum

New advances in aircraft MRO services: data mining enhancement

Aircraft Maintenance, Repair and Overhaul (MRO) agencies rely largely on row-data based quotation systems to select the best suppliers for the customers (airlines). The data quantity and quality becomes a key issue to determining the success of an MRO job, since we need to ensure we achieve cost and quality benchmarks. This paper introduces a data mining approach to create an MRO quotation system that enhances the data quantity and data quality, and enables significantly more precise MRO job quotations. Regular Expression was utilized to analyse descriptive textual feedback (i.e. engineer’s reports) in order to extract more referable highly normalised data for job quotation. A text mining based key influencer analysis function enables the user to proactively select sub-parts, defects and possible solutions to make queries more accurate. Implementation results show that system data would improve cost quotation in 40% of MRO jobs, would reduce service cost without causing a drop in service quality

Arithmetic--some drill aspects

Thesis (M.A.)--Boston Universit

Coulomb Blockade in Hierarchical Quantum Hall Droplets

The degeneracy of energy levels in a quantum dot of Hall fluid, leading to conductance peaks, can be readily derived from the partition functions of conformal field theory. Their complete expressions can be found for Hall states with both Abelian and non-Abelian statistics, upon adapting known results for the annulus geometry. We analyze the Abelian states with hierarchical filling fractions, \nu=m/(mp \pm 1), and find a non trivial pattern of conductance peaks. In particular, each one of them occurs with a characteristic multiplicity, that is due to the extended symmetry of the m-folded edge. Experimental tests of the multiplicity can shed more light on the dynamics of this composite edge.Comment: 8 pages; v2: published version; effects of level multiplicities not well understood, see arXiv:0909.3588 for the correct analysi

Factors affecting the establishment of Leptospermum scoparium J.R. et G. Forst. (manuka) : a thesis presented in partial fulfillment of the requirements for the degree of Master of Agricultural Science at Massey University

L. scoparium is one of New Zealand's most important weeds of unploughable infertile hill country. The plant is an indigenous shrub, characteristic of the early stages of succession to forest in a wide range of habitats (Cockayne, 1928). In the eight years prior to 1959/60 nearly 40,000 acres of unimproved grassland reverted to scrub, fern and second growth each year. L. scoparium is one of the most important components of the scrub, fern and second growth category. By 1959/60 the total area of reverted land in New Zealand was 5.7 million acres of which 3.65 million were in the North Island. (Rigg, 1962). Control of L. scoparium on unploughable hill country has been limited to pulling, cutting, or cutting and burning, depending on stage of growth. Chemical methods and standing burns have generally proved unsuccessful. Most methods are expensive. Levy (1932, 1940, 1946) postulated that establishment of L. scoparium in pasture could be prevented by good farming techniques. Today there is a growing body of practical evidence to support this hypothesis (Suckling, 1959; New Zealand Farmer 83 (42, 43, 45)). This study was carried out to determine what intrinsic factors favour the establishment of L. scoparium, and the quantitative effect of farm management techniques on this process

Zero field spin splitting in AlSb/InAs/AlSb quantum wells induced by surface proximity effects

InAs quantum well heterostructures are of considerable interest for mesoscopic device applications such as scanning probe and magnetic recording sensors, which require the channel to be close to the surface. Here we report on magnetotransport measurements of AlSb/InAs/AlSb Hall bars at a shallow depth of 20 nm. Analysis of the observed Shubnikov-de Haas oscillations and modeling show that spin splitting energies in excess of 2.3 meV occur at zero magnetic field. We conclude that the spin-splitting results from the Rashba effect due to the band bending in the quantum well. This is caused by substantial electron transfer from the surface to the quantum well and becomes significant when the quantum well is located near the surface.Comment: 14 pages, 2 figures. (To be published in APL

The biosynthesis of galactolipids in red clover (Trifolium pratense) : a thesis presented in partial fulfilment of the requirements for the degree of Master of Science in Biochemistry

Galactolipids occur in all cells capable of the photosynthetic evolution of oxygen. The main galactolipids are monogalactosyl diglyceride (MGDG), digalactosyldiglyceride (DGDG) and sulfolipid (SL), MGDG being the most abundant. These three together form the major nonpigment lipids in both leaves and green algae, accounting for about 40% of the total lipids. Nearly all of the cellular MGDG of plants is present in the chloroplasts and is concentrated in the lamellae. Galactolipids contain unusually high percentages of polyunsaturated acids (MGDG contains greater than 90% in some plants), the major one being α-linolenic acid (9,12,15-octadecatrienoic acid; 18:3). Thus in higher plants most of the MGDG is monogalactosyl dilinolenoyl glycerol. MGDG may be the actual substrate of the desaturation reactions of α-linolenic biosynthesis

Family Supportive Supervision Around the Globe

Family-supportive supervision (FSS) refers to the degree to which employees perceive their immediate supervisors as exhibiting attitudes and behaviors that are supportive of their family role demands (Hammer, Kossek, Zimmerman, & Daniels, 2007; Kossek, Pichler, Bodner & Hammer, 2011: Thomas & Ganster, 1995). A growing body of research suggests that leaders\u27 and supervisors\u27 social support of employees\u27 needs to jointly carry out work and family demands is important for general health and job attitudes, such as satisfaction, work-family conflict, commitment, and intention to turn over (Hammer, Kossek, Anger, Bodner, & Zimmerman, 2009; Kossek et al., 2011). Thus, employee perceptions of FSS are critical to individual well-being and productivity (Hammer, Kossek, Yragui, Bodner, & Hansen, 2009). [excerpt