Fabrication and microstrain evolution of Al-TiB2 composite coating by cold spray deposition

This paper investigates the microstructure evolution of Al-TiB2 coatings prepared by cold spraying. In situ Al-TiB2 composite powders containing uniformly distributed titanium diboride (TiB2) particles with a size range of 5 to 100 nm in the Al matrix and Al/Al-TiB2 blended powders were used as the cold spray feedstock for coating fabrication on aluminium alloy substrates. The microstructures of the feedstock powders and as-deposited coatings were characterised using scanning electron microscopy with energy dispersive X-ray (EDX) analysis and X-ray diffraction (XRD). Al/Al-TiB2 blended powder coatings, compromising closely packed powder particles, were sprayed to an approximate thickness of 500 μm. Al-TiB2 composite coatings (approximately 50 μm thick) were obtained retaining the microstructure of the composite powders being sprayed and no evidence of detrimental phase transformation was found. However, micro-cracks were found to exist in the Al-TiB2 coating due to the hardly deformable powder particles. Little or no microstrain was revealed in the as-sprayed Al-TiB2 coating, indicating that annealing may have occurred due to the localised adiabatic heating during the spraying process. It is demonstrated that it is possible to fabricate the Al-TiB2 composite coating by cold spray deposition but further improvements to eliminate coating cracking are required

Development of a Multiphase Photon Monte Carlo Method for Spray Combustion and its Application in High-pressure Conditions

In this work the development of a multiphase photon Monte Carlo (PMC) method with a focus on resolving radiative heat transfer in combustion simulations is presented. The multiphase PMC solver can account for description of participating media in both Lagrangian and Eulerian frameworks. The solver is validated against exact solutions in several one-dimensional configurations. The developed solver is then applied to Diesel spray combustions, where liquid spray droplets are assumed to be cold, nonemitting, large, and isotropically scattering. Several formulations for radiative properties of the Diesel spray are first explored. The PMC solver has then been coupled with the multiphase spray combustion solver in OpenFOAM and the coupled solver is used for simulations of high pressure Diesel spray combustion. It was found that in typical Diesel spray combustion applications, such as in an internal combustion engine, impact of radiation on the evolution of the liquid spray was insignificant. Although the impact of radiation on the spray was minimal, nongray spectral properties and the assumption of semi-transparency for Diesel spray were found to impact the radiative transfer significantly, while impact of scattering was marginal. Spray radiation was also found not to have much effect on global combustion characteristics in high-pressure engine-relevant configurations. However, a small but noticeable effect on minor species distribution relevant to pollutant formation was observed

Increase of cold tolerance in cotton plant (Gossypium hirsutum L.) by mepiquat chloride

Three mepiquat chloride (MC) concentrations - 40, 70, and 100 g a.i./ha - were used to spray cotton (Gossypium hirsutum L., cultival McNair 220) plants to determine whether or not MC would increase their cold tolerance. Seven to ten days after the spray, the plants were exposed to three different cold treatments. No important difference in cold damage was noticed between the control and the MC-treated plants when they were exposed repeatedly to 4.5 C. No plants died when exposed to 0.5 C for 12 h; however, 90% of the 1st and 2nd leaves of the control plants were damaged. This was three times more damage than those leaves of plants treated with 70 and 100 g a.i./ha MC concentrations; 60% f the control and 10-20% of the MC-treated plants died when the plants were subjected to a cold hardening process with 15.5 C day (12 h) and 1.7 C night (12 h) for 10 days, and then, held at -2.2 C for 24 hours. The electrolyte leakage and reflectance measurement data showed that the cell membranes of the MC-treated plants sustained much less damage than those of the control. Freezing injury was easily assessed by reflectance measurements at the 1.65 micrometer wavelength

Copper-acrylic enamel serves as lubricant for cold drawing of refractory metals

Acrylic enamel spray containing metallic copper pigment lubricates refractory metal tubing during cold drawing operations so that the tubing surface remains free from scratches and nicks and does not seize in the die. Zirconium alloys, zirconium, tantalum alloys, niobium alloys, vanandium alloys and titanium alloys have been drawn using this lubricant

Experimental investigation of the elastoplastic response of aluminum silicate spray dried powder during cold compaction

Mechanical experiments have been designed and performed to investigate the elasto-plastic behaviour of green bodies formed from an aluminum silicate spray dried powder used for tiles production. Experiments have been executed on samples obtained from cold compaction into a cylindrical mould and include: uniaxial strain, equi-biaxial flexure and high-pressure triaxial compression/extension tests. Two types of powders have been used to realize the green body samples, differing in the values of water content, which have been taken equal to those usually employed in the industrial forming of traditional ceramics. Yielding of the green body during compaction has been characterized in terms of yield surface shape, failure envelope, and evolution of cohesion and void ratio with the forming pressure, confirming the validity of previously proposed constitutive models for dense materials obtained through cold compaction of granulates.Comment: 17 pages; Journal of the European Ceramic Society, 201

Coating by the Cold Spray Process: a state of the art

A brief description of cold spray coating process is presented. This paper intends to review some the previous works which are mostly about the influences of the cold spray parameters, mostly the surface ofthe substrate, on the deposition efficiency (DE). Almost all the important parameters, with more focus on the roughness of the substrate, on increasing the DE are briefly studied; this review also includes a description of application of cold spray and of some important effect of this method on substrate properties.On this basis, some possible development in this field of research are drawn and discussed

LOX/Hydrogen Coaxial Injector Atomization Test Program

Quantitative information about the atomization of injector sprays is needed to improve the accuracy of computational models that predict the performance and stability margin of liquid propellant rocket engines. To obtain this data, a facility for the study of spray atomization is being established at NASA-Lewis to determine the drop size and velocity distributions occurring in vaporizing liquid sprays at supercritical pressures. Hardware configuration and test conditions are selected to make the cold flow simulant testing correspond as closely as possible to conditions in liquid oxygen (LOX)/gaseous H2 rocket engines. Drop size correlations from the literature, developed for liquid/gas coaxial injector geometries, are used to make drop size predictions for LOX/H2 coaxial injectors. The mean drop size predictions for a single element coaxial injector range from 0.1 to 2000 microns, emphasizing the need for additional studies of the atomization process in LOX/H2 engines. Selection of cold flow simulants, measured techniques, and hardware for LOX/H2 atomization simulations are discussed

Detailed investigation of a vaporising fuel spray. Part 1: Experimental investigation of time averaged spray

A laser tomographic light scattering technique provides rapid and accurate high resolution measurements of droplet sizes, concentrations, and vaporization. Measurements using a computer interfaced thermocouple are presented and it is found that the potential exists for separating gas and liquid temperature measurements and diagnosing local spray density by in situ analysis of the response characteristics of the thermocouple. The thermocouple technique provides a convenient means for measuring mean gas velocity in both hot and cold two phase flows. The experimental spray is axisymmetric and has carefully controlled initial and boundary conditions. The flow is designed to give relatively insignificant transfer of momentum and mass from spray to air flow. The effects of (1) size-dependent droplet dispersion by the turbulence, (2) the initial spatial segregation of droplet sizes during atomization, and (3) the interaction between droplets and coherent large eddies are diagnosed

Young's Moduli of Cold and Vacuum Plasma Sprayed Metallic Coatings

Monolithic metallic copper alloy and NiCrAlY coatings were fabricated by either the cold spray (CS) or the vacuum plasma spray (VPS) deposition processes. Dynamic elastic modulus property measurements were conducted on these monolithic coating specimens between 300 K and 1273 K using the impulse excitation technique. The Young's moduli decreased almost linearly with increasing temperature at all temperatures except in the case of the CS Cu-23%Cr-5%Al and VPS NiCrAlY, where deviations from linearity were observed above a critical temperature. It was observed that the Young's moduli for VPS Cu-8%Cr were larger than literature data compiled for Cu. The addition of 1%Al to Cu- 8%Cr significantly increased its Young's modulus by 12 to 17% presumably due to a solid solution effect. Comparisons of the Young s moduli data between two different measurements on the same CS Cu- 23%Cr-5%Al specimen revealed that the values measured in the first run were about 10% higher than those in the second run. It is suggested that this observation is due to annealing of the initial cold work microstructure resulting form the cold spray deposition process