Effects of stretching on the frictional stress of rubber

In this paper, we report on new experimental results on the effects of in-plane surface stretching on the friction of Poly(DiMethylSiloxane) (PDMS) rubber with smooth rigid probes. Friction-induced displacement fields are measured at the surface of the PDMS substrate under steady-state sliding. Then, the corresponding contact pressure and frictional stress distributions are determined from an inversion procedure. Using this approach, we show that the local frictional stress $\tau$ is proportional to the local stretch ratio $\lambda$ at the rubber surface. Additional data using a triangular flat punch indicate that $\tau(\lambda)$ relationship is independent on the contact geometry. From friction experiments using pre-stretched PDMS substrate, it is also found that the stretch-dependence of the frictional stress is isotropic, i.e. it does not depend on the angle between stretching and sliding directions. Potential physical explanations for this phenomenon are provided within the framework of Schallamach's friction model. Although the present experiments are dealing with smooth contact interfaces, the reported $\tau(\lambda)$ dependence is also relevant to the friction of statistically rough contact interfaces, while not accounted for in related contact mechanics models

The Intimate Relationship between Cavitation and Fracture

Nearly three decades ago, the field of mechanics was cautioned of the obscure nature of cavitation processes in soft materials [Gent, A.N., 1990. Cavitation in rubber: a cautionary tale. Rubber Chemistry and Technology, 63(3)]. Since then, the debate on the mechanisms that drive this failure process is ongoing. Using a high precision volume controlled cavity expansion procedure, this paper reveals the intimate relationship between cavitation and fracture. Combining a Griffith inspired formulation for crack propagation, and a Gent inspired formulation for cavity expansion, we show that despite the apparent complexity of the fracture patterns, the pressure-volume response follows a predictable path. In contrast to available studies, both the model and our experiments are able to track the entire process including the unstable branch, by controlling the volume of the cavity. Moreover, this minimal theoretical framework is able to explain the ambiguity in previous experiments by revealing the presence of metastable states that can lead to first order transitions at onset of fracture. The agreement between the simple theory and all of the experimental results conducted in PDMS samples with shear moduli in the range of 25-246 [kPa], confirms that cavitation and fracture work together in driving the expansion process. Through this study we also determine the fracture energy of PDMS and show its significant dependence on strain stiffening

Leak-rate of seals: comparison of theory with experiment

Seals are extremely useful devices to prevent fluid leakage. We present experimental results for the leak-rate of rubber seals, and compare the results to a novel theory, which is based on percolation theory and a recently developed contact mechanics theory. We find good agreement between theory and experiment.Comment: 6 pages, 10 figure

Interfacial separation between elastic solids with randomly rough surfaces: comparison of experiment with theory

We study the average separation between an elastic solid and a hard solid with a nominal flat but randomly rough surface, as a function of the squeezing pressure. We present experimental results for a silicon rubber (PDMS) block with a flat surface squeezed against an asphalt road surface. The theory shows that an effective repulse pressure act between the surfaces of the form p proportional to exp(-u/u0), where u is the average separation between the surfaces and u0 a constant of order the root-mean-square roughness, in good agreement with the experimental results.Comment: 6 pages, 10 figure

Cracks in rubber under tension exceed the shear wave speed

The shear wave speed is an upper limit for the speed of cracks loaded in tension in linear elastic solids. We have discovered that in a non-linear material, cracks in tension (Mode I) exceed this sound speed, and travel in an intersonic range between shear and longitudinal wave speeds. The experiments are conducted in highly stretched sheets of rubber; intersonic cracks can be produced simply by popping a balloon.Comment: 4 pages, 5 eps figure

Dynamics of Simple Cracks

Cracks are the major vehicle for material failure, and often exhibit rather complex dynamics. The laws that govern their motion have remained an object of constant study for nearly a century. The simplest kind of dynamic crack is a single crack that moves along a straight line. We first briefly review current understanding of this "simple" object. We then critically examine the assumptions of the classic, scale-free, theory of dynamic fracture, and note when it works and how it may fail if certain of these assumptions are relaxed. A number of examples is provided, where the introduction of physical scales into this scale-free theory profoundly affects both a crack's structure and the resulting dynamics.Comment: 36 pages, 8 figures, a review paper submitted to "Annual Review of Condensed Matter Physics

Contact mechanics for randomly rough surfaces

When two solids are squeezed together they will in general not make atomic contact everywhere within the nominal (or apparent) contact area. This fact has huge practical implications and must be considered in many technological applications. In this paper I briefly review basic theories of contact mechanics. I consider in detail a recently developed contact mechanics theory. I derive boundary conditions for the stress probability distribution function for elastic, elastoplastic and adhesive contact between solids and present numerical results illustrating some aspects of the theory. I analyze contact problems for very smooth polymer (PMMA) and Pyrex glass surfaces prepared by cooling liquids of glassy materials from above the glass transition temperature. I show that the surface roughness which results from the frozen capillary waves can have a large influence on the contact between the solids. The analysis suggest a new explanation for puzzling experimental results [L. Bureau, T. Baumberger and C. Caroli, arXiv:cond-mat/0510232] about the dependence of the frictional shear stress on the load for contact between a glassy polymer lens and flat substrates. I discuss the possibility of testing the theory using numerical methods, e.g., finite element calculations.Comment: Review paper, 29 pages, 31 picture

Shock wave theory for rupture of rubber

This article presents a theory for the rupture of rubber. Unlike conventional cracks, ruptures in rubber travel faster than the speed of sound, and consist in two oblique shocks that meet at a point. Physical features of rubber needed for this phenomenon include Kelvin dissipation and an increase of toughness as rubber retracts. There are three levels of theoretical description: an approximate continuum theory, an exact analytical solution of a slightly simplified discrete problem, and numerical solution of realistic and fully nonlinear equations of motion.Comment: 4 pages and 2 figure