The role of chemistry in the oscillating combustion of hydrocarbons : an experimental and theoretical study

The stable operation of low-temperature combustion processes is an open challenge, due to the presence of undesired deviations from steady-state conditions: among them, oscillatory behaviors have been raising significant interest. In this work, the establishment of limit cycles during the combustion of hydrocarbons in a wellstirred reactor was analyzed to investigate the role of chemistry in such phenomena. An experimental investigation of methane oxidation in dilute conditions was carried out, thus creating quasi-isothermal conditions and decoupling kinetic effects from thermal ones. The transient evolution of the mole fractions of the major species was obtained for different dilution levels (0.0025 <= X-CH4 <= 0.025), inlet temperatures (1080K <= T <= 1190K) and equivalence ratios (0.75 <= Phi <= 1). Rate of production analysis and sensitivity analysis on a fundamental kinetic model allowed to identify the role of the dominating recombination reactions, first driving ignition, then causing extinction. A bifurcation analysis provided further insight in the major role of these reactions for the reactor stability. One-parameter continuation allowed to identify a temperature range where a single, unstable solution exists, and where oscillations were actually observed. Multiple unstable states were identified below the upper branch, where the stable (cold) solution is preferred. The role of recombination reactions in determining the width of the unstable region could be captured, and bifurcation analysis showed that, by decreasing their strength, the unstable range was progressively reduced, up to the full disappearance of oscillations. This affected also the oxidation of heavier hydrocarbons, like ethylene. Finally, less dilute conditions were analyzed using propane as fuel: the coupling with heat exchange resulted in multiple Hopf Bifurcations, with the consequent formation of intermediate, stable regions within the instability range in agreement with the experimental observations

Low NOx heavy fuel combustor concept program

Three simulated coal gas fuels based on hydrogen and carbon monoxide were tested during an experimental evaluation with a rich lean can combustor: these were a simulated Winkler gas, Lurgi gas and Blue Water gas. All three were simulated by mixing together the necessary pure component species, to levels typical of fuel gases produced from coal. The Lurgi gas was also evaluated with ammonia addition. Fuel burning in a rich lean mode was emphasized. Only the Blue Water gas, however, could be operated in such fashion. This showed that the expected NOx signature form could be obtained, although the absolute values of NOx were above the 75 ppm goals for most operating conditions. Lean combustion produced very low NOx well below 75 ppm with the Winkler and Lurgi gases. In addition, these low levels were not significantly impacted by changes in operating conditions

Reduction of nitrogen oxides by injection of urea in the freeboard of a pilot scale fluidized bed combustor

The ‘thermal deNOx’ process using urea has been investigated in a 1 MW fluidized bed combustor. NOx reductions of up to 76% were obtainable by using this method. The experimental results show that urea is at least as active as NH3, which is commonly used in this application, but which is far more toxic and corrosive. Emission levels of 200 mg m−3 for NOx could be achieved by injecting the urea at a height of 2 m above the distribution plate in a molar ratio urea:NOx = 1.5. The SO2 emission value also appeared to be reduced when the urea was injected at a urea: NOx molar ratio > 4

Influence of combusting methane-hydrogen mixtures on compression–ignition engine exhaust emissions and in-cylinder gas composition

The paper presents an experimental investigation of combusting methane-hydrogen mixtures, pilot-ignited by diesel fuel, on a naturally aspirated, direct injection compression ignition engine. The tests were performed with two diesel fuel flow rates for pilot-ignition, and the engine was supplied with different quantities of methane-hydrogen mixtures (in various proportions) to vary the engine load between 0 and 7 bar IMEP. In addition, engine in-cylinder gas samples were collected with two geometric sampling arrangements and at various instants during the engine cycle, to measure species concentrations within the engine cylinder. The results showed lower exhaust CO2 and particulate emissions at all engine loads when combusting methane-hydrogen mixtures as compared to diesel fuel only. CO and unburned THC emissions were higher for methane-hydrogen mixtures at all engine loads when compared with diesel fuel only. NOx emissions increased with increasing proportion of hydrogen in the aspirated mixture at all engine loads. In-cylinder NOx levels were observed to be higher in the region between the fuel sprays as compared to within the spray core, attributable to higher temperatures reached in between the sprays post ignition

Jet engine exhaust emissions of high altitude commercial aircraft projected to 1990

Projected minimum levels of engine exhaust emissions that may be practicably achievable for future commercial aircraft operating at high-altitude cruise conditions are presented. The forecasts are based on:(1) current knowledge of emission characteristics of combustors and augmentors; (2) the status of combustion research in emission reduction technology; and (3) predictable trends in combustion systems and operating conditions as required for projected engine designs that are candidates for advanced subsonic or supersonic commercial aircraft fueled by either JP fuel, liquefied natural gas, or hydrogen. Results are presented for cruise conditions in terms of both an emission index (g constituent/kg fuel) and an emission rate (g constituent/hr)

Simulation of Hydrogen Generation from Methane Partial Oxidation in a Plasma Fuel Reformer

A model for the chemistry in a plasma fuel reformer or plasmatron has been developed. The plasma fuel reformer is set up to produce syngas (hydrogen and carbon monoxide gas mixture) from partial oxidation of hydrocarbons. The behavior of methane as fuel has been investigated to characterize and simulate the plasmatron performance. The goal of this work has been improved understanding of the physical/chemical processes within the reactor. The simulation tool used was CHEMKIN 3.7, using the GRI methane combustion mechanism. The Partially Stirred Reactor application (PASR) simulates random mixing by a frequency mixing parameter, which is directly dependant of the system fluid dynamic properties. The fuel reformer was designed as a reactor where combustion is initiated by an electric discharge due to ohmic heating of the arc region. From discharge observations, energy estimations and model simulations, it was found that the electric arc initiates combustion by locally raising the temperature and then propagating the reaction by heat and mass transfer/mixing to the surroundings. Simulation results demonstrated that there is an optimum characteristic mixing time for each residence time, depending on the initial temperature reached at the arc. It was also found that for given power input into the system, the more spread the energy is, or the more mass is heated to a moderate temperature, the better the calculated performance

A study of flame ionization

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