Developing an Entrepreneurial Identity

The Case Study section of the International Journal of Entrepreneurship and Innovation serves two purposes. First, the case studies presented are concerned with problematical issues that are pertinent to students of entrepreneurship. Thus they constitute appropriate teaching and learning vehicles on a variety of postgraduate and undergraduate programmes. Each case study is accompanied by a set of guidelines for the use of tutors. Second, it is envisaged that those engaged in entrepreneurial activities will find the cases both interesting and useful. The case in this issue concerns an ex-corporate manager who is in the process of establishing and developing her own business after being made redundant from her senior management position. It is based on two in-depth discussions, one held in the first year of setting up the business, the second occurring after the business had been up and running for 18 months. Focusing on the question of identity, the story illustrates the complex issues involved in the transformation, development and maintenance of identity during such a transition. The case is a real-life one but all names are pseudonyms

Review of: Lewis\u27 Dictionary of Toxicology (Robert A. Lewis, ed.; Lewis Publishers 1998)

Review of the book: Lewis\u27 Dictionary of Toxicology (Robert A. Lewis, ed.; Lewis Publishers 1998). About the author, acknowledgments, alphabetical listing of terms defined. ISBN 1-56670-223-2; [1127 pp. $84.95. Hardbound. 2000 Corporate Blvd. N.W., Boca Raton, FL 33431.

The Lewis Heat Pipe Code with Application to SP-100 GES Heat Pipes

The NASA Lewis Research Center has a thermal management program supporting SP-100 goals, which includes heat pipe radiator development. As a part of the program Lewis has elected to prepare an in-house heat pipe code tailored to the needs of its SP-100 staff to supplement codes from other sources. The latter, designed to meet the needs of the originating organizations, were deemed not entirely appropriate for use at Lewis. However, a review of their features proved most beneficial in the design of the Lewis code

A Cartesian co-ordinate system for representing the second to fifth metacarpals in the human hand

Description: This is tha authors' PDF version of an article published in Radiography© 2004. The definitive version is available at www.elsevierhealth.comPurpose The use of hand radiographs has both clinical and anthropometric applications. However, a method for converting standard bony points within the metacarpus to Cartesian co-ordinates does not exist. Methods A simple method for converting standard bony points of the second to fifth metacarpals to Cartesian co-ordinates is described for the first time. Results Using a small set of measurements and treating these with equations of known voracity, this method is accurate and allows the metacarpus to be interro¬gated via a much wider range of geometrical techniques than has so far been available. Conclusions This method allows naked-eye assessments to be supported or re¬placed by metrical evaluations. It is likely to have both clinical and anthropometric uses.University of Liverpool research development grant

Metal-Free Dihydrogen Oxidation by a Borenium Cation:A Combined Electrochemical/Frustrated Lewis Pair Approach

In order to use H2 as a clean source of electricity, prohibitively rare and expensive precious metal electrocatalysts, such as Pt, are often used to overcome the large oxidative voltage required to convert H2 into 2 H+ and 2 e−. Herein, we report a metal-free approach to catalyze the oxidation of H2 by combining the ability of frustrated Lewis pairs (FLPs) to heterolytically cleave H2 with the in situ electrochemical oxidation of the resulting borohydride. The use of the NHC-stabilized borenium cation [(IiPr2)(BC8H14)]+ (IiPr2=C3H2(NiPr)2, NHC=N-heterocyclic carbene) as the Lewis acidic component of the FLP is shown to decrease the voltage required for H2 oxidation by 910 mV at inexpensive carbon electrodes, a significant energy saving equivalent to 175.6 kJ mol−1. The NHC–borenium Lewis acid also offers improved catalyst recyclability and chemical stability compared to B(C6F5)3, the paradigm Lewis acid originally used to pioneer our combined electrochemical/frustrated Lewis pair approach

Some notes on crucifixion

This article discusses the injuries caused by crucifixion, based on an adult male skeleton found in ossuary I:4 in north-east Jerusalem in 1968

Metacarpophalangeal pattern profile analysis of a sample drawn from a North Wales population

This is tha author's PDF version of an article published in Annals of human biology© 2001. The definitive version is available at http://www.tandf.co.uk/journalsSexual dimorphism and population differences were investigated using metacarpophalangeal pattern profile (MCPP) analysis. Although it is an anthropmetric technique, MCPP analysis is more frequently used in genetic syndrome analysis and has been under-used in the study of human groups. The present analysis used a series of hand radiographics from Gwynedd, North Wales, to make comparisons, first, between the sexes within the sample and then with previously reported data from Japan. The Welsh sexes showed MCPP analyses that indicated size and shape differences but certain similarities in shape were also evident. Differences with the Japanese data were more marked. MCPP anlysis is a potentially useful anthropmetric technique but requires further statistical development

A frustrated-Lewis-pair approach to catalytic reduction of alkynes to cis-alkenes

Frustrated Lewis pairs are compounds containing both Lewis acidic and Lewis basic moieties, where the formation of an adduct is prevented by steric hindrance. They are therefore highly reactive, and have been shown to be capable of heterolysis of molecular hydrogen, a property that has led to their use in hydrogenation reactions of polarized multiple bonds. Here, we describe a general approach to the hydrogenation of alkynes to cis-alkenes under mild conditions using the unique ansa-aminohydroborane as a catalyst. Our approach combines several reactions as the elementary steps of the catalytic cycle: hydroboration (substrate binding), heterolytic hydrogen splitting (typical frustrated-Lewis-pair reactivity) and facile intramolecular protodeborylation (product release). The mechanism is verified by experimental and computational studies