70,858 research outputs found
THEORY OF ELECTRON-DIFFRACTION BY VOID LATTICE
The theory is given for the electron diffraction by the void lattice in molybdenum, recently observed by Sass and Eyre (see abstr. A52564 of 1973). The results are analysed to see if this method can give useful new information about the voids and their ordering. The predictions of the positions and intensities of the extra peaks agree with observation. However, the quantitative theory shows that void shapes cannot readily be found from the diffraction data. Nor is it easy to get accurate information about void sizes or the nature of the disorder in the void lattice, mainly because of the problems of measuring intensity profiles. The effects of the various forms of lattice disorder are discussed qualitatively
Structure determination of PF3 adsorption on Cu(100) using X-ray standing waves
The local structure of the Cu(100)c(4x2)-PF3 adsorption phase has been investigated through the use of normal-incidence X-ray standing waves (NIXSW), monitored by P 1s and F 1s photoemission, together with P K-edge near-edge X-ray absorption fine structure (NEXAFS). NEXAFS shows the molecule to be oriented with its C3v symmetry axis essentially perpendicular to the surface, while the P NIXSW data show the molecule to be adsorbed in atop sites 2.37±0.04 Å above the surface, this distance corresponding to the Cu-P nearest-neighbour distance in the absence of any surface relaxation. F NIXSW indicates a surprisingly small height difference of the P and F atoms above the surface 0.44±0.06 Å, compared with the value expected for an undistorted gas-phase geometry of 0.77 Å, implying significant increases in the F-P-F bond angles. In addition, however, the F NIXSW data indicate that the molecules have a well-defined azimuthal orientation with a molecular mirror plane aligned in a substrate mirror plane, and with a small (5-10°) tilt of the molecule in this plane such that the two symmetrically-equivalent F atoms in each molecule are tilted down towards the surface
Optimisation of the T-square sampling method to estimate population sizes.
Population size and density estimates are needed to plan resource requirements and plan health related interventions. Sampling frames are not always available necessitating surveys using non-standard household sampling methods. These surveys are time-consuming, difficult to validate, and their implementation could be optimised. Here, we discuss an example of an optimisation procedure for rapid population estimation using T-Square sampling which has been used recently to estimate population sizes in emergencies. A two-stage process was proposed to optimise the T-Square method wherein the first stage optimises the sample size and the second stage optimises the pathway connecting the sampling points. The proposed procedure yields an optimal solution if the distribution of households is described by a spatially homogeneous Poisson process and can be sub-optimal otherwise. This research provides the first step in exploring how optimisation techniques could be applied to survey designs thereby providing more timely and accurate information for planning interventions
Spin Gaps and Bilayer Coupling in YBaCuO and YBaCuO
We investigate the relevance to the physics of underdoped
YBaCuO and YBaCuO of the quantum critical point
which occurs in a model of two antiferromagnetically coupled planes of
antiferromagnetically correlated spins. We use a Schwinger boson mean field
theory and a scaling analysis to obtain the phase diagram of the model and the
temperature and frequency dependence of various susceptibilities and relaxation
rates. We distinguish between a low coupled-planes regime in which
the optic spin excitations are frozen out and a high
decoupled-planes regime in which the two planes fluctuate independently. In the
coupled-planes regime the yttrium nuclear relaxation rate at low temperatures
is larger relative to the copper and oxygen rates than would be naively
expected in a model of uncorrelated planes. Available data suggest that in
YBaCuO the crossover from the coupled to the decoupled planes
regime occurs at or . The predicted correlation length is
of order 6 lattice constants at . Experimental data related to the
antiferromagnetic susceptibility of YBaCuO may be made consistent
with the theory, but available data for the uniform susceptibility are
inconsistent with the theory.Comment: RevTex 3.
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