Electrical permittivity and resistivity time lapses of multiphase DNAPLs in a lab test

Dense Non-Aqueous Phase Liquids (DNAPLs) induce variation in electromagnetic characteristics of the ground e.g. electric permittivity and resistivity. The most used indirect methods in the mapping of these physical characteristics are electrical resistivity and ground penetrating radar. To better understand the effect of DNAPL release on electrical permittivity and resistivity in a water saturated medium, we carried out a controlled laboratory experiment where the host material was simulated by glass beads and the DNAPL by HFE-7100 (hydrofluoroether). The experiment measured the electric resistivity and permittivity of each fluid, the multi-phase fluid system, and the host material, along with time-lapse electrical resistivity and GPR measurements in a controlled cell. We found that the different phases of DNAPL within a saturated medium (free, dissolved and gaseous phase) affect the physical characteristics differently. The reflection pull-up behind contaminated sediments, which is normally detected by GPR, was mainly inferred from the HFE free phase. The dissolved phase causes small variations in electric permittivity not usually readily detected by GPR measurements. Both the dissolved and free HFE phases induce variation in resistivity. The study showed that GPR and electrical resistivity differ in sensitivity to the different HFE phases, and can be complementary in the characterization of DNAPL contaminated sites

The influence of changes in water content on the electrical resistivity of a natural unsaturated loess

Non-destructive methods of measuring water content in soils have been extensively developed in the last decades, especially in soil science. Among these methods, the measurements based on the electrical resistivity are simple and reliable thanks to the clear relationship between the water content and the electrical resistivity of soils. In this work, a new electrical resistivity probe was developed to monitor the change in local water content in the triaxial apparatus. The probe is composed of two-pair of electrodes, and an electrical current is induced through the soil at the vicinity of the contact between the probe and the specimen. Some experimental data on the changes in resistivity with the degree of saturation were obtained in specimens of a natural unsaturated loess from Northern France. Two theoretical models of resistivity were also used to analyze the obtained data. Results are finally discussed with respect to the loess's water retention properties

Saturation of electrical resistivity

Resistivity saturation is observed in many metallic systems with a large resistivity, i.e., when the resistivity has reached a critical value, its further increase with temperature is substantially reduced. This typically happens when the apparent mean free path is comparable to the interatomic separations - the Ioffe-Regel condition. Recently, several exceptions to this rule have been found. Here, we review experimental results and early theories of resistivity saturation. We then describe more recent theoretical work, addressing cases both where the Ioffe-Regel condition is satisfied and where it is violated. In particular we show how the (semiclassical) Ioffe-Regel condition can be derived quantum-mechanically under certain assumptions about the system and why these assumptions are violated for high-Tc cuprates and alkali-doped fullerides.Comment: 16 pages, RevTeX, 15 eps figures, additional material available at http://www.mpi-stuttgart.mpg.de/andersen/saturation

High-pressure study of non-Fermi liquid and spin-glass-like behavior in CeRhSn

We present measurements of the temperature dependence of electrical resistivity of CeRhSn up to ~ 27 kbar. At low temperatures, the electrical resistivity varies linearly with temperature for all pressures, indicating non-Fermi liquid behavior. Below a temperature Tf ~ 6 K, the electrical resistivity deviates from a linear dependence. We found that the low-temperature feature centered at T = Tf shows a pressure dependence dTf/dP ~ 30 mK/kbar which is typical of canonical spin glasses. This interplay between spin-glass-like and non-Fermi liquid behavior was observed in both CeRhSn and a Ce0.9La0.1RhSn alloy.Comment: 5 pages, 3 figures, accepted for publication to Journal of Physics: Condensed Matte

Observation of a temperature dependent electrical resistance minimum above the magnetic ordering temperature in Gd2_2PdSi3_3

Results on electrical resistivity, magnetoresistance, magnetic Results on electrical resistivity, magnetoresistance, magnetic susceptibility, heat capacity and Gd Mossbauer measurements on a Gd-based intermetallic compound, Gd$_{2}$PdSi$_{3}$ are reported. A finding of interest is that the resistivity unexpectedly shows a well-defined minimum at about 45 K, well above the long range magnetic ordering temperature (21 K), a feature which gets suppressed by the application of a magnetic field. This observation in a Gd alloy presents an interesting scenario. On the basis of our results, we propose electron localization induced by s-f (or d-f) exchange interaction prior to long range magnetic order as a mechanism for the electrical resistance minimum.Comment: 4 pages, 4 figure

Magnetic Phase Diagram and Metal-Insulator Transition of NiS2-xSex

Magnetic phase diagram of NiS2-xSex has been reexamined by systematic studies of electrical resistivity, uniform magnetic susceptibility and neutron diffraction using single crystals grown by a chemical transport method. The electrical resistivity and the uniform magnetic susceptibility exhibit the same feature of temperature dependence over a wide Se concentration. A distinct first order metal-insulator (M-I) transition accompanied by a volume change was observed only in the antiferromagnetic ordered phase for 0.50<x<0.59. In this region, the M-I transition makes substantial effects to the thermal evolution of staggered moments. In the paramagnetic phase, the M-I transition becomes broad; both the electrical resistivity and the uniform magnetic susceptibility exhibit a broad maximum around the temperatures on the M-I transition-line extrapolated to the paramagnetic phase.Comment: 6 pages, 8 figures, corrected EPS fil

Thermal conductivity of austenitic stainless steel, SRM 735, from 5 to 280 K

Thermal conductivity and electrical resistivity measurements were conducted on two lots of an austenitic stainless steel. Electrical resistivity measurements were performed on the second lot, both before and after the material was hot-swaged and reannealed to a size 1/10 the original diameter. These measurements indicate that this steel can be swaged and reannealed without an appreciable change in thermal conductivity. Electrical resistivity measurements as well as direct thermal conductivity measurements on several specimens from both lots indicate a material variability in these lots of less than 1% in thermal conductivity

Fluctuation of the Solute Concentration in Al Rich Al-Zn Alloys

Several Al-Zn alloys containing 0.041-4.4 at % Zn were studied by means of measurements of electrical resistivity. The results obtained are as follows : (1) The electrical resistivity increases when the specimen is annealed at temperatures higher than the solvus temperature of the G.P. zones. The increase of the resistivity is due to the formation of fluctuation. (2) The electrical resistivity of the specimen containing fluctuation is dependent upon annealing temperature only and independent of quenching temperature. (3) The fluctuation is formed in very dilute alloys as 0.041 at % Zn at temperatures higher than the solvus temperature of the G.P. zones. (4) The formation energy of vacancy and the migration energy of the Zn atom in the alloys determined by the formation process of fluctuation are in good agreement with those by the formation process of G.P. zones. (5) In spite of the result (4), it seems that the fluctuation is not the same as the small G.P. zones which are observed in the early stage of aging

Spin singlet small bipolarons in Nb-doped BaTiO3

The magnetic susceptibility and electrical resistivity of n-type BaTi{1-x}Nb{x}O3 have been measured over a wide temperature range. It is found that, for 0 < x < 0.2, dopant electrons form immobile spin singlet small bipolarons with binding energy around 110 meV. For x = 0.2, a maximum in the electrical resistivity around 15 K indicates a crossover from band to hopping transport of the charge carriers, a phenomenon expected but rarely observed in real polaronic systems.Comment: 5 pages, 4 figure