Wood-Inspired Morphologically Tunable Aligned Hydrogel for High-Performance Flexible All-Solid-State Supercapacitors

Oriented microstructures are widely found in various biological systems for multiple functions. Such anisotropic structures provide low tortuosity and sufficient surface area, desirable for the design of high-performance energy storage devices. Despite significant efforts to develop supercapacitors with aligned morphology, challenges remain due to the predefined pore sizes, limited mechanical flexibility, and low mass loading. Herein, a wood-inspired flexible all-solid-state hydrogel supercapacitor is demonstrated by morphologically tuning the aligned hydrogel matrix toward high electrode-materials loading and high areal capacitance. The highly aligned matrix exhibits broad morphological tunability (47–12 µm), mechanical flexibility (0°–180° bending), and uniform polypyrrole loading up to 7 mm thick matrix. After being assembled into a solid-state supercapacitor, the areal capacitance reaches 831 mF cm−2 for the 12 µm matrix, which is 259% times of the 47 µm matrix and 403% times of nonaligned matrix. The supercapacitor also exhibits a high energy density of 73.8 µWh cm−2, power density of 4960 µW cm−2, capacitance retention of 86.5% after 1000 cycles, and bending stability of 95% after 5000 cycles. The principle to structurally design the oriented matrices for high electrode material loading opens up the possibility for advanced energy storage applications

Superseismic Loading and Shock Polars: An Example of Fluid-Solid Coupling

We propose a two-dimensional problem involving fluid-solid coupling where a solution is given in closed form. The upper half of the domain is modeled as an isotropic solid; the lower part as a compressible gas. The loading of the solid at the fluid-solid boundary is called superseismic when its speed is larger than the speed of propagation of disturbances in the bulk of the material. The loading is modeled by a shock coupled to the deformation of the boundary. The problem is relevant to high explosive applications, since it is very similar to the interaction between an explosive and the casing in a cylinder test experiment. Within this framework, we show the existence of self-similar solutions in the reference frame moving with the shock wave

Composite nanostructured solid-acid fuel-cell electrodes via electrospray deposition

Stable, porous, nanostructured composite electrodes were successfully fabricated via the inexpensive and scalable method of electrospray deposition, in which a dissolved solute is deposited onto a substrate using an electric field to drive droplet migration. The desirable characteristics of high porosity and high surface area were obtained under conditions that favored complete solvent evaporation from the electrospray droplets prior to contact with the substrate. Solid acid (CsH_2PO_4) feature sizes of 100 nm were obtained from electrosprayed water–methanol solutions with 10 g L^(−1) CsH_2PO_4 and 5 g L^(−1) Pt catalyst particles suspended using polyvinylpyrrolidone (PVP). Alternative additives such as Pt on carbon and carbon-nanotubes (CNTs) were also successfully incorporated by this route, and in all cases the PVP could be removed from the electrode by oxygen plasma treatment without damage to the structure. In the absence of additives (Pt, Pt/C and CNTs), the feature sizes were larger, 300 nm, and the structure morphologically unstable, with significant coarsening evident after exposure to ambient conditions for just two days. Electrochemical impedance spectroscopy under humidified hydrogen at 240 °C indicated an interfacial impedance of ~1.5 Ω cm^2 for the Pt/CsH_2PO_4 composite electrodes with a total Pt loading of 0.3 ± 0.2 mg cm^(−2). This result corresponds to a 30-fold decrease in Pt loading relative to mechanically milled electrodes with comparable activity, but further increases in activity and Pt utilization are required if solid acid fuel cells are to attain widespread commercial adoption

Advances in solid polymer electrolyte fuel cell technology with low-platinum-loading electrodes

The Gemini Space program demonstrated the first major application of fuel cell systems. Solid polymer electrolyte fuel cells were used as auxiliary power sources in the spacecraft. There has been considerable progress in this technology since then, particularly with the substitution of Nafion for the polystyrene sulfonate membrane as the electrolyte. Until recently the performance was good only with high platinum loading (4 mg/sq cm) electrodes. Methods are presented to advance the technology by (1) use of low platinum loading (0.35 mg/sq cm) electrodes; (2) optimization of anode/membrane/cathode interfaces by hot pressing; (3) pressurization of reactant gases, which is most important when air is used as cathodic reactant; and (4) adequate humidification of reactant gases to overcome the water management problem. The high performance of the fuel cell with the low loading of platinum appears to be due to the extension of the three dimensional reaction zone by introduction of a proton conductor, Nafion. This was confirmed by cyclic voltammetry

Optimisation of fractal spaceframes under gentle compressive load

The principle of hierarchical design is a prominent theme in many natural systems where mechanical efficiency is of importance. Here we establish the properties of a particular hierarchical structure, showing that high mechanical efficiency is found in certain loading regimes. We show that in the limit of gentle loading, the optimal hierarchical order increases without bound. We show that the scaling of material required for stability against loading to be withstood can be altered in a systematic, beneficial manner through manipulation of the number of structural length scales optimised upon. We establish the relationship between the Hausdorff dimension of the optimal structure and loading for which the structure is optimised. Practicalities of fabrication are discussed and examples of hierarchical frames of the same geometry constructed from solid beams are shown.Comment: 8 pages, 6 figure

Hybrid Organic−Inorganic Solids That Show Shape Selectivity

Hybrid organic−inorganic solids featuring millimolar/gram concentrations of intracrystalline organic moieties and shape-selectivity are synthesized. Pure-silica zeolite beta crystals are coated with zirconia and treated in aqueous sodium hydroxide to create defects and mesoporosity within the crystalline structure. Aminopropyl organic groups are subsequently grafted onto the generated intracrystalline silanol groups. After grafting, characterization data indicate a high organic concentration localized primarily within the intracrystalline voids. Specifically, thermogravimetric analysis shows an organic loading of 0.7 mmol of NH_2/g, ^(29)Si solid-state nuclear magnetic resonance (NMR) spectra display a quantitative decrease in Q^3 silicon atoms with a corresponding resharpening of the Q^4 resonances, and N_2 adsorption data show a decrease in micropore volume to 0.10 cm^3/g. Knoevenagel condensation reactions are catalyzed by the aminopropyl-functionalized materials using differently sized aldehydes and the results show that the zirconia-protected functionalized solid have shape selective properties

Manipulation of Spherical Droplets on a Liquid Platform Using Thermal Gradients

In the recent years, there has been a growing interest in droplet-based (digital) microfluidics for which, reliable means of droplet manipulation are required. In this study we demonstrate thermal actuation of droplets on liquid platforms, which is ideal for biochemical microsystems and lab-on-chip applications because droplets can be transported with high speed, good control and minimal thermal loading as compared to using conventional solid substrates. In addition, other disadvantages of using solid surfaces such as evaporation, contamination, pinning, hysteresis and irreversibility of droplet motion are avoided. Based on the theoretical development and measurements, a silicon-based droplet transportation platform was developed with embedded Titanium micro heaters. A shallow liquid pool of inert liquid (FC-43) served as the carrier liquid. Heaters were interfaced with control electronics and driven through a computer graphical user interface. By creating appropriate spatio-temporal thermal gradient maps, transport of droplets on predetermined pathways was successfully demonstrated with high level of robustness, speed and reliability. The video shows normal imaging of droplet manipulation accompanied by the corresponding infrared thermal imaging showing the spatio-temporal temperature maps and the outline of the drop as it moves towards hot spots.Comment: 63rd APS - Division of Fluid Dynamics - 201

Clarification Of Aqueous Suspensions With A High Content Of Suspended Solids In Rapid Sand Filters

The presented work is devoted to solving the actual problem of increasing the efficiency of rapid sand filters with granular filling, which operate at a constant filtration rate when cleaning suspensions with a relatively high concentration of contaminants. The proposed mathematical model for clarifying the suspension by filtration consists of three interconnected blocks: clarified, filtration, and hydraulic. Convenient dimensionless mathematical dependencies are obtained for calculating the concentrations of contaminants and sediment from the height of the filter and suspension in the filtrate; head loss in the filter loading; the effective time of the filter (the duration of the filter cycle). The design of the experimental setup and the methodology for conducting experimental studies and mathematical processing of the results are valid. The results of experimental studies of the suspension filtering process through the granular loading are presented, and the obtained data is analyzed. Measurement of pressure losses in the filter loading is performed when a suspension is passed with a relatively high concentration of contaminants at various filtration rates. The nature of the change in the filtration rate with time and height (length) loading at various filtration rates and initial contamination concentrations is determined. Measured variable concentration of suspended matter in filtered water and retained contamination over time. As a result of the experiments, it is confirmed that an increase in the concentration of retained contaminants S leads to an increase in the parameter Δn/n. Upon reaching a certain value of the concentration of the retained sediment S (in our case S=30 g/dm3), an increase in the relative specific volume of the sediment greater than Δn/n0=0.65 is not observed. It is established that an important characteristic of the retained sediment is the ratio of the volume concentration of the sediment to the volume concentration of solid particles in this sediment γ=Csd/Сs. The values of the adhesion and detachment of particles of contaminant in the particles of the material loading =4,9; =0,009. The results of experimental studies in general confirm the correctness and reliability of the obtained analytical dependencies

Catalytic Wet Air Oxidation of Aqueous Organic Mixtures

Catalytic Wet Air Oxidation (CWAO) has been investigated for the treatment of water contaminated by 4-hydroxybenzoic acid (4HBA) and equimolar mixture of phenol-4HBA. Both batch measurements for kinetics determination and continuous fixed bed operation have been performed on the same Activated Carbon (AC). After a fast initial deactivation AC was proved stable and efficient at moderate temperature and oxygen pressure, like for phenol degradation. The kinetic study in the case of highly adsorbing material as AC may require complex approach to account for the variation of adsorbed reactants during batch oxidation. Adsorption isotherms at reaction temperature and with aged AC have been obtained according to Langmuir equation and used in 4HBA mass balance to derive more significant kinetic parameters. At high catalyst loading and relatively low pollutant concentration, the variation of 4HBA during the batch may be even higher on the solid than in the aqueous phase