Remote object configuration/orientation determination

This invention relates to object detection and location systems and, more particularly, to a method for determining the configuration and location of an object with respect to an X, Y, X coordinate frame. In space applications in particular, there is a need to be able to passively determine the orientation of an object at a distance, for example, in the control of large, flexible space structures. At present, there is no available method or apparatus which will allow the operator to make such a determination. A similar problem and need exists in robotic application. It is the primary object of this invention to provide a system for remotely defining an object's configuration in a manner compatible with a computer's analytical capability

Optical Resolution and Configuration of Trans-2,3-epoxybutyric Acid

Optical resolution of epoxy derivative of butyric acid with brucine and configuration determination by treatment with ammoni

Comparative study of the vibrational optical activity techniques in structure elucidation : the case of galantamine

The absolute configuration of the alkaloid galantamine was studied using a range of solution-state techniques; nuclear magnetic resonance (NMR), vibrational circular dichroism (VCD), and Raman optical activity (ROA). While the combined use of NMR and VCD does provide a fast, high-resolution methodology for determining the absolute configuration of galantamine, both techniques were needed in concert to achieve this goal. ROA, on the other hand, proved to be sensitive enough to assign the full absolute configuration without relying on other techniques. In both cases, statistical validation was applied to aid the determination of absolute configuration. In the case of galantamine, ROA combined with statistical validation is shown to be a powerful stand-alone tool for absolute configuration determination

Evaluation of the two-photon exchange diagrams for the (1s)22p3/2(1s)^2 2p_{3/2} electron configuration in Li-like ions

We present ab initio calculations of the complete gauge-invariant set of two-photon exchange graphs for the $(1s)^2 2p_{3/2}$ electron configuration in Li-like ions. These calculations are an important step towards the precise theoretical determination of the $2p_{3/2}$-$2s$ transition energy in the framework of QED.Comment: 17 pages, 6 figure

Finite-size effect of antiferromagnetic transition and electronic structure in LiFePO4

The finite-size effect on the antiferromagnetic (AF) transition and electronic configuration of iron has been observed in LiFePO4. Determination of the scaling behavior of the AF transition temperature (TN) versus the particle-size dimension (L) in the critical regime 1-TN(L)/TN(XTL)\simL^-1 reveals that the activation nature of the AF ordering strongly depends on the surface energy. In addition, the effective magnetic moment that reflects the electronic configuration of iron in LiFePO4 is found to be sensitive to the particle size. An alternative structural view based on the polyatomic ion groups of (PO4)3- is proposed.Comment: To be published in Phys. Rev. B - Rapid Communicatio

Optical spectroscopy of complex open 4dd-shell ions Sn7+^{7+}-Sn10+^{10+}

We analyze the complex level structure of ions with many-valence-electron open [Kr] 4$d^\textrm{m}$ sub-shells ($\textrm{m}$=7-4) with ab initio calculations based on configuration-interaction many-body perturbation theory (CI+MBPT). Charge-state-resolved optical and extreme ultraviolet (EUV) spectra of Sn$^{7+}$-Sn$^{10+}$ ions were obtained using an electron beam ion trap. Semi-empirical spectral fits carried out with the orthogonal parameters technique and Cowan code calculations lead to 90 identifications of magnetic-dipole transitions and the determination of 79 energy ground-configuration levels, questioning some earlier EUV-line assignments. Our results, the most complete data set available to date for these ground configurations, confirm the ab initio predictive power of CI+MBPT calculations for the these complex electronic systems.Comment: 18 pages, 5 figure

Relativistic heavy ion collisions with realistic non-equilibrium mean fields

We study the influence of non-equilibrium phase space effects on the dynamics of heavy ion reactions within the relativistic BUU approach. We use realistic Dirac-Brueckner-Hartree-Fock (DBHF) mean fields determined for two-Fermi-ellipsoid configurations, i.e. for colliding nuclear matter, in a local phase space configuration approximation (LCA). We compare to DBHF mean fields in the local density approximation (LDA) and to the non-linear Walecka model. The results are further compared to flow data of the reaction $Au$ on $Au$ at 400 MeV per nucleon measured by the FOPI collaboration. We find that the DBHF fields reproduce the experiment if the configuration dependence is taken into account. This has also implications on the determination of the equation of state from heavy ion collisions.Comment: Physics Letters B in press; 10 pages, Postscript file replaced by Latex file and 3 Postscript figure

Pair potential with submillikelvin uncertainties and nonadiabatic treatment of the halo state of helium dimer

The pair potential for helium has been computed with accuracy improved by an order of magnitude relative to the best previous determination. For the well region, its uncertainties are now below 1 millikelvin. The main improvement is due to the use of explicitly correlated wave functions at the nonrelativistic Born-Oppenheimer (BO) level of theory. The diagonal BO and the relativistic corrections were obtained from large full configuration interaction calculations. The nonadiabatic perturbation theory was used to predict the properties of the halo state of helium dimer. Its binding energy and the average value of interatomic distance are found to be 138.9(5) neV and 47.13(8) {\AA}. The binding energy agrees with its first experimental determination of 151.9(13.3) neV [Zeller et al., PNAS 113, 14651 (2016)]