Addressing the challenges of modeling the scattering from bottlebrush polymers in solution

Small‐angle scattering measurements of complex macromolecules in solution are used to establish relationships between chemical structure and conformational properties. Interpretation of the scattering data requires an inverse approach where a model is chosen and the simulated scattering intensity from that model is iterated to match the experimental scattering intensity. This raises challenges in the case where the model is an imperfect approximation of the underlying structure, or where there are significant correlations between model parameters. We examine three bottlebrush polymers (consisting of polynorbornene backbone and polystyrene side chains) in a good solvent using a model commonly applied to this class of polymers: the flexible cylinder model. Applying a series of constrained Monte‐Carlo Markov Chain analyses demonstrates the severity of the correlations between key parameters and the presence of multiple close minima in the goodness of fit space. We demonstrate that a shape‐agnostic model can fit the scattering with significantly reduced parameter correlations and less potential for complex, multimodal parameter spaces. We provide recommendations to improve the analysis of complex macromolecules in solution, highlighting the value of Bayesian methods. This approach provides richer information for understanding parameter sensitivity compared to methods which produce a single, best fit

The Arecibo HII Region Discovery Survey

We report the detection of radio recombination line emission (RRL) using the Arecibo Observatory at X-band (9GHz, 3cm) from 37 previously unknown HII regions in the Galactic zone 66 deg. > l > 31 deg. and |b| < 1 deg. This Arecibo HII Region Discovery Survey (Arecibo HRDS) is a continuation of the Green Bank Telescope (GBT) HRDS. The targets for the Arecibo HRDS have spatially coincident 24 micron and 20 cm emission of a similar angular morphology and extent. To take advantage of Arecibo's sensitivity and small beam size, sources in this sample are fainter, smaller in angle, or in more crowded fields compared to those of the GBT HRDS. These Arecibo nebulae are some of the faintest HII regions ever detected in RRL emission. Our detection rate is 58%, which is low compared to the 95% detection rate for GBT HRDS targets. We derive kinematic distances to 23 of the Arecibo HRDS detections. Four nebulae have negative LSR velocities and are thus unambiguously in the outer Galaxy. The remaining sources are at the tangent point distance or farther. We identify a large, diffuse HII region complex that has an associated HI and 13CO shell. The ~90 pc diameter of the G52L nebula in this complex may be the largest Galactic HII region known, and yet it has escaped previous detection.Comment: Accepted to ApJ Data can be found here: http://go.nrao.edu/hrd

Brane Mediated Supersymmetry Breaking

We propose a mechanism for mediating supersymmetry breaking in Type I string constructions. The basic set-up consists of a system of three D-branes: two parallel D-branes, a matter D-brane and a source D-brane, with supersymmetry breaking communicated via a third D-brane, the mediating D-brane, which intersects both of the parallel D-branes. We discuss an example in which the first and second family matter fields correspond to open strings living on the intersection of the matter D-brane and mediating D-brane, while the gauge fields, Higgs doublets and third family matter fields correspond to open strings living on the mediating D-brane. As in gaugino mediated models, the gauginos and Higgs doublets receive direct soft masses from the source brane, and flavour-changing neutral currents are naturally suppressed since the first and second family squarks and sleptons receive suppressed soft masses. However, unlike the gaugino mediated model, the third family squarks and sleptons receive unsuppressed soft masses, resulting in a very distinctive spectrum with heavier stops, sbottoms and staus.Comment: Version to appear in Nucl.Phys.B. 28 pages, Late