Two-dimensional mapping of triaxial strain fields in a multiferroic BiFeO3 thin film using scanning x-ray microdiffraction

The dramatically enhanced polarizations and saturation magnetizations observed in the epitaxially constrained BiFeO3 (BFO) thin films with their pronounced grain-orientation dependence have attracted much attention and are attributed largely to the constrained in-plane strain. Thus, it is highly desirable to directly obtain information on the two-dimensional (2D) distribution of the in-plane strain and its correlation with the grain orientation of each corresponding microregion. Here the authors report a 2D quantitative mapping of the grain orientation and the local triaxial strain field in a 250 nm thick multiferroic BFO film using a synchrotron x-ray microdiffraction technique. This direct scanning measurement demonstrates that the deviatoric component of the in-plane strain tensor is between 5x10(-3) and 6x10(-3) and that the local triaxial strain is fairly well correlated with the grain orientation in that particular region. (c) 2007 American Institute of Physics.X1145Nsciescopu

Effect of local anisotropy on fatigue crack initiation in a coarse grained nickel-base superalloy

In the present work, theoretical approaches, based on grain orientation dependent Young's modulus and Schmid factor are used to describe the influence of local grain orientation on crack initiation behaviour of the coarse grained nickel base superalloy Ren\'e80. Especially for strongly anisotropic crystal structures with large grain size, such as the investigated material, the local elastic properties must be taken into account for assessment of fatigue crack initiation. With an extension of Schmid's law, the resulting shear stress amplitude, which triggers local cyclic plastic deformation, can be calculated depending on local Young's modulus and Schmid factor. A Monte Carlo simulation with 100,000 samples shows how random grain orientation affects these parameters. Furthermore, the product of Young's modulus and Schmid factor (called $E\cdot m$) is used as a parameter to determine how grain orientation influences resulting shear stress amplitude for given total strain amplitude. In addition to the theoretical work using that approach, this model is also validated using isothermal LCF experiments by determining local grain orientation influence on the crack initiation site using SEM-EBSD analyses.Comment: 8 pages, 8 figure

Grain orientation in high Tc superconductors by molten salt powder synthesis

The molten salt or the flux method is used to fabricate a grain oriented YBa2Cu3O(7-x) (123) superconductor. Here we suggest a two-stage approach in using the 'green phase', Y2BaCuO5 (211), as seed crystals in the formation of YBa2Cu3O(7-x). The process uses Y2BaCuO5 formed by molten salt synthesis. The Y2BaCuO5 phase was observed to be stable in water and in most of the salt systems. Salt processing can form a small quantity of anisotropic particles of Y2BaCuO5. This material can form the 123 phase when tape cast and sintered in the presence of the required levels of Ba and Cu

Energy conserving Anisotropic Anhysteretic Magnetic Modelling for Finite Element Analysis

To model ferromagnetic material in finite element analysis a correct description of the constitutive relationship (BH-law) must be found from measured data. This article proposes to use the energy density function as a centrepiece. Using this function, which turns out to be a convex function of the flux density, guarantees energy conservative modelling. The magnetic field strength can be seen as a derivative with respect to the flux density. Especially for anisotropic materials (from lamination and/or grain orientation) this method has advantages. Strictly speaking this method is only valid for anhysteretic and thermodynamically stable material

Penetration Depth and Anisotropy in MgB2

The penetration depth lambda of MgB2 was deduced from both the ac susceptibility chi and the magnetization M(H) of sorted powders. The good agreement between the two sets of data without geometric correction for the grain orientation suggests that MgB2 is an isotropic superconductor.Comment: 9 pages, 5 figures; submitted to Physical Review B (February 28, 2001; revised June 28, 2001); reference list update

TEM study of the AlN grain orientation grown on NCD diamond substrate

Piezoelectric AlN layer grain orientation, grown by room temperature reactive sputtering, is analyzed by transmission electron microscopy (TEM).Two types of samples are studied: (i) AlN grown on well-polished NCD (nano-crystalline diamond) diamond, (ii) AlN grown on an up-side down NCD layer previously grown on a Si substrate, i.e. diamond surface as smooth as that of Si substrates. The second set of sample show a faster lignment of their AlN grain caxis attributed to it smoother diamond free surface. No grain orientation relationship between diamond substrate grain and the AlN ones is evidenced, which seems to indicate the preponderance role of the surface substrate state