Polydimethylsiloxane Substrates for passive UHFRFID Sensors

PDMS has previously shown to be a suitable substrate for UHF-RFID strain sensor tags due to their elastomer characteristics. However, PDMS has further properties such as polymer swelling which could be utilized in gas sensing. Macroporous PDMS sponges have been proposed as suitable substrates for passive gas sensors. Porous sponges were fabricated using sugar templates and their absorption capacity was investigated along with standard PDMS elastomers. Possible applications could include food package and air quality monitoring

Swelling of PDMS Networks in Solvent Vapours; Applications for Passive RFID Wireless Sensors

The relative degree of swelling of a poly(dimethylsiloxane) (PDMS) network in organic vapours is demonstrated to be related to the chemical and physical properties of the organic compounds. The swelling ratio, based on volume change, QV, is directly correlated with the Hansen solubility parameters, dd, dp and dh and the vapour pressures of the organic vapours employed. A practical use for such PDMS networks in combination with an understanding of the relationship is demonstrated by the use of PDMS as a mechanical actuator in a prototype wireless RFID passive sensor. The swelling of the PDMS displaces a feed loop resulting in an increase in transmitted power, at a fixed distance

Candida albicans biofilm formation on peptide functionalized polydimethylsiloxane

In order to prevent biofilm formation by Candida albicans, several cationic peptides were covalently bound to polydimethylsiloxane (PDMS). The salivary peptide histatin 5 and two synthetic variants (Dhvar 4 and Dhvar 5) were used to prepare peptide functionalized PDMS using 4-azido-2,3,5,6-tetrafluoro-benzoic acid (AFB) as an interlinkage molecule. In addition, polylysine-, polyarginine-, and polyhistidine-PDMS surfaces were prepared. Dhvar 4 functionalized PDMS yielded the highest reduction of the number of C. albicans biofilm cells in the Modified Robbins Device. Amino acid analysis demonstrated that the amount of peptide immobilized on the modified disks was in the nanomole range. Poly-d-lysine PDMS, in particular the homopeptides with low molecular weight (2500 and 9600) showed the highest activity against C. albicans biofilms, with reductions of 93% and 91%, respectively. The results indicate that the reductions are peptide dependent

PDMS residues-free micro/macrostructures on flexible substrates

Transfer printing has been reported recently as a viable route for electronics on flexible substrates. The method involves transferring micro-/macrostructures such as wires or ultra-thin chips from Si (silicon) wafers to the flexible substrates by using elastomeric transfer substrates such as poly(dimethylsiloxane) (PDMS). A major challenge in this process is posed by the residues of PDMS, which are left over on Si surface after the nanostructures have been transferred. As insulator, PDMS residues make it difficult to realize metal connections and hence pose challenge in the way of using nanostructures as the building blocks for active electronics. This paper presents a method for PDMS residues-free transfer of Si micro-/macrostructures to flexible substrates such as polyimide (PI). The PDMS residues are removed from Si surface by immersing the transferred structures in a solution of quaternary ammonium fluoride such as TBAF (Tetrabutylammonium Fluoride) and non-hydroxylic aprotic solvent such as PMA (propylene glycol methyl ether acetate). The residues are removed at a rate (∼1.5 μm/min) which is about five times faster than the traditional dry etch methods. Unlike traditional alternatives, the presented method removes PDMS without attacking the flexible PI substrates

Molecular Dynamics Simulations of Poly(dimethylsiloxane) Elasticity

Cross-linked polymers have unique and advantageous properties due to the infinite elastic chains. Poly(dimethylsiloxane) (PDMS) belongs into a group of non-toxic, relatively inert and highly elastic polymers (elastomers). In addition, this material is easy to fabricate and has favorable optical and mechanical properties, and it is widely used in fiber optics. Based on testing three different simulation techniques for getting closer insight into the structural background of physical properties of PDMS resin, the molecular dynamics method is chosen. The main topic of this paper is an analysis of relationship between the PDMS cross-linking level and its elasticity. The calculations are performed within the Materials Studio (MS) simulation environment (Biovia Software Inc. USA) using molecular dynamics (MD) theory implemented in MS Forcite Plus module. The obtained results are compared with the newest experimental data available for real PDMS materials

An investigation of PDMS structures for optimized ferroelectret performance

This paper reports the ANSYS simulation and fabrication processes for optimising PDMS ferroelectret performance. The proposed model extends the previously published analytical models and compares this with simulation of individual void geometry. The ferroelectret material is fabricated from PDMS using 3D-printed plastic moulds. The analytical model and Ansys simulation results predict the variation in performance of the PDMS ferroelectret with the different void geometry and surface charge density. The theoretical maximum piezoelectric coefficient d33 achieved was about 220 pC/N. The experimental maximum d33 obtained was 172 pC/N

Fabrication of Embedded Microvalve on PMMA Microfluidic Devices through Surface Functionalization

The integration of a PDMS membrane within orthogonally placed PMMA microfluidic channels enables the pneumatic actuation of valves within bonded PMMA-PDMS-PMMA multilayer devices. Here, surface functionalization of PMMA substrates via acid catalyzed hydrolysis and air plasma corona treatment were investigated as possible techniques to permanently bond PMMA microfluidic channels to PDMS surfaces. FTIR and water contact angle analysis of functionalized PMMA substrates showed that air plasma corona treatment was most effective in inducing PMMA hydrophilicity. Subsequent fluidic tests showed that air plasma modified and bonded PMMA multilayer devices could withstand fluid pressure at an operational flow rate of 9 mircoliters/min. The pneumatic actuation of the embedded PDMS membrane was observed through optical microscopy and an electrical resistance based technique. PDMS membrane actuation occurred at pneumatic pressures of as low as 10kPa and complete valving occurred at 14kPa for 100 micrometers x 100 micrometers channel cross-sections.Comment: Submitted on behalf of EDA Publishing Association (http://irevues.inist.fr/handle/2042/16838

High-Resolution Contact Printing with Chemically Patterned Flat Stamps Fabricated by Nanoimprint Lithography

Chemically patterned flat stamps provide an effective solution to avoid mechanical stamp-stability problems currently encountered in microcontact printing. A new method is developed to fabricate chemical patterns on a flat PDMS stamp using nanoimprint lithography. Sub-100 nm gold patterns are successfully replicated by these chemically patterned flat PDMS stamps. \ud \u

Thin film diffusion barrier formation in PDMS microcavities

We describe a method to form glass like thin film barrier in polydimethylsiloxane (PDMS) microcavities. The reactive fragments for the surface reaction were created from O2 and hexamethyldisiloxane (HMDS) in RF plasma environment. The reaction is based on migration of the reactive fragments into the microcavities by diffusion, to form a glass like thin film barrier to conceal the naked surface of PDMS. The barrier successfully blocked penetration of a fluorescent dye rhodamine B (RhB) into PDMS. The thickness of the barrier could be controlled by the time of reaction and the pressure inside the reaction chamber. There is a wide range of applications of such a technique in various fields, e.g. for coating the covered surfaces of microfluidic channels, tubes, capillaries, medical devices, catheters, as well as chip-integrated capillary electrophoresis and advanced electronic and opto-fluidic packaging