CO-ELECTROPHORETIC DEPOSITION OF LIQUID METAL AND SILICON FOR LITHIUM-ION BATTERY APPLICATION

A low cost electrophoretic deposition (EPD) process was successfully used for liquid metal thin film deposition with a high depositing rate of 0.6 µ/min. Furthermore, silicon nano-powder and liquid metal were then simultaneously deposited as the negative electrode of lithium-ion battery by a technology called co-EPD. The liquid metal was hoping to act as the matrix for silicon particles during lithium ion insertion and distraction. Half-cell testing was performed using as prepared co-EPD sample. An initial discharge capacity of 1500 mAh/g was reported for nano-silicon and galinstan electrode, although the capacity fading issue of these samples was also observed

Biomaterial Properties of Titanium in Dentistry

Background Among various dental materials and their successful restorative uses, titanium provides an excellent example of integrating science and technology involving multiple disciplines of dentistry including biomaterials, prosthodontics and surgical sciences. Titanium and its alloys have emerged as a material of choice for dental implants fulfilling all requirements biologically, chemically and mechanically. Several excellent reviews have discussed the properties of titanium and its surface characteristics that render it biocompatible. However, in most patients, titanium implants are used alongside several other metals. Presence of different metals in the same oral environment can alter the properties of titanium. Other influencing factors include intra-oral pH, salivary content, and effect of fluorides. Highlight This review discusses the effect of the above-mentioned conditions on the properties of titanium and its alloys. An extensive literature search encompassing the properties of titanium in an altered oral environment and its interaction with other restorative materials is presented. Specific conditions that could cause titanium to corrode, specifically due to interaction with other dental materials used in oral rehabilitation, as well as methods that can be employed for passivation of titanium are discussed. Conclusion This review presents an overview of the properties of titanium that are vital for its use in implant dentistry. From a restorative perspective, interaction between implant restoration metals, intra-oral fluorides and pH may cause titanium to corrode. Therefore, in order to avoid the resulting deleterious effects, an understanding of these interactions is important for long-term prognosis of implant restorations

Electrophoretic deposition of gradated oxidation resistant coatings on tantalum-10 tungsten alloy

Material selection and electrophoretic deposition studies of high temperature oxidation resistant coatings on tantalum-10 tungsten allo

A STUDY OF FACTORS AFFECTING ENTREPRENEURIAL INTENTION: THE MODERATING ROLE OF INDIVIDUALISM

The main purpose of this study is to identify the factors which affect the entrepreneurial intention (EI) of the university students of Gilgit-Baltistan. This research study mainly focuses on the theory of planned behaviour (TPB) and Hofstede national culture dimension of individualism. The quantitative research method was applied for the data analysis. The data were collected from the public sector universities of Gilgit-Baltistan with the total number of 362 final year students. Moreover, to test the hypothesis of the study structural equation modeling (PLS-SEM) version 4.0 software were used for the data analysis and interpretation. The findings of the research are follows: i) attitude towards behaviour positively influence the entrepreneurial intention of the university students ii) subjective norms also significantly affect the entrepreneurial intention iii) perceived behaviour control has a positive effect on the entrepreneurial intention of the university students. However, the moderating variable of individualism does not moderate the relationship between TPB and EI. Moreover, this research study provides a comprehensive research model which includes the behavioural, and culture factors that were analyzed and validated through empirical evidence. It is also one of the pioneer research conducted in the rural areas i.e. Gilgit-Baltistan of Pakistan

Versatile electrochemical coatings and surface layers from aqueous methanesulfonic acid

Ever tightening environmental pressure together with the continued need for coatings able to meet challenging service environments have stimulated advances in coating technology. In the case of electrochemical techniques, the classical techniques of electrodeposition and anodising are being upgraded to meet the need for modern surface engineering coatings (including nanostructured films) on metals. A major challenge is to retain conventional processing, including aqueous solutions, simple power supplies and existing electrolyte tanks while using cost effective, ‘green’ electrolytes. One successful direction has been the emergence of electrolytes based on methanesulfonic acid, MSA which has good electrolytic conductivity and is capable of dissolving many metals as well as acting as a useful medium for dispersion of solids prior to electrophoretic coating. A range of application methods result, including electroplating, anodising and electrophoretic deposition from a stable, aqueous sol. A diverse range of coating materials is emerging, including metals, alloys, porous metal oxide films, conductive polymers and many composites. This review illustrates the usefulness and applications of MSA electrolytes using recent examples from the authors' laboratories and others. Developing coatings, including alternating multilayers of Sn and Cu, nanostructured metals, hierarchical pores, nanotubular metal oxides and graphene composites are briefly considered. This is a review with 94 references

Transforming a compact disk into a simple and cheap photocatalytic nanoreactor

A commercial compact disk has been converted into an effective photocatalytic nanoreactor by depositing a catalyst layer inside the nanochannels by means of an electrophoretic method. The resultant device has been tested for water splitting, obtaining a high yield of hydrogen at an unbeatable low cost.Postprint (published version

Electrophoretic deposition of ferrite

The ability to integrate a material with a high permeability on chip, allows for magnetically coupled circuits and structures to be designed and incorporated along side CMOS circuitry. Devices ranging from A.C. transformers to magnetically driven MEMS structures can be designed and fabricated. Desirable characteristics of magnetic cores for integrated inductors and transformers are first high saturation flux in order to obtain high saturation current; high permeability to obtain high inductance; high resistivity to reduce eddy current loss at high frequencies and compatible deposition and patterning processes. High frequency magnetic materials are oxide based ceramics and are therefore difficult to evaporate, sputter, plate and selectively etched. ElectroPhoretic Deposition (EPD) is a method where insulating particles are imparted charge in a suspension and are made to deposit on an electrode by applying electric field. EPD has been extensively employed in depositing oxide based phosphors for display applications. In this study, ferrite particles have been prepared by grinding sintered toroids and deposited by EPD. The electrophoretic solution bath is composed of isopropyl alcohol with traces of Mg(N03)2 and La(N03)3 salts. Glycerol is added to the solution bath as a surfactant to promote increased substrate adhesion. The dissociation of magnesium nitrate in the solution bath charges the ferrite particles. An electric field of ~ 50-160 V/cm is applied with negative terminal connected to the wafer to be plated and aluminum electrode is used as the anode. The deposition process is found to be self limiting with the initial high elerophoretic current declining to 10% of its value in 10 minutes. The deposition rate and zeta potential measurements indicate a high particle velocity on the order 5.7x10-3 cm/s with an electric field of 160V/cm generated across the 2 cm electrode spacing. Pattern filling and conformal coverage in copper damascene planar microinductors has been investigated. A method to extracted permeability from S11 impedance analysis has been employed. It has been found that grinding process deteriorates magnetic response. With recent advances in magnetic particle technology for high frequency materials, these results enable unique hard and soft powder ferrite material to be selectively deposited in wide variety of CMOS and MEM’s based applications

Immobilizing bacteriorhodopsin on a single electron transistor

As awareness of potential human and environmental impacts from toxins has increased, so has the development of innovative sensors. Bacteriorhodopsin (bR) is a light activated proton pump contained in the purple membrane (PM) of the bacteria Halobacterium salinarum. Bacteriorhodopsin is a robust protein which can function in both wet and dry states and can withstand extreme environmental conditions. A single electron transistor(SET) is a nano-scale device that exploits the quantum mechanical properties of electrons to switch on and off. SETs have tremendous potential in practical applications due to their size, ultra low power requirements, and electrometer-like sensitivity. The main goal of this research was to create a bionanohybrid device by integrating bR with a SET device. This was achieved by a multidisciplinary approach. The SET devices were created by a combination of sputtering, photolithography, and focused ion beam machining. The bionanomaterial bacteriorhodopsin was created through oxidative fermentation and a series of transmembrane purification processes. The bR was then integrated with the SET by electrophoretic deposition, creating a bionanohybrid device. The bionanohybrid device was then characterized using a semiconductor parametric analyzer. Characterization demonstrated that the bR modulated the operational characteristics of the SET when bR was activated with light within its absorbance spectrum. To effectively integrate bacteriorhodopsin with microelectromechanical systems (MEMS) and nanoelectromechanical systems (NEMS), it is critical to know the electrical properties of the material and to understand how it will affect the functionality of the device. Tests were performed on dried films of bR to determine if there is a relationship between inductance, capacitance, and resistance (LCR) measurements and orientation, light-on/off, frequency, and time. The results indicated that the LCR measurements of the bR depended on the thickness and area of the film, but not on the orientation, as with other biological materials such as muscle. However, there was a transient LCR response for both oriented and unoriented bR which depended on light intensity. From the impedance measurements an empirical model was suggested for the bionanohybrid device. The empirical model is based on the dominant electrical characteristics of the bR which were the parallel capacitance and resistance. The empirical model suggests that it is possible to integrate bR with a SET without influencing its functional characteristics

Colloidal Monolayers for Concentration Light in Ultra-Thin Semiconductor Layers

Thin film semiconductors are used as photoconductive absorber layers for the development of broadband terahertz generation. Using a femtosecond laser pulse, the generation of a transient increase in the conductivity occurs by photoexciting conduction band electrons in the semiconductor. These thermalize through the emission of terahertz radiation. The route to terahertz generation is not particularly efficient as significant losses come from the absorption in the substrate that is beneath the photoconductive antenna layer. This work explores the application of hexagonally close-packed monolayers of chemically synthesized nanospheres as a potential light concentration method for ultra-thin films of GaAs and black phosphorus that are relevant to terahertz generation. A nanosphere layer can induce an advantageous scattering texture which can increase the effective path length of light transport through the thin film. The nanosphere layer can also induce a significant absorption increase through optical resonances that are caused by the periodic arrangement of hexagonally close-packed spheres. To aid in the study of these effects, we use finite element simulations of absorption in a model GaAs photoconductive layer since GaAs is the present standard photoconductive absorber layer. These simulations enable us to map the absorption resonances in the material as a function of the photoconductive absorber layer thickness and sphere diameter. We are also able to construct the equivalent materials to characterize the optical absorption increases in real, experimental systems. With the aid of these results, we will show that a simple light concentration strategy is able to generate a significant increase in light absorption. Through the increase in light absorption, an improvement of the light-to-terahertz power conversion efficiency is achieved

Investigation of refractory dielectrics for integrated circuits

Pyrolytic silicon nitride dielectric for integrated circuit