Microstructural and XRD analysis and study of the properties of the system Ti-TiAl-B4C processed under different operational conditions

High specific modulus materials are considered excellent for the aerospace industry. The system Ti-TiAl-B4C is presented herein as an alternative material. Secondary phases formed in situ during fabrication vary depending on the processing conditions and composition of the starting materials. The final behaviors of these materials are therefore difficult to predict. This research focuses on the study of the system Ti-TiAl-B4C, whereby relations between microstructure and properties can be predicted in terms of the processing parameters of the titanium matrix composites (TMCs). The powder metallurgy technique employed to fabricate the TMCs was that of inductive hot pressing (iHP) since it offers versatility and flexibility. The short processing time employed (5 min) was set in order to test the temperature as a major factor of influence in the secondary reactions. The pressure was also varied. In order to perform this research, not only were X-Ray Diffraction (XRD) analyses performed, but also microstructural characterization through Scanning Electron Microscopy (SEM). Significant results showed that there was an inflection temperature from which the trend to form secondary compounds depended on the starting material used. Hence, the addition of TiAl as an elementary blend or as prealloyed powder played a significant role in the final behavior of the TMCs fabricated, where the prealloyed TiAl provides a better precursor of the formation of the reinforcement phases from 1100 °C regardless of the pressur

Nickel base coating alloy

Zirconium is added to a Ni-30 Al (beta) intermetallic alloy in the range of 0.05 w/o to 0.25 w/o. This addition is made during melting or by using metal powders. The addition of zirconium improves the cyclic oxidation resistance of the alloys at temperatures above 1100 C

Flow stress and hot deformation activation energy of 6082 aluminium alloy influenced by initial structural state

Stress-strain curves of the EN AW 6082 aluminium alloy with 1.2 Si-0.51 Mg-0.75 Mn (wt.%) were determined by the uniaxial compression tests at temperatures of 450-550 degrees C with a strain rate of 0.5-10 s(-1). The initial structure state corresponded to three processing types: as-cast structure non-homogenized or homogenized at 500 degrees C, and the structure after homogenization and hot extrusion. Significantly higher flow stress appeared as a result of low temperature forming of the non-homogenized material. Hot deformation activation energy Q-values varied between 99 and 122 kJ.mol(-1) for both homogenized materials and from 200 to 216 kJ.mol(-1) for the as-cast state, while the Q-values calculated from the measured steady-state stress were always higher than those calculated from the peak stress values. For the extruded state of the 6082 alloy, the physically-based model was developed to reliably predict the flow stress influenced by dynamic softening, temperature, strain rate, and true strain up to 0.6.Web of Science912art. no. 124

Method of fabricating a twisted composite superconductor

A method of producing a twisted, stabilized wire or tube superconductor which can be used to wind electromagnets, armatures, rotors, field windings for motors and generators, and other magnetic devices which use a solenoid, toroidal, or other type winding is reported. At least one groove is formed along the length of a wire substrate which is then twisted into a helix and a layer of intermetallic superconducting material is formed in the groove. This layer can be formed by depositing the desired intermetallic compound into the groove or by diffusing one component of the superconductor into the groove formed in a substrate composed of the other component. The superconductor prepared by this method comprises a non-superconductor wire twisted into the shape of a helix, having at least one groove containing a layer of superconductor material along the length of the wire

Study of defect formation in Al 7050 alloys

The Al 7050 alloy is an Al-Zn-Mg-Cu-Zr alloy having good mechanical properties. This alloy has been developed in order to overcome stress corrosion cracking problems that characterise 7xxx Al alloys. Despite Al 7050 is widely used for aerospace applications, it can be subjected to crack initiation and propagation during the manufacturing process. In this work cracked Al 7050 components have been analysed in order to identify possible causes of crack formation such as coarse intermetallic phase presence, voids or wrong mechanical machining processes

Hydrogen solubility in zirconium intermetallic second phase particles

The enthalpies of solution of H in Zr binary intermetallic compounds formed with Cu, Cr, Fe, Mo, Ni, Nb, Sn and V were calculated by means of density functional theory simulations and compared to that of H in {\alpha}-Zr. It is predicted that all Zr-rich phases (formed with Cu, Fe, Ni and Sn), and those phases formed with Nb and V, offer lower energy, more stable sites for H than {\alpha}-Zr. Conversely, Mo and Cr containing phases do not provide preferential solution sites for H. In all cases the most stable site for H are those that offer the highest coordination fraction of Zr atoms. Often these are four Zr tetrahedra but not always. Implications with respect to H-trapping properties of commonly observed ternary phases such as Zr(Cr,Fe)2, Zr2(Fe,Ni) and Zr(Nb,Fe)2 are also discussed.Comment: manuscript accepted for publication in Journal of Nuclear Materials (2013

Palladium-bismuth intermetallic and surface-poisoned catalysts for the semi-hydrogenation of 2-methyl-3-butyn-2-ol

The effects of poisoning of Pd catalysts with Bi and annealing in a polyol (ethylene glycol) were studied on the semi-hydrogenation of 2-methyl-3-butyn-2-ol (MBY). An increase in the Pd:Bi ratio from 7 to 1 in the Bi-poisoned catalysts decreased the hydrogenation activity due to blocking of active sites, but increased maximum alkene yield from 91.5% for the Pd catalyst to 94–96% for all Bi-poisoned Pd catalysts, by decreasing the adsorption energy of alkene molecules and suppressing the formation of β-hydride phase. Annealing of the catalysts induced the formation of intermetallic phases and decreased its activity due to sintering of the catalytic particles and low activity of intermetallic compounds. Langmuir–Hinshelwood kinetic modelling of the experimental data showed that poisoning of Pd with Bi changed the relative adsorption constants of organic species suggesting ligand effects at high Bi content

Microstructural characterisation and thermal stability of an Mg-Al-Sr alloy prepared by rheo-diecasting

A commercial Mg-6Al-2Sr (AJ62) alloy has been prepared by a semisolid rheo-diecasting (RDC) process. The microstructure of the RDC alloy exhibits typical semisolid solidification features, i.e., 8.4 vol% primary α-Mg globules (23 μm in diameter), formed in the slurry maker at the primary solidification stage, uniformly distributed in the matrix of fine α-Mg grain size (8.2 μm) and intergranular eutectic Al4Sr lamellae, which resulted from secondary solidification inside the die. A ternary Mg-Al-Sr phase was also observed. Heat treatment revealed the extreme thermal stability of the RDC AJ62 alloy. The hardness showed little change up to 12 hours at 450°C, whilst the Al4Sr eutectic lamellae were broken up, spheroidised and coarsened during the annealing. The RDC alloy offers superior mechanical properties, especially ductility, over the same alloy produced by high pressure die-casting