Optical properties of NaxV2O5

The optical properties of sodium-deficient NaxV2O5 (0.85 < x <1) single crystals are analyzed in the wide energy range, from 0.012 to 4.5 eV, using ellipsometry, infrared reflectivity, and Raman scattering techniques. The material remains insulating up to the maximal achieved hole concentration of about 15%. In sodium deficient samples the optical absorption peak associated to the fundamental electronic gap develops at about 0.44 eV. It corresponds to the transition between vanadium dxy and the impurity band, which forms in the middle of the pure NaV2O5 gap. Raman spectra measured with incident photon energy larger then 2 eV show strong resonant behavior, due to the presence of the hole-doping activated optical transitions, peaked at 2.8 eV.Comment: 7 pages, 4 fugures, to be published in PR

Optical properties of lowest-energy carbon allotropes from the first-principles calculations

We study the optical properties of lowest-energy carbon allotropes in the infrared, visible and ultra-violet ranges of light in the general gradient approximation of the density functional theory. In our calculations we used the all-electron approach as well as the pseudo-potential approximation. In the infrared range, the complex dielectric functions, infrared and Raman spectra have been calculated using CRYSTAL14 program. The electronic properties and energy-dependent dielectric functions in the visible and ultraviolet ranges have been calculated using VASP program. We have described with a good accuracy experimentally known optical properties of cubic diamond crystal. Using obtained set of relevant parameters for calculations, we have predicted optical constants, dielectric functions and Raman spectra for the lowest-energy hypothetical carbon allotropes and lonsdaleite.Comment: 11 pages, 7 tables, 5 figures, to be published in Computer Optic

Performance of silicon solar cell assemblies

Solar cell assembly current-voltage characteristics, thermal-optical properties, and power performance were determined. Solar cell cover glass thermal radiation, optical properties, confidence limits, and temperature intensity effects on maximum power were discussed

Electronic depth profiles with atomic layer resolution from resonant soft x-ray reflectivity

The analysis of x-ray reflectivity data from artificial heterostructures usually relies on the homogeneity of optical properties of the constituent materials. However, when the x-ray energy is tuned to an absorption edge, this homogeneity no longer exists. Within the same material, spatial regions containing elements at resonance will have optical properties very different from regions without resonating sites. In this situation, models assuming homogeneous optical properties throughout the material can fail to describe the reflectivity adequately. As we show here, resonant soft x-ray reflectivity is sensitive to these variations, even though the wavelength is typically large as compared to the atomic distances over which the optical properties vary. We have therefore developed a scheme for analyzing resonant soft x-ray reflectivity data, which takes the atomic structure of a material into account by "slicing" it into atomic planes with characteristic optical properties. Using LaSrMnO4 as an example, we discuss both the theoretical and experimental implications of this approach. Our analysis not only allows to determine important structural information such as interface terminations and stacking of atomic layers, but also enables to extract depth-resolved spectroscopic information with atomic resolution, thus enhancing the capability of the technique to study emergent phenomena at surfaces and interfaces.Comment: Completely overhauled with respect to the previous version due to peer revie

Optical monitoring system

Instrument can measure optical transmission, reflectance, and scattering. This information can be used to identify changes in optical properties or deviations from required optical standards. Device consists of monochromatic source, photo detector, transfer mirror, and hemiellipsoid. System might be used to measure optical properties of thin film

Optical properties of bialkali photocathodes

The optical properties of the `bialkali' KCsSb and RbCsSb photomultiplier cathodes have been experimentally investigated in the visible range. The measurements carried out include the absolute reflectance at near-normal incidence, the polarization-dependent relative reflectance at various angles and the change in polarization upon reflection from the photocathode. These experimental inputs have been combined with a theoretical model to determine the complex refractive index of the photocathodes in the wavelength range 380 to 680 nm and their thickness. As a result of this work, we derive a model which predicts the fraction of light impinging on a photomultiplier tube that is reflected, absorbed or transmitted, as a function of wavelength and angle, and dependent on the medium to which the photomultiplier is coupled.Comment: 51 pages (double spacing), 16 figures, submitted for publication in NIM