238,204 research outputs found
Nucleation in binary polymer blends: Effects of foreign mesoscopic spherical particles
We study nucleation in binary polymer blends in the presence of mesoscopic spherical particles using self-consistent field theory, considering both heterogeneous and homogeneous nucleation mechanisms. Heterogeneous nucleation is found to be highly sensitive to surface selectivity and particle size, with rather subtle dependence on the particle size. Particles that preferentially adsorb the nucleating species generally favor heterogeneous nucleation. For sufficiently strong adsorption, barrierless nucleation is possible. By comparing the free energy barrier for homogeneous and heterogeneous nucleation, we construct a kinetic phase diagram
Ternary nucleation of H_2SO_4, NH_3 and H_2O
A classical theory of the ternary homogeneous nucleation of sulfuric acid—ammonia—water is presented. For NH3 mixing ratios exceeding 1 ppt, the presence of ammonia enhances the binary (sulfuric acid—water) nucleation rate by several orders of magnitude. However, the limiting component for ternary nucleation—as for binary nucleation—is sulfuric acid. The sulfuric acid concentration needed for significant ternary nucleation is several orders of magnitude below that required in binary case
Observation of inhomogeneous domain nucleation in epitaxial Pb(Zr,Ti)O3 capacitors
We investigated domain nucleation process in epitaxial Pb(Zr,Ti)O3 capacitors
under a modified piezoresponse force microscope. We obtained domain evolution
images during polarization switching process and observed that domain
nucleation occurs at particular sites. This inhomogeneous nucleation process
should play an important role in an early stage of switching and under a high
electric field. We found that the number of nuclei is linearly proportional to
log(switching time), suggesting a broad distribution of activation energies for
nucleation. The nucleation sites for a positive bias differ from those for a
negative bias, indicating that most nucleation sites are located at
ferroelectric/electrode interfaces
Observing classical nucleation theory at work by monitoring phase transitions with molecular precision.
It is widely accepted that many phase transitions do not follow nucleation pathways as envisaged by the classical nucleation theory. Many substances can traverse intermediate states before arriving at the stable phase. The apparent ubiquity of multi-step nucleation has made the inverse question relevant: does multistep nucleation always dominate single-step pathways? Here we provide an explicit example of the classical nucleation mechanism for a system known to exhibit the characteristics of multi-step nucleation. Molecular resolution atomic force microscopy imaging of the two-dimensional nucleation of the protein glucose isomerase demonstrates that the interior of subcritical clusters is in the same state as the crystalline bulk phase. Our data show that despite having all the characteristics typically associated with rich phase behaviour, glucose isomerase 2D crystals are formed classically. These observations illustrate the resurfacing importance of the classical nucleation theory by re-validating some of the key assumptions that have been recently questioned
Nucleation in Systems with Elastic Forces
Systems with long-range interactions when quenced into a metastable state
near the pseudo-spinodal exhibit nucleation processes that are quite different
from the classical nucleation seen near the coexistence curve. In systems with
long-range elastic forces the description of the nucleation process can be
quite subtle due to the presence of bulk/interface elastic compatibility
constraints. We analyze the nucleation process in a simple 2d model with
elastic forces and show that the nucleation process generates critical droplets
with a different structure than the stable phase. This has implications for
nucleation in many crystal-crystal transitions and the structure of the final
state
The uphill turtle race: on short time nucleation probabilities
The short time behavior of nucleation probabilities is studied by
representing nucleation as diffusion in a potential well with escape over a
barrier. If initially all growing nuclei start at the bottom of the well, the
first nucleation time on average is larger than the inverse nucleation
frequency. Explicit expressions are obtained for the short time probability of
first nucleation. For very short times these become independent of the shape of
the potential well. They agree well with numerical results from an exact
enumeration scheme. For a large number N of growing nuclei the average first
nucleation time scales as 1/\log N in contrast to the long-time nucleation
frequency, which scales as 1/N. For linear potential wells closed form
expressions are obtained for all times.Comment: 8 pages, submitted to J. Stat. Phy
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