Structure of hard-hypersphere fluids in odd dimensions

The structural properties of single component fluids of hard hyperspheres in odd space dimensionalities $d$ are studied with an analytical approximation method that generalizes the Rational Function Approximation earlier introduced in the study of hard-sphere fluids [S. B. Yuste and A. Santos, Phys. Rev. A {\bf 43}, 5418 (1991)]. The theory makes use of the exact form of the radial distribution function to first order in density and extends it to finite density by assuming a rational form for a function defined in Laplace space, the coefficients being determined by simple physical requirements. Fourier transform in terms of reverse Bessel polynomials constitute the mathematical framework of this approximation, from which an analytical expression for the static structure factor is obtained. In its most elementary form, the method recovers the solution of the Percus-Yevick closure to the Ornstein-Zernike equation for hyperspheres at odd dimension. The present formalism allows one to go beyond by yielding solutions with thermodynamic consistency between the virial and compressibility routes to any desired equation of state. Excellent agreement with available computer simulation data at $d=5$ and $d=7$ is obtained. As a byproduct of this study, an exact and explicit polynomial expression for the intersection volume of two identical hyperspheres in arbitrary odd dimensions is given.Comment: 18 pages, 7 figures; v2: new references added plus minor changes; to be published in PR

Long-Range Correlations in Self-Gravitating N-Body Systems

Observed self-gravitating systems reveal often fragmented non-equilibrium structures that feature characteristic long-range correlations. However, models accounting for non-linear structure growth are not always consistent with observations and a better understanding of self-gravitating $N$-body systems appears necessary. Because unstable gravitating systems are sensitive to non-gravitational perturbations we study the effect of different dissipative factors as well as different small and large scale boundary conditions on idealized $N$-body systems. We find, in the interval of negative specific heat, equilibrium properties differing from theoretical predictions made for gravo-thermal systems, substantiating the importance of microscopic physics and the lack of consistent theoretical tools to describe self-gravitating gas. Also, in the interval of negative specific heat, yet outside of equilibrium, unforced systems fragment and establish transient long-range correlations. The strength of these correlations depends on the degree of granularity, suggesting to make the resolution of mass and force coherent. Finally, persistent correlations appear in model systems subject to an energy flow.Comment: 20 pages, 21 figures. Accepted for publication in A&

Equation of state for five-dimensional hyperspheres from the chemical-potential route

We use the Percus-Yevick approach in the chemical-potential route to evaluate the equation of state of hard hyperspheres in five dimensions. The evaluation requires the derivation of an analytical expression for the contact value of the pair distribution function between particles of the bulk fluid and a solute particle with arbitrary size. The equation of state is compared with those obtained from the conventional virial and compressibility thermodynamic routes and the associated virial coefficients are computed. The pressure calculated from all routes is exact up to third density order, but it deviates with respect to simulation data as density increases, the compressibility and the chemical-potential routes exhibiting smaller deviations than the virial route. Accurate linear interpolations between the compressibility route and either the chemical-potential route or the virial one are constructed.Comment: 9 pages, 6 figures; v2: Change in one referenc

Geometrical effects on energy transfer in disordered open quantum systems

We explore various design principles for efficient excitation energy transport in complex quantum systems. We investigate energy transfer efficiency in randomly disordered geometries consisting of up to 20 chromophores to explore spatial and spectral properties of small natural/artificial Light-Harvesting Complexes (LHC). We find significant statistical correlations among highly efficient random structures with respect to ground state properties, excitonic energy gaps, multichromophoric spatial connectivity, and path strengths. These correlations can even exist beyond the optimal regime of environment-assisted quantum transport. For random configurations embedded in spatial dimensions of 30 A and 50 A, we observe that the transport efficiency saturates to its maximum value if the systems contain 7 and 14 chromophores respectively. Remarkably, these optimum values coincide with the number of chlorophylls in (Fenna-Matthews-Olson) FMO protein complex and LHC II monomers, respectively, suggesting a potential natural optimization with respect to chromophoric density.Comment: 11 pages, 10 figures. Expanded from the former appendix to arXiv:1104.481

Energy non-equipartition in multicomponent granular mixtures

We study non-equipartition of energy in granular fluids composed by an arbitrarily large number of components. We focus on a simple mean field model, based upon a Maxwell collision operator kernel, and predict the temperature ratios for the species. Moreover, we perform Direct Monte Carlo simulations in order to verify the predictions.Comment: submitted to PR