Effect of flow pattern in superstructure-based optimisation of fixed-site carrier membrane gas separation during post-combustion CO2 capture

The authors would like to acknowledge the University of the Witwatersrand Research Office for support.Membrane-based gas separation continues to be an area of interest that is being explored for various applications and efforts are being made to enable large-scale implementation and commercialisation. Works on techno-economic studies in areas such as carbon capture, natural gas sweetening, and biogas upgrading has been reported. Various simulation studies have reported the effect of the membrane flow pattern on permeate recovery and purity. The simulation studies in this area have been limited to single-stage and two-stage membrane processes, while many of these studies considered polymer membranes, facilitated transport has barely been investigated. In addition, optimisation studies that compared different flow patterns in the membrane module have been few. The facilitation of gas permeation decreases as pressure is increased due to carrier saturation. However, an increased pressure increases the driving force, and a trade-off should be achieved. The different membrane flow patterns also have inherent driving force potential. In this work, a superstructurebased model that also embeds a fixed site carrier permeation membrane has been developed for CO2 capture from a coal-fired power plant and three scenarios based on the different flow patterns, i.e., co-current, countercurrent and crossflow, were analysed to determine the effect of the flow pattern in the membrane module. The main objective of the optimisation was to minimise the cost of capture. The counter-current flow pattern resulted in the lowest cost of capture as it resulted in the most energy-efficient process system. The co-current flowbased optimisation results in configuration result in an 18 % increase in cost compared to the counter-current flow pattern optimisation run due to a 29 % increase in energy consumption. The crossflow pattern optimisation results in a 9 % increase in the annualised cost of capture compared to the counter-current flow.http://www.aidic.it/cetam2023Chemical Engineerin

Efficient computation of solution space and conflicts detection for linear systems

Mémoire M1 sous la forme d'articleWe analyze a system of linear inequations $l \leq A\cdot x \leq u$, used for the purpose of Material Flow Analysis, with three different but complementary goals: (i) given some known variables $x_i$, efficiently compute the solution space of unknown variables, (ii) if the set of constraints is infeasible, efficiently identify the conflicts, (iii) efficiently classify variables to determine whereas they are redundant, just measured, determinable or non-determinable. In each case we compare the efficiency of different algorithms or languages