Comparative inverse analysis of satellite (MOPITT) and aircraft (TRACE-P) observations to estimate Asian sources of carbon monoxide

We use an inverse model analysis to compare the top-down constraints on Asian sources of carbon monoxide (CO) in spring 2001 from (1) daily MOPITT satellite observations of CO columns over Asia and the neighboring oceans and (2) aircraft observations of CO concentrations in Asian outflow from the TRACE-P aircraft mission over the northwest Pacific. The inversion uses the maximum a posteriori method (MAP) and the GEOS-CHEM chemical transport model (CTM) as the forward model. Detailed error characterization is presented, including spatial correlation of the model transport error. Nighttime MOPITT observations appear to be biased and are excluded from the inverse analysis. We find that MOPITT and TRACE-P observations are independently consistent in the constraints that they provide on Asian CO sources, with the exception of southeast Asia for which the MOPITT observations support a more modest decrease in emissions than suggested by the aircraft observations. Our analysis indicates that the observations do not allow us to differentiate source types (i.e., anthropogenic versus biomass burning) within a region. MOPITT provides ten pieces of information to constrain the geographical distribution of CO sources, while TRACE-P provides only four. The greater information from MOPITT reflects its ability to observe all outflow and source regions. We conducted a number of sensitivity studies for the inverse model analysis using the MOPITT data. Temporal averaging of the MOPITT data (weekly and beyond) degrades the ability to constrain regional sources. Merging source regions beyond what is appropriate after careful selection of the state vector leads to significant aggregation errors. Calculations for an ensemble of realistic assumptions lead to a range of inverse model solutions that has greater uncertainty than the a posteriori errors for the MAP solution. Our best estimate of total Asian CO sources is 361 Tg yr−1, over half of which is attributed to east Asia

Prediction of forbidden ultraviolet and visible emissions in comet 67P/Churyumov-Gerasimenko

Remote observation of spectroscopic emissions is a potential tool for the identification and quantification of various species in comets. CO Cameron band (to trace \cod) and atomic oxygen emissions (to trace H$_2$O and/or CO$_2$, CO) have been used to probe neutral composition in the cometary coma. Using a coupled-chemistry emission model, various excitation processes controlling CO Cameron band and different atomic oxygen and atomic carbon have been modelled in comet 67P-Churyumov-Gerasimenko at 1.29~AU (perihelion) and at 3~AU heliocentric distances, which is being explored by ESA's Rosetta mission. The intensities of CO Cameron band, atomic oxygen and atomic carbon emission lines as a function of projected distance are calculated for different CO and CO$_2$ volume mixing ratios relative to water. Contributions of different excitation processes controlling these emissions are quantified. We assess how CO$_2$ and/or CO volume mixing ratios with respect to H$_2$O can be derived based on the observed intensities of CO Cameron band, atomic oxygen, and atomic carbon emission lines.The results presented in this work serve as base line calculations to understand the behaviour of low out-gassing cometary coma and compare them with the higher gas production rate cases (e.g. comet Halley). Quantitative analysis of different excitation processes governing the spectroscopic emissions is essential to study the chemistry of inner coma and to derive neutral gas composition.Comment: 46 pages, 12 figures, Accepted in The Astrophysical Journa

Improved quantification of Chinese carbon fluxes using CO2/CO correlations in Asian outflow

[1] We use observed CO2:CO correlations in Asian outflow from the TRACE-P aircraft campaign (February–April 2001), together with a three-dimensional global chemical transport model (GEOS-CHEM), to constrain specific components of the east Asian CO2 budget including, in particular, Chinese emissions. The CO2/CO emission ratio varies with the source of CO2 (different combustion types versus the terrestrial biosphere) and provides a characteristic signature of source regions and source type. Observed CO2/CO correlation slopes in east Asian boundary layer outflow display distinct regional signatures ranging from 10–20 mol/mol (outflow from northeast China) to 80 mol/mol (over Japan). Model simulations using best a priori estimates of regional CO2 and CO sources from Streets et al. [2003] (anthropogenic), the CASA model (biospheric), and Duncan et al. [2003] (biomass burning) overestimate CO2 concentrations and CO2/CO slopes in the boundary layer outflow. Constraints from the CO2/CO slopes indicate that this must arise from an overestimate of the modeled regional net biospheric CO2 flux. Our corrected best estimate of the net biospheric source of CO2 from China for March–April 2001 is 3200 Gg C/d, which represents a 45 % reduction of the net flux from the CASA model. Previous analyses of the TRACE-P data had found that anthropogenic Chinese C

Fourier analyses of commensurability oscillations in Fibonacci lateral superlattices

Magnetotransport measurements have been performed on Fibonacci lateral superlattices (FLSLs) -- two-dimensional electron gases subjected to a weak potential modulation arranged in the Fibonacci sequence, LSLLSLS..., with L/S=tau (the golden ratio). Complicated commensurability oscillation (CO) is observed, which can be accounted for as a superposition of a series of COs each arising from a sinusoidal modulation representing the characteristic length scale of one of the self-similar generations in the Fibonacci sequence. Individual CO components can be separated out from the magnetoresistance trace by performing a numerical Fourier band-pass filter. From the analysis of the amplitude of a single-component CO thus extracted, the magnitude of the corresponding Fourier component in the potential modulation can be evaluated. By examining all the Fourier contents observed in the magnetoresistance trace, the profile of the modulated potential seen by the electrons can be reconstructed with some remaining ambiguity about the interrelation of the phase between different components.Comment: 11 pages, 10 figures, added references in Introduction, minor revision

Herschel spectral-mapping of the Helix Nebula (NGC 7293): Extended CO photodissociation and OH+ emission

The Helix Nebula (NGC 7293) is the closest planetary nebulae. Therefore, it is an ideal template for photochemical studies at small spatial scales in planetary nebulae. We aim to study the spatial distribution of the atomic and the molecular gas, and the structure of the photodissociation region along the western rims of the Helix Nebula as seen in the submillimeter range with Herschel. We use 5 SPIRE FTS pointing observations to make atomic and molecular spectral maps. We analyze the molecular gas by modeling the CO rotational lines using a non-local thermodynamic equilibrium (non-LTE) radiative transfer model. For the first time, we have detected extended OH+ emission in a planetary nebula. The spectra towards the Helix Nebula also show CO emission lines (from J= 4 to 8), [NII] at 1461 GHz from ionized gas, and [CI] (2-1), which together with the OH+ lines, trace extended CO photodissociation regions along the rims. The estimated OH+ column density is (1-10)x1e12 cm-2. The CH+ (1-0) line was not detected at the sensitivity of our observations. Non-LTE models of the CO excitation were used to constrain the average gas density (n(H2)=(1-5)x1e5 cm-3) and the gas temperature (Tk= 20-40 K). The SPIRE spectral-maps suggest that CO arises from dense and shielded clumps in the western rims of the Helix Nebula whereas OH+ and [CI] lines trace the diffuse gas and the UV and X-ray illuminated clumps surface where molecules reform after CO photodissociation. [NII] traces a more diffuse ionized gas component in the interclump medium.Comment: Accepted for publication in Astronomy and Astrophysic

Carbon monoxide pollution experiment

The experiment is designed to obtain data for the investigation of mechanisms by which CO is removed from the earth's atmosphere. The approach uses an orbiting platform to remotely map global CO concentrations and determine vertical CO profiles using a correlation interferometer measurement technique. The instrument is capable of measuring CO over the range of expected atmospheric burdens and of measuring trace atmospheric constituents

CO preferential oxidation in a novel Au@ZrO₂ flow-through catalytic membrane reactor with high stability and efficiency

CO preferential oxidation (CO-PROX) achieves much interest as a strategy to remove trace CO in reformed gases for hydrogen utilization. Herein, we reported a novel Au@ZrO₂ catalytic membrane reactor by embedding gold nano-particles in ZrO₂ hollow fiber membrane for CO-PROX. The flow-through catalytic membrane exhibited high catalytic activity and oxygen selectivity, which gave a turnover frequency of 4.73 s⁻¹ at 60 °C, 2–3 times higher than conventional catalyst pellets. CO conversion of >95% was achieved over the catalytic membrane, which maintained great operational stability during 500-h operation even CO₂ and H₂O were added in the feed stream. The excellent catalytic performance of the flow-through catalytic membrane makes gold catalyst possible for practical application in the removal of CO from hydrogen

Biomass burning emisison inventory with daily resolution: Application to aircraft observations of Asian outflow

We develop a daily-resolved global emission inventory for biomass burning using AVHRR satellite observations of fire activity corrected for data gaps and scan angle biases. We implemented this inventory in a global three-dimensional model (GEOSCHEM) to simulate aircraft CO observations during the TRACE-P mission over the NW Pacific in February-April 2001. Seasonal biomass burning in SE Asia was a major contributor to the outflow of Asian pollution observed in TRACE-P and shows large day-to-day fluctuations that vary depending on location. Three simulations were conducted with the same 3-month total (February-April) emissions but different temporal distributions: 2001 daily resolved, 2001 monthly resolved, and climatological monthly resolved. The effect of daily resolved versus monthly resolved 2001 emissions in the simulation of CO is less than 8 ppbv in Asian outflow over the NW Pacific but can exceed 100 ppbv over source regions. The relatively small effect in Asian outflow reflects spatial and temporal averaging of emissions during ageing in the continental boundary layer. Significant improvement in the simulation of TRACE-P observations (as diagnosed by the resolved variance) is found when using 2001 monthly versus climatological monthly emissions, but using 2001 daily emissions does not offer further improvement. Copyright 2003 by the American Geophysical Union

Sub-arcsecond imaging of the radio continuum and neutral hydrogen in the Medusa merger

We present sub-arcsecond, Multi-Element Radio Linked Interferometer (MERLIN) observations of the decimetre radio continuum structure and neutral hydrogen (HI) absorption from the nuclear region of the starburst galaxy NGC 4194 (the Medusa Merger). The continuum structure of the central kiloparsec of the Medusa has been imaged, revealing a pair of compact radio components surrounded by more diffuse, weak radio emission. Using the constraints provided by these observations and those within the literature we conclude that the majority of this radio emission is related to the ongoing star-formation in this merger system. With these observations we also trace deep HI absorption across the detected radio continuum structure. The absorbing HI gas structure exhibits large variations in column densities. The largest column densities are found toward the south of the nuclear radio continuum, co-spatial with both a nuclear dust lane and peaks in $^{12}$CO (1->0) emission. The dynamics of the HI absorption, which are consistent with lower resolution $^{12}$CO emission observations, trace a shallow north-south velocity gradient of ~320km/s/kpc. This gradient is interpreted as part of a rotating gas structure within the nuclear region. The HI and CO velocity structure, in conjunction with the observed gas column densities and distribution, is further discussed in the context of the fuelling and gas physics of the ongoing starburst within the centre of this merger.Comment: 12 pages, 5 figures, to appear in A&