Impact of Si nanocrystals in a-SiOx<Er> in C-Band emission for applications in resonators structures

Si nanocrystals (Si-NC) in a-SiOx were created by high temperature annealing. Si-NC samples have large emission in a broadband region, 700nm to 1000nm. Annealing temperature, annealing time, substrate type, and erbium concentration is studied to allow emission at 1550 nm forsamples with erbium. Emission in the C-Band region is largely reduced by the presence of Si-NC. This reduction may be due to less efficient energy transfer processes from the nanocrystals than from the amorphous matrix to the Er3+ ions, perhaps due to the formation of more centro-symmetric Er3+ sites at the nanocrystal surfaces or to very different optimal erbium concentrations between amorphous and crystallized samples.Comment: 3 pages, 4 figure

Non-collinear Magnetic states of Mn5Ge3 compound

Mn5Ge3 thin films epitaxially grown on Ge(111) exhibit metallic conductivity and strong ferromagnetism up to about 300 K. Recent experiments suggest a non-collinear spin structure. In order to gain deep insights into the magnetic structure of this compound, we have performed fully unconstrained ab-initio pseudopotential calculations within density functional theory, investigating the different magnetic states corresponding to Collinear (C) and Non-Collinear (NC) spin configurations. We focus on their relative stability under pressure and strain field. Under pressure, the C and NC configurations are degenerate, suggesting the possible occurrence of accidental magnetic degeneracy also in Mn5Ge3 real samples. We found a continuous transition from a ferromagnetic C low-spin state at small volumes to a NC high-spin state at higher volumes. Remarkably, the degeneracy is definitely removed under the effect of uniaxial strain: in particular, NC spin configurations is favoured under tensile uniaxial strain.Comment: 13 pages,2 Tables, 5 figures, Revised Version, Materials Science in Semiconductor Processing (in press

The Influence of Silicon Nanoclusters on the Optical Properties of a-SiNx Samples: A Theoretical Study

By means of ab-initio calculations we investigate the optical properties of pure a-SiN$_x$ samples, with $x \in [0.4, 1.8]$, and samples embedding silicon nanoclusters (NCs) of diameter $0.5 \leq d \leq 1.0$ nm. In the pure samples the optical absorption gap and the radiative recombination rate vary according to the concentration of Si-N bonds. In the presence of NCs the radiative rate of the samples is barely affected, indicating that the intense photoluminescence of experimental samples is mostly due to the matrix itself rather than to the NCs. Besides, we evidence an important role of Si-N-Si bonds at the NC/matrix interface in the observed photoluminescence trend

Characterization of ageing resistant transparent nanocrystalline yttria-stabilized zirconia implants.

The "Window to the Brain" is a transparent cranial implant under development, based on nanocrystalline yttria-stabilized zirconia (nc-YSZ) transparent ceramic material. Previous work has demonstrated the feasibility of this material to facilitate brain imaging over time, but the long-term stability of the material over decades in the body is unknown. In this study, the low-temperature degradation (LTD) of nc-YSZ of 3, 6, and 8 mol % yttria is compared before and after accelerated ageing treatments following ISO standards for assessing the ageing resistance of zirconia ceramics. After 100 hr of accelerated ageing (equivalent to many decades of ageing in the body), the samples do not show any signs of phase transformation to monoclinic by X-ray diffraction and micro-Raman spectroscopy. Moreover, the mechanical hardness of the samples did not decrease, and changes in optical transmittance from 500 to 1000 nm due to ageing treatments was minimal (below 3% for all samples), and unlikely to be due to phase transformation of surface crystals to monoclinic. These results indicate the nc-YSZ has excellent ageing resistance and can withstand long-term implantation conditions without exhibiting LTD

Local-field effects in silicon nanoclusters

The effect of the local fields on the absorption spectra of silicon nanoclusters (NCs), freestanding or embedded in SiO2, is investigated in the DFT-RPA framework for different size and amorphization of the samples. We show that local field effects have a great influence on the optical absorption of the NCs. Their effect can be described by two separate contributions, both arising from polarization effects at the NC interface. First, local fields produce a reduction of the absorption that is stronger in the low energy limit. This contribution is a direct consequence of the screening induced by polarization effects on the incoming field. Secondly, local fields cause a blue shift on the main absorption peak that has been explained in terms of perturbation of the absorption resonance conditions. Both contributions do not depend either on the NC diameter nor on its amorphization degree, while showing a high sensitivity to the environment enclosing the NCs

Spectro-photometric close pairs in GOODS-S: major and minor companions of intermediate-mass galaxies

(Abriged) Our goal here is to provide merger frequencies that encompass both major and minor mergers, derived from close pair statistics. We use B-band luminosity- and mass-limited samples from an Spitzer/IRAC-selected catalogue of GOODS-S. We present a new methodology for computing the number of close companions, Nc, when spectroscopic redshift information is partial. We select as close companions those galaxies separated by 6h^-1 kpc < rp < 21h^-1 kpc in the sky plane and with a difference Delta_v <= 500 km s^-1 in redshift space. We provide Nc for four different B-band-selected samples. Nc increases with luminosity, and its evolution with redshift is faster in more luminous samples. We provide Nc of M_star >= 10^10 M_Sun galaxies, finding that the number including minor companions (mass ratio >= 1/10) is roughly two times the number of major companions alone (mass ratio >= 1/3) in the range 0.2 <= z < 1.1. We compare the major merger rate derived by close pairs with the one computed by morphological criteria, finding that both approaches provide similar merger rates for field galaxies when the progenitor bias is taken into account. Finally, we estimate that the total (major+minor) merger rate is ~1.7 times the major merger rate. Only 30% to 50% of the M_star >= 10^10 M_Sun early-type (E/S0/Sa) galaxies that appear z=1 and z=0 may have undergone a major or a minor merger. Half of the red sequence growth since z=1 is therefore unrelated to mergers.Comment: Accepted in A&A. 14 pages, 6 figures, 8 tables. We have tested the method with a local, volume-limited spectroscopic sample

Structure and spatial distribution of Ge nanocrystals subjected to fast neutron irradiation

The influence of fast neutron irradiation on the structure and spatial distribution of Ge nanocrystals (NC) embedded in an amorphous SiO2 matrix has been studied. The investigation was conducted by means of laser Raman Scattering (RS), High Resolution Transmission Electron Microscopy (HR-TEM) and X-ray photoelectron spectroscopy (XPS). The irradiation of NC-Ge samples by a high dose of fast neutrons lead to a partial destruction of the nanocrystals. Full reconstruction of crystallinity was achieved after annealing the radiation damage at 800 deg. C, which resulted in full restoration of the RS spectrum. HR-TEM images show, however, that the spatial distributions of NC-Ge changed as a result of irradiation and annealing. A sharp decrease in NC distribution towards the SiO2 surface has been observed. This was accompanied by XPS detection of Ge oxides and elemental Ge within both the surface and subsurface region

Probing polymer chain constraint and synergistic effects in nylon 6-clay nanocomposites and nylon 6-silica flake sub-micro composites with nanomechanics

In this study, we report that a synergistic effect exists in the surface mechanical properties of nylon 6–clay nanocomposites (NC) that can be shown by nanomechanical testing. The hardness, elastic modulus, and nanoindentation creep behavior of nylon 6 and its nanocomposites with different filler loading produced by melt compounding were contrasted to those of model nylon 6 sub-microcomposites (SMC) reinforced by sub-micro-thick silica flakes in which constraint cannot occur due to the difference in filler geometry. Polymer chain constraint was assessed by the analysis of nanoindentation creep data. Time-dependent creep decreased with increasing the filler loading in the NC consistent with the clay platelets exerting a constraint effect on the polymer chains which increases with filler loading. In contrast, there was no evidence of any reduced time-dependent creep for the SMC samples, consistent with a lack of constraint expected due to much lower aspect ratio of the silica flake