Microrheological Characterisation of Anisotropic Materials

We describe the measurement of anisotropic viscoelastic moduli in complex soft materials, such as biopolymer gels, via video particle tracking microrheology of colloid tracer particles. The use of a correlation tensor to find the axes of maximum anisotropy, and hence the mechanical director, is described. The moduli of an aligned DNA gel are reported, as a test of the technique; this may have implications for high DNA concentrations in vivo. We also discuss the errors in microrheological measurement, and describe the use of frequency space filtering to improve displacement resolution, and hence probe these typically high modulus materials.Comment: 5 pages, 5 figures. Replaced after refereeing/ improvement. Main results are the same. The final, published version of the paper is here http://link.aps.org/abstract/PRE/v73/e03190

Computational modelling and experimental characterisation of heterogeneous materials

Heterogeneous materials can exhibit behaviour under load that cannot be described by classical continuum elasticity. Beams in bending can show a relative stiffening as the beam depth tends to zero, a size effect. Size effects are recognised in higher order continuum elastic theories such as micropolar elasticity. The drawback of higher order theories is the requirement of addition constitutive relations and associated properties that are often difficult to establish experimentally. Furthermore the finite element method, of great benefit in classical elasticity, has shown limitations when applied to micropolar elasticity. The determination of additional constitutive properties and the computational modelling of micropolar elasticity will be discussed in the context of a model heterogeneous material loaded in simple 3 point bending. The model material was created by drilling holes in aluminium bar in a regular pattern, with the hole axis normal to the plane of bending. The bending tests show that a size effect is present. These results are compared against modelling the detailed beam geometries in the finite element package ANSYS, which again shows the size effect. These two bending test are used to extract the additional micropolar elastic material properties. A comparison is then made against analytical solutions,numerical solutions using a micropolar beam finite element and a micropolar plane stress control volume method.It will be shown that the need for extensive experimental testing to determine the additional constitutive properties may not be necessary with the appropriate use of numerical methods

Post-yield characterisation of metals with significant pile-up through spherical indentations

Finite element simulations of spherical indentations accounting for frictional contact provide validated load–indentation output for assessing and improving existing methods used to determine the stress–strain curve of materials with significant pile-up. The importance of friction to the proper assessment of the pile-up effect is established. Weaknesses in current characterisation relations and procedures are also identified. Existing correction formulae accounting for pile-up are modified so that the contact area radius is more accurately determined. This modification is implemented in the context of a characterisation process that relies on analysing unloading portions of load–indentation curves. Post-yield material behaviour predictions from such analysis are found to be in very good agreement with the initial finite element material input

Sampling eigenmodes in colloidal solids

We study the properties of correlation matrices widely used in the characterisation of vibrational modes in colloidal materials. We show that the eigenvectors in the middle of the spectrum are strongly mixed, but that at both the top and the bottom of the spectrum it is possible to extract a good approximation to the true eigenmodes of an elastic system.Comment: 6 pages, 10 figure

INFLUENCE OF MATERIAL CHARACTERIZATION IN THE DESIGN OF TUNNEL LIGHTING INSTALLATIONS

The paper describes the influence of the characterisation of reflectance behaviour of tunnel pavements and wall materials on the tunnel lighting design. CIE 189 document suggests considering lambertian behaviour for inter-reflection calculations for road luminance evaluation at design stage, because, unfortunately, no bi-directional reflection data for tunnel surfaces are commonly available. This simplification is supported by the low impact of inter- reflection contribution to road luminance. A European funded research project ha the task of developing the metrological support for the road surface characterisation in new geometries of measurements. The paper suggests to apply the outcomes on new geometries to tunnel wall materials characterisation suggesting that the suggested SURFACE observation angle of 2.29° can be useful for short tunnel too, including wall surfaces

Polyterthiophenes incorporating 3,4-difluorothiophene units : application in organic field-effect transistors

Two terthiophenes bearing core fluorinated thienyl units have been synthesised as potential semiconductor materials for organic field-effect transistors. Polymerisation of these compounds has been achieved using conventional iron(III) chloride oxidative coupling methods and by electrochemical oxidation. Characterisation of the fluorinated materials has been achieved by absorption spectroscopy and cyclic voltammetry. A soluble hexyl-functionalised polymer (poly8b) was used in an OFET device; hole mobilities were measured up to 3 × 10−3 cm2 · V−1 · s−1, and the device had an on/off ratio of 105 and a turn-on voltage of +4 V

Editorial: biodegradable materials

This Special Issue “Biodegradable Materials” features research and review papers concerning recent advances on the development, synthesis, testing and characterisation of biomaterials. These biomaterials, derived from natural and renewable sources, offer a potential alternative to existing non-biodegradable materials with application to the food and biomedical industries amongst many others. In this Special Issue, the work is expanded to include the combined use of fillers that can enhance the properties of biomaterials prepared as films. The future application of these biomaterials could have an impact not only at the economic level, but also for the improvement of the environment

Analysis of wear mechanism in TPU-steel contact pair by means of long stroke tribometer tests

A complete wear characterisation of a thermoplastic polyurethane (TPU) sliding against steel is presented. Wear tests were performed using a long stroke tribometer under sliding reciprocating movement and dry conditions. The dependence of some of the most significant parameters was studied. Before and after wear tests, complementary observations, analyses and measurements were also performed on both contacting materials. These various characterisations involved weight loss of TPU, physico-chemical and thermo- mechanical analyses of TPU, included topographical measurements and morphological observations of worn surfaces of contacting pairs and calculations of the temperature rise generated by friction