Emerging giant resonant exciton induced by Ta-substitution in anatase TiO2_{2}: a tunable correlation effect

Titanium dioxide (TiO$_2$) has rich physical properties with potential implications in both fundamental physics and new applications. Up-to-date, the main focus of applied research is to tune its optical properties, which is usually done via doping and/or nano-engineering. However, understanding the role of $d$-electrons in materials and possible functionalization of $d$-electron properties are still major challenges. Herewith, within a combination of an innovative experimental technique, high energy optical conductivity, and of the state-of-the-art {\it ab initio} electronic structure calculations, we report an emerging, novel resonant exciton in the deep ultraviolet region of the optical response. The resonant exciton evolves upon low concentration Ta-substitution in anatase TiO$_{2}$ films. It is surprisingly robust and related to strong electron-electron and electron-hole interactions. The $d$- and $f$- orbitals localization, due to Ta-substitution, plays an unexpected role, activating strong electronic correlations and dominating the optical response under photoexcitation. Our results shed light on a new optical phenomenon in anatase TiO$_{2}$ films and on the possibility of tuning electronic properties by Ta substitution

The Quantum Superstring as a WZNW Model with N=2 Superconformal Symmetry

We present a new development in our approach to the covariant quantization of superstrings in 10 dimensions which is based on a gauged WZNW model. To incorporate worldsheet diffeomorphisms we need the quartet of ghosts (b_{zz},c^{z}, \b_{zz}, \g^{z}) for topological gravity. The currents of this combined system form an N=2 superconformal algebra. The model has vanishing central charge and contains two anticommuting BRST charges, Q_{S}=Q_{W} + \oint \g^{z} b_{zz} + \oint \eta_{z} and Q_{V} = \oint c^{z} \Big(T^{W}_{zz} + {1\over 2} T^{top}_{zz}\Big) + \g^{z} (B^{W}_{zz} + {1\over 2} B^{top}_{zz} \Big), where $\eta_{z}$ is obtained by the usual fermionization of \b_{zz}, \g^{z}. Physical states form the cohomology of $Q_{S}+Q_{V}$, have nonnegative grading, and are annihilated by $b_{0}$ and $\beta_{0}$. We no longer introduce any ghosts by hand, and the formalism is completely Lorentz covariant.Comment: 26 pages, harmvac; major additions and new result

Convergence to equilibrium for many particle systems

The goal of this paper is to give a short review of recent results of the authors concerning classical Hamiltonian many particle systems. We hope that these results support the new possible formulation of Boltzmann's ergodicity hypothesis which sounds as follows. For almost all potentials, the minimal contact with external world, through only one particle of $N$, is sufficient for ergodicity. But only if this contact has no memory. Also new results for quantum case are presented

Superstrings and WZNW Models

We give a brief review of our approach to the quantization of superstrings. New is a covariant derivation of the measure at tree level and a path integral formula for this measure.Comment: 12 pp, LaTeX, Contribution to the QTS3 Conference Proceeding

Sato-Tate equidistribution for families of Hecke-Maass forms on SL(n,R)/SO(n)

We establish the Sato-Tate equidistribution of Hecke eigenvalues on average for families of Hecke--Maass cusp forms on SL(n,R)/SO(n). For each of the principal, symmetric square and exterior square L-functions we verify that the families are essentially cuspidal and deduce the level distribution with restricted support of the low-lying zeros. We also deduce average estimates toward Ramanujan