Observable Dependent Quasi-Equilibrium in Slow Dynamics

We present examples demonstrating that quasi-equilibrium fluctuation-dissipation behavior at short time differences is not a generic feature of systems with slow non-equilibrium dynamics. We analyze in detail the non-equilibrium fluctuation-dissipation ratio X(t,tw) associated with a defect-pair observable in the Glauber-Ising spin chain. It turns out that $X \neq 1$ throughout the short-time regime and in particular X(tw,tw) = 3/4 for $tw \to \infty$. The analysis is extended to observables detecting defects at a finite distance from each other, where similar violations of quasi-equilibrium behaviour are found. We discuss our results in the context of metastable states, which suggests that a violation of short-time quasi-equilibrium behavior could occur in general glassy systems for appropriately chosen observables.Comment: 17 pages, 5 figures; substantially improved version of cond-mat/040571

Generalized Elastic Model: thermal vs non-thermal initial conditions. Universal scaling, roughening, ageing and ergodicity

We study correlation properties of the generalized elastic model which accounts for the dynamics of polymers, membranes, surfaces and fluctuating interfaces, among others. We develop a theoretical framework which leads to the emergence of universal scaling laws for systems starting from thermal (equilibrium) or non-thermal (non-equilibrium) initial conditions. Our analysis incorporates and broadens previous results such as observables' double scaling regimes, (super)roughening and anomalous diffusion, and furnishes a new scaling behavior for correlation functions at small times (long distances). We discuss ageing and ergodic properties of the generalized elastic model in non-equilibrium conditions, providing a comparison with the situation occurring in continuous time random walk. Our analysis also allows to assess which observable is able to distinguish whether the system is in or far from equilibrium conditions in an experimental set-up

Non-equilibrium Anisotropic Phases, Nucleation and Critical Behavior in a Driven Lennard-Jones Fluid

We describe short-time kinetic and steady-state properties of the non--equilibrium phases, namely, solid, liquid and gas anisotropic phases in a driven Lennard-Jones fluid. This is a computationally-convenient two-dimensional model which exhibits a net current and striped structures at low temperature, thus resembling many situations in nature. We here focus on both critical behavior and details of the nucleation process. In spite of the anisotropy of the late--time spinodal decomposition process, earlier nucleation seems to proceed by Smoluchowski coagulation and Ostwald ripening, which are known to account for nucleation in equilibrium, isotropic lattice systems and actual fluids. On the other hand, a detailed analysis of the system critical behavior rises some intriguing questions on the role of symmetries; this concerns the computer and field-theoretical modeling of non-equilibrium fluids.Comment: 7 pages, 9 ps figures, to appear in PR