Augmented saddle point formulation of the steady-state Stefan--Maxwell diffusion problem

We investigate structure-preserving finite element discretizations of the steady-state Stefan--Maxwell diffusion problem which governs diffusion within a phase consisting of multiple species. An approach inspired by augmented Lagrangian methods allows us to construct a symmetric positive definite augmented Onsager transport matrix, which in turn leads to an effective numerical algorithm. We prove inf-sup conditions for the continuous and discrete linearized systems and obtain error estimates for a phase consisting of an arbitrary number of species. The discretization preserves the thermodynamically fundamental Gibbs--Duhem equation to machine precision independent of mesh size. The results are illustrated with numerical examples, including an application to modelling the diffusion of oxygen, carbon dioxide, water vapour and nitrogen in the lungs.Comment: 27 pages, 5 figure

A convergent entropy diminishing finite volume scheme for a cross-diffusion system

We study a two-point flux approximation finite volume scheme for a cross-diffusion system. The scheme is shown to preserve the key properties of the continuous systems, among which the decay of the entropy. The convergence of the scheme is established thanks to compactness properties based on the discrete entropy-entropy dissipation estimate. Numerical results illustrate the behavior of our scheme

An entropy structure preserving space-time Galerkin method for cross-diffusion systems

Cross-diffusion systems are systems of nonlinear parabolic partial differential equations that are used to describe dynamical processes in several application, including chemical concentrations and cell biology. We present a space-time approach to the proof of existence of bounded weak solutions of cross-diffusion systems, making use of the system entropy to examine long-term behavior and to show that the solution is nonnegative, even when a maximum principle is not available. This approach naturally gives rise to a novel space-time Galerkin method for the numerical approximation of cross-diffusion systems that conserves their entropy structure. We prove existence and convergence of the discrete solutions, and present numerical results for the porous medium, the Fisher-KPP, and the Maxwell-Stefan problem.Comment: 33 page

A convergent entropy diminishing finite volume scheme for a cross-diffusion system

International audienceWe study a two-point flux approximation finite volume scheme for a cross-diffusion system. The scheme is shown to preserve the key properties of the continuous systems, among which the decay of the entropy. The convergence of the scheme is established thanks to compactness properties based on the discrete entropy-entropy dissipation estimate. Numerical results illustrate the behavior of our scheme