Valorisation of cork by-products for the treatment of vegetal and animal oil containing wastewaters

In this study, cork granules, which are by-products of the cork processing industry, were used as biosorbents for the removal of vegetable and animal oils from water. Simple oil-in-water emulsions were created by ultrasonic emulsification and batch adsorption tests were performed by contacting cork with these emulsions for a defined period of time. A mass transfer model was able to predict adequately the kinetic data, using a Linear Driving Force approximation for intraparticle diffusion and equilibrium described by the Langmuir-Freundlich equation. Maximum sorption capacities for vegetable and animal oil, as calculated by the Langmuir-Freundlich model, were 5 ± 4 and 2.3 ± 0.9 g g-1, respectively. Therefore, expanded cork granules proved to be an efficient, low-cost sorbent for both vegetable and animal oilsThis work is supported by project HIDROCORK “Utilization of Cork Wastes and By-Products for Elimination of Oils and Fats from Waters”, supported by QREN (National Strategic Reference Framework). This work is also partially supported by project PEst-C/EQB/LA0020/2011, financed by FEDER through COMPETE -Programa Operacional Factores de Competitividade and by FCT -Fundação para a Ciência e a Tecnologia

Corn cob lightweight concrete for non-structural applications

A lightweight concrete using granulated corn cob (without corn) as an aggregate is proposed in this research work. Taking into account that corn cob, after extracting the corn, is generally considered an agricultural waste, an interesting economic and sustainable benefit may result by using it as a building material. Therefore, it can be an alternative sustainable lightweight aggregate solution in comparison to the most currently applied ones such as expanded clay, particles of cork, particles of expanded polystyrene (EPS), among others. The density, the compressive strength and the thermal insulation properties of a corn cob concrete were experimentally quantified. An expanded clay concrete was also studied as reference. The main results obtained are presented and discussed showing that the proposed corn cob concrete may have the adequate material properties required for a lightweight concrete for non-structural application purposes

Are drought and wildfires turning Mediterranean cork oak forests into persistent shrublands?

In the Iberian Peninsula Mediterranean oak forests have been transformed into a mosaic landscape of four main patch-types: forests, savannas, shrublands and grasslands. We used aerial photographs over a period of 45 years (1958-2002) to quantify the persistence and rates of transitions between vegetation patch-types in southern Portugal, where cork oak is the dominant tree species. We used logistic regression to relate vegetation changes with topographical features and wildfire history. Over the 45 years, shrublands have been the most persistent patch-type (59%), and have been expanding; forests are also persistent (55%) but have been decreasing since 1985; savannas and grasslands were less persistent (33% and 15%, respectively). Shrublands persistence was significantly correlated with wildfire occurrence, particularly on southern exposures after 1995. In contrast, forest persistence decreased with wildfire occurrence, and forests were more likely to change into shrublands where wildfire had occurred after 1995

New applications of cork in building

Several types of prefabricated elements for partitions and extrados, which improve the similar systems presently in the market, are presented in this research. These elements, manufactured with cork and lightened plaster, can be classified in two well defined groups. The first group is formed by lightened plaster panels for partitions of dimensions 60 x 265 cm (width, height) and of 7cm and 10 cm thickness. In the second group, panels for extrados with the same dimensions are included but with a thickness of 9.5 and 5 cm, including the 3 cm thickness of the incorporated high density expanded polystyrene sheet

Polyominoes with nearly convex columns: A model with semidirected blocks

In most of today's exactly solved classes of polyominoes, either all members are convex (in some way), or all members are directed, or both. If the class is neither convex nor directed, the exact solution uses to be elusive. This paper is focused on polyominoes with hexagonal cells. Concretely, we deal with polyominoes whose columns can have either one or two connected components. Those polyominoes (unlike the well-explored column-convex polyominoes) cannot be exactly enumerated by any of the now existing methods. It is therefore appropriate to introduce additional restrictions, thus obtaining solvable subclasses. In our recent paper, published in this same journal, the restrictions just mentioned were semidirectedness and an upper bound on the size of the gap within a column. In this paper, the semidirectedness requirement is made looser. The result is that now the exactly solved subclasses are larger and have greater growth constants. These new polyomino families also have the advantage of being invariant under the reflection about the vertical axis.Comment: 25 pages, 14 figures, 2 table

Determination of the Insulation Solution that Leads to Lower CO2 Emissions during the Construction Phase of a Building

The characteristics of the envelope of a building determine, together with other factors, its consumption of energy. Additionally, the climate zone and insulation material may vary the minimum insulation thickness of walls and roofs, making it different, according to cooling down or warming up the home. Spanish legislation establishes different maximum values for energy demand according to different climate area both for heating and for cooling. This paper presents the results of a study that determines the influence of many variables as the climate zone or the orientation, among others, in the optimization of thickness insulation in residential homes in Spain to reduce the CO2 emissions embodied. To do that, 12 representative cities in Spain corresponding to different climate zones, four orientations, two constructive solutions, and four different configurations of the same house have been combined, for three different hypotheses and four insulation materials, resulting in 4608 cases of study. The results show that, under equal conditions on energy demand, the optimal insulation requirements are determined by heating necessities more than by cooling ones. In addition, a higher insulation thickness need does not necessarily mean more CO2 emissions, since it can be compensated with a lower Global Warming Potential characterization factor that is associated to the insulation material. The findings of this study can serve to designers and architects to establish the better combination of the variables that are involved in order to minimize the CO2 emissions embodied during the construction phase of a building, making it more energy efficient