12,255 research outputs found

    EBSD mapping of herringbone domain structures in tetragonal piezoelectrics

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    Herringbone domain structures have been mapped using electron backscatter diffraction (EBSD) in two tetragonal piezoelectrics, lead zirconate titanate, [Pb(Zr,Ti)O<sub>3</sub>] and bismuth ferrite – lead titanate, [(PbTi)<sub>0.5</sub>(BiFe)<sub>0.5</sub>O<sub>3</sub>]. Analysis of the domain misorientations across the band junctions shows that the structures correspond very well to crystallographic models. High resolution mapping with a 20 nm step size allowed the crystal rotation across one of these band junctions in lead zirconate titanate to be studied in detail and allowed an improved estimation of the peak strain at the junction, of 0.56 GPa. The significance of this for crack nucleation and propagation in such materials is discussed

    Charge transport through a single molecule of trans-1-bis-diazofluorene [60]fullerene

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    Fullerenes have attracted interest for their possible applications in various electronic, biological, and optoelectronic devices. However, for efficient use in such devices, a suitable anchoring group has to be employed that forms well-defined and stable contacts with the electrodes. In this work, we propose a novel fullerene tetramalonate derivate functionalized with trans-1 4,5-diazafluorene anchoring groups. The conductance of single-molecule junctions, investigated in two different setups with the mechanically controlled break junction technique, reveals the formation of molecular junctions at three conductance levels. We attribute the conductance peaks to three binding modes of the anchoring groups to the gold electrodes. Density functional theory calculations confirm the existence of multiple binding configurations and calculated transmission functions are consistent with experimentally determined conductance values.Comment: 22 pages, 6 figure

    Craquelure as a Graph: Application of Image Processing and Graph Neural Networks to the Description of Fracture Patterns

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    Cracks on a painting is not a defect but an inimitable signature of an artwork which can be used for origin examination, aging monitoring, damage identification, and even forgery detection. This work presents the development of a new methodology and corresponding toolbox for the extraction and characterization of information from an image of a craquelure pattern. The proposed approach processes craquelure network as a graph. The graph representation captures the network structure via mutual organization of junctions and fractures. Furthermore, it is invariant to any geometrical distortions. At the same time, our tool extracts the properties of each node and edge individually, which allows to characterize the pattern statistically. We illustrate benefits from the graph representation and statistical features individually using novel Graph Neural Network and hand-crafted descriptors correspondingly. However, we also show that the best performance is achieved when both techniques are merged into one framework. We perform experiments on the dataset for paintings' origin classification and demonstrate that our approach outperforms existing techniques by a large margin.Comment: Published in ICCV 2019 Workshop

    Characterisation of spatial network-like patterns from junctions' geometry

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    We propose a new method for quantitative characterization of spatial network-like patterns with loops, such as surface fracture patterns, leaf vein networks and patterns of urban streets. Such patterns are not well characterized by purely topological estimators: also patterns that both look different and result from different morphogenetic processes can have similar topology. A local geometric cue -the angles formed by the different branches at junctions- can complement topological information and allow to quantify the large scale spatial coherence of the pattern. For patterns that grow over time, such as fracture lines on the surface of ceramics, the rank assigned by our method to each individual segment of the pattern approximates the order of appearance of that segment. We apply the method to various network-like patterns and we find a continuous but sharp dichotomy between two classes of spatial networks: hierarchical and homogeneous. The first class results from a sequential growth process and presents large scale organization, the latter presents local, but not global organization.Comment: version 2, 14 page

    Detecting the presence of large buildings in natural images

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    This paper addresses the issue of classification of lowlevel features into high-level semantic concepts for the purpose of semantic annotation of consumer photographs. We adopt a multi-scale approach that relies on edge detection to extract an edge orientation-based feature description of the image, and apply an SVM learning technique to infer the presence of a dominant building object in a general purpose collection of digital photographs. The approach exploits prior knowledge on the image context through an assumption that all input images are ïżœoutdoorïżœ, i.e. indoor/outdoor classification (the context determination stage) has been performed. The proposed approach is validated on a diverse dataset of 1720 images and its performance compared with that of the MPEG-7 edge histogram descriptor

    Conductance of Atomic-Sized Lead Contacts in an Electrochemical Environment

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    Atomic-sized lead (Pb) contacts are deposited and dissolved in an electrochemical environment, and their transport properties are measured. Due to the electrochemical fabrication process, we obtain mechanically unstrained contacts and conductance histograms with sharply resolved, individual peaks. Charge transport calculations based on density functional theory (DFT) for various ideal Pb contact geometries are in good agreement with the experimental results. Depending on the atomic configuration, single-atom-wide contacts of one and the same metal yield very different conductance values.Comment: 5 pages, 4 figure

    Transition from tunneling to direct contact in tungsten nanojunctions

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    We apply the mechanically controllable break junctions technique to investigate the transition from tunneling to direct contact in tungsten. This transition is quite different from that of other metals and is determined by the local electronic properties of the tungsten surface and the relief of the electrodes at the point of their closest proximity. The conductance traces show a rich variety of patterns from the avalanche-like jump to a mesoscopic contact to the completely smooth transition between direct contact and tunneling. Due to the occasional absence of an adhesive jump the conductance of the contact can be continuously monitored at ultra-small electrode separations. The conductance histograms of tungsten are either featureless or show two distinct peaks related to the sequential opening of spatially separated groups of conductance channels. The role of surface states of tungsten and their contribution to the junction conductance at sub-Angstrom electrode separations are discussed.Comment: 6 pages, 6 figure

    Correlating Cell Behavior with Tissue Topology in Embryonic Epithelia

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    Measurements on embryonic epithelial tissues in a diverse range of organisms have shown that the statistics of cell neighbor numbers are universal in tissues where cell proliferation is the primary cell activity. Highly simplified non-spatial models of proliferation are claimed to accurately reproduce these statistics. Using a systematic critical analysis, we show that non-spatial models are not capable of robustly describing the universal statistics observed in proliferating epithelia, indicating strong spatial correlations between cells. Furthermore we show that spatial simulations using the Subcellular Element Model are able to robustly reproduce the universal histogram. In addition these simulations are able to unify ostensibly divergent experimental data in the literature. We also analyze cell neighbor statistics in early stages of chick embryo development in which cell behaviors other than proliferation are important. We find from experimental observation that cell neighbor statistics in the primitive streak region, where cell motility and ingression are also important, show a much broader distribution. A non-spatial Markov process model provides excellent agreement with this broader histogram indicating that cells in the primitive streak may have significantly weaker spatial correlations. These findings show that cell neighbor statistics provide a potentially useful signature of collective cell behavior.Comment: PLoS one 201
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