Strontium Isotope as Tracers of Groundwater Contamination

Groundwater flowing under a municipal solid waste landfill has been studied to identify potential contamination phenomenon and to test strontium isotopic composition as a natural tracer of contamination. The study was carried on in June 2014 in central Italy. Five selected boreholes were selected and analysed according to their location related to the site. Samples taken from boreholes placed upward to the site were considered as uncontaminated groundwater. One borehole located downward from the site and with major contaminant values has been considered as potentially contaminated end-member. Sr isotope results show that samples located upward from the site present lower Sr concentration and highest Sr isotopic values, which reflects weathered bedrock, while borehole located downward from the site show lowest Sr values and 87Sr/86Sr ratio, probably due to pollution by landfill leachate. The mixing calculation highlights the possible mixing phenomenon for the other samples located downward from the site

Using CFCs and SF6 for groundwater dating : a SWOT analysis

A knowledge of the residence time of groundwater is of importance in understanding key issues in the evolution of water quality. Chlorofluorocarbons (CFCs) and sulphur hexafluoride (SF6) offer a convenient way of dating waters up to ~60 yrs old. In contrast to tritium, these gases are well-mixed in the atmosphere so their input functions are much less problematic. While any one of these gases can in principle provide a groundwater age, when two or more are measured on water samples the potential exists to distinguish between different modes of flow including piston flow, exponential flow and simple endmember mixing. As with all groundwater dating methods, caveats apply. Factors such as recharge temperature and elevation must be reasonably well-constrained. Mainly for SF6, the phenomenon of ‘excess air’ also requires consideration. Mainly for the CFCs, local sources of contamination need to be considered, as do redox conditions. For both SF6 and the CFCs, the nature and thickness of the unsaturated zone need to be factored into residence time calculations. This paper attempts a balanced look at the pros and cons of the trace-gas dating method

Tracer Applications of Noble Gas Radionuclides in the Geosciences

The noble gas radionuclides, including 81Kr (half-life = 229,000 yr), 85Kr (11 yr), and 39Ar (269 yr), possess nearly ideal chemical and physical properties for studies of earth and environmental processes. Recent advances in Atom Trap Trace Analysis (ATTA), a laser-based atom counting method, have enabled routine measurements of the radiokrypton isotopes, as well as the demonstration of the ability to measure 39Ar in environmental samples. Here we provide an overview of the ATTA technique, and a survey of recent progress made in several laboratories worldwide. We review the application of noble gas radionuclides in the geosciences and discuss how ATTA can help advance these fields, specifically determination of groundwater residence times using 81Kr, 85Kr, and 39Ar; dating old glacial ice using 81Kr; and an 39Ar survey of the main water masses of the oceans, to study circulation pathways and estimate mean residence times. Other scientific questions involving deeper circulation of fluids in the Earth's crust and mantle also are within the scope of future applications. We conclude that the geoscience community would greatly benefit from an ATTA facility dedicated to this field, with instrumentation for routine measurements, as well as for research on further development of ATTA methods

Signatures of accretion events in the halos of early-type galaxies from comparing PNe and GCs kinematics

We have compared the halo kinematics traced by globular clusters (GCs) and planetary nebulae (PNe) for two elliptical galaxies in the Fornax and Virgo clusters NGC 1399 and NGC 4649, and for the merger remnant NGC 5128 (Centaurus A). We find differences in the rotational properties of the PN, red GC, and blue GC systems in all these three galaxies. NGC 1399 PNe and GCs show line of sight velocity distributions in specific regions that are significantly different, based on Kolmogorov-Smirnov tests. The PN system shows multi-spin components, with nearly opposite direction of rotation in the inner and the outer parts. The GCs velocity field is not point-symmetric in the outer regions of the galaxy, indicating that the system has not reached dynamical equilibrium yet. In NGC 4649 PNe, red and blue GCs have different rotation axes and rotational velocities. Finally, in NGC 5128 both PNe and GCs deviate from equilibrium in the outer regions of the galaxy, and in the inner regions the PN system is rotationally supported, whereas the GC system is dominated by velocity dispersion. The observed different kinematic properties, including deviations from point-symmetry, between PNe and GCs suggest that these systems are accreted at different times by the host galaxy, and the most recent accretion took place only few Gyr ago.We discuss two scenarios which may explain some of these differences: i) tidal stripping of loosely-bound GCs, and ii) multiple accretion of low luminosity and dwarf galaxies. Because these two mechanisms affect mostly the GC system, differences with the PNe kinematics can be expected.Comment: 14 pages, 13 figures, Accepted for publication in MNRAS. This new version contains an improved analysis, which includes the study of point-symmetry in the velocity fields and its implications for dynamical equilibriu

Use of isotope dilution method to predict bioavailability of organic pollutants in historically contaminated sediments.

Many cases of severe environmental contamination arise from historical episodes, where recalcitrant contaminants have resided in the environment for a prolonged time, leading to potentially decreased bioavailability. Use of bioavailable concentrations over bulk chemical levels improves risk assessment and may play a critical role in determining the need for remediation or assessing the effectiveness of risk mitigation operations. In this study, we applied the principle of isotope dilution to quantify bioaccessibility of legacy contaminants DDT and PCBs in marine sediments from a Superfund site. After addition of 13C or deuterated analogues to a sediment sample, the isotope dilution reached a steady state within 24 h of mixing. At the steady state, the accessible fraction (E) derived by the isotope dilution method (IDM) ranged from 0.28 to 0.89 and was substantially smaller than 1 for most compounds, indicating reduced availability of the extensively aged residues. A strong linear relationship (R2=0.86) was found between E and the sum of rapid (Fr) and slow (Fs) desorption fractions determined by sequential Tenax desorption. The IDM-derived accessible concentration (Ce) was further shown to correlate closely with tissue residue in the marine benthic polychaete Neanthes arenaceodentata exposed in the same sediments. As shown in this study, the IDM approach involves only a few simple steps and may be readily adopted in laboratories equipped with mass spectrometers. This novel method is expected to be especially useful for historically contaminated sediments or soils, for which contaminant bioavailability may have changed significantly due to aging and other sequestration processes

Future cosmic microwave background delensing with galaxy surveys

The primordial B-modes component of the cosmic microwave background (CMB) polarization is a promising experimental dataset to probe the inflationary paradigm. B-modes are indeed a direct consequence of the presence of gravitational waves in the early universe. However, several secondary effects in the low redshift universe will produce \textit{non-primordial} B-modes. In particular, the gravitational interactions of CMB photons with large-scale structures will distort the primordial E-modes, adding a lensing B-mode component to the primordial signal. Removing the lensing component ("delensing") will then be necessary to constrain the amplitude of the primordial gravitational waves. Here we examine the role of current and future large-scale structure surveys in a multi-tracers approach to CMB delensing. We find that, in general, galaxy surveys should be split into tomographic bins as this can increase the reduction of lensing B-modes by $\sim 25\%$ in power in the most futuristic case. Ongoing or recently completed CMB experiments (CMB-S2) will particularly benefit from large-scale structure tracers that, once properly combined, will have a better performance than a CMB internal reconstruction. With the decrease of instrumental noise, the lensing B-modes power removed using CMB internal reconstruction alone will rapidly increase. Nevertheless, optical galaxy surveys will still play an important role even for CMB S4. In particular, an LSST-like survey can a achieve a delensing performance comparable to a 3G CMB experiment but with entirely different systematics. This redundancy will be essential to demonstrate the robustness against systematics of an eventual detection of primordial B-modes.Comment: 13 pages, 9 figures. This is part of a dissertation submitted for the degree Doctor of Philosophy in Astrophysics at the University of Chicag

The Kinematic Sunyaev-Zel'dovich Effect with Projected Fields II: prospects, challenges, and comparison with simulations

The kinematic Sunyaev-Zel'dovich (kSZ) signal is a powerful probe of the cosmic baryon distribution. The kSZ signal is proportional to the integrated free electron momentum rather than the electron pressure (which sources the thermal SZ signal). Since velocities should be unbiased on large scales, the kSZ signal is an unbiased tracer of the large-scale electron distribution, and thus can be used to detect the "missing baryon" that evade most observational techniques. While most current methods for kSZ extraction rely on the availability of very accurate redshifts, we revisit a method that allows measurements even in the absence of redshift information for individual objects. It involves cross-correlating the square of an appropriately filtered cosmic microwave background (CMB) temperature map with a projected density map constructed from a sample of large-scale structure tracers. We show that this method will achieve high signal-to-noise when applied to the next generation of high-resolution CMB experiments, provided that component separation is sufficiently effective at removing foreground contamination. Considering statistical errors only, we forecast that this estimator can yield $S/N \approx$ 3, 120 and over 150 for Planck, Advanced ACTPol, and hypothetical Stage-IV CMB experiments, respectively, in combination with a galaxy catalog from WISE, and about 20% larger $S/N$ for a galaxy catalog from the proposed SPHEREx experiment. This work serves as a companion paper to the first kSZ measurement with this method, where we used CMB temperature maps constructed from Planck and WMAP data, together with galaxies from the WISE survey, to obtain a 3.8 - 4.5$\sigma$ detection of the kSZ$^2$ amplitude.Comment: 14 pages, 10 figures. Comments welcom

Primordial non-Gaussianity with μ\mu-type and yy-type spectral distortions: exploiting Cosmic Microwave Background polarization and dealing with secondary sources

Cross-correlations between Cosmic Microwave Background (CMB) temperature and $y$-spectral distortions anisotropies have been previously proposed as a way to measure the local bispectrum parameter $f_{\rm NL}^{\rm loc.}$ in a range of scales inaccessible to either CMB ($T$, $E$) bispectra or $T$-$\mu$ correlations. This is useful e.g. to test scale dependence of primordial non-Gaussianity. Unfortunately, the primordial $y$-T signal is strongly contaminated by the late-time correlation between the Integrated Sachs Wolfe and Sunyaev-Zel'dovich (SZ) effects. Moreover, SZ itself generates a large noise contribution in the $y$-parameter map. We consider two original ways to address these issues. In order to remove the bias due to the SZ-CMB temperature coupling, while also adding new signal, we include in the analysis the cross-correlation between $y$-distortions and CMB {\em polarization}. In order to reduce the noise, we propose to clean the $y$-map by subtracting a SZ template, reconstructed via cross-correlation with external tracers (CMB and galaxy-lensing signals). We combine this SZ template subtraction with the previously adopted solution of directly masking detected clusters. Our final forecasts show that, using $y$-distortions, a PRISM-like survey can achieve $1\sigma(f_{\rm NL}^\text{loc.}) = 300$, while an ideal experiment will achieve $1\sigma(f_{\rm NL}^\text{loc.}) = 130$, with improvements of a factor $\sim 3$ from adding the $y$-$E$ signal, and a further $20-30 \%$ from template cleaning. These forecasts are much worse than current $f_{\rm NL}^\text{loc.}$ boundaries from {\em Planck}, but we stress again that they refer to completely different scales.Comment: 24 pages, 5 figure