Electro-oxidation of Ethanol on Carbon Supported PtSn and PtSnNi Catalysts

Even though platinum is known as an active electro-catalyst for ethanol oxidation at low temperatures (< 100 oC), choosing the electrode material for ethanol electro-oxidation is a crucial issue. It is due to its property which easily poisoned by a strong adsorbed species such as CO. PtSn-based electro-catalysts have been identified as better catalysts for ethanol electro-oxidation. The third material is supposed to improved binary catalysts performance. This work presents a study of the ethanol electro-oxidation on carbon supported Pt-Sn and Pt-Sn-Ni catalysts. These catalysts were prepared by alcohol reduction. Nano-particles with diameters between 2.5-5.0 nm were obtained. The peak of (220) crystalline face centred cubic (fcc) Pt phase for PtSn and PtSnNi alloys was repositioned due to the presence of Sn and/or Ni in the alloy. Furthermore, the modification of Pt with Sn and SnNi improved ethanol and CO electro-oxidation. Copyright © 2016 BCREC GROUP. All rights reserved Received: 10th November 2015; Revised: 1st February 2016; Accepted: 1st February 2016 How to Cite: Hidayati, N., Scott, K. (2016). Electro-oxidation of Ethanol on Carbon Supported PtSn and PtSnNi Catalysts. Bulletin of Chemical Reaction Engineering & Catalysis, 11 (1): 10-20. (doi:10.9767/bcrec.11.1.394.10-20) Permalink/DOI: http://dx.doi.org/10.9767/bcrec.11.1.394.10-2

Progress in Material Handling Research: 2016

Table of contents

The Material Affinity of Design and Science for a Circular Economy

This paper presents a design and material science collaboration in a science laboratory for regenerated cellulose. The material affinity outlines how both disciplines are connected through a materials practice in communication and production of cellulose films. The outcome presents new transdisciplinary approaches for design and science towards circularity of materials

Two-dimensional Phononic Crystals with Acoustic-Band Negative Refraction

A two-dimensional phononic crystal (PC) can exhibit longitudinal-mode negative energy refraction on its lowest (acoustical) frequency pass band. The effective elastodynamic properties of a typical PC are calculated and it is observed that the components of the effective density tensor can achieve negative values at certain low frequencies on the acoustical branches for the longitudinal-mode pass-band, and that negative refraction may be accompanied by either positive or negative effective density. Furthermore, such a PC has a high anisotropy ratio at certain low frequencies, offering potential for application to acoustic cloaking where effective material anisotropy is essential.Comment: in Proceedings of the ASME 2016 Conference on Smart Materials, Adaptive Structures and Intelligent Systems, Stowe, VT (2016