The Direct Detection of Lyman Continuum Emission from Star-forming Galaxies at z~3

We present the results of rest-frame UV spectroscopic observations of a sample of 14 z ~ 3 star-forming galaxies in the SSA 22a field. These spectra are characterized by unprecedented depth in the Lyman continuum region. For the first time, we have detected escaping ionizing radiation from individual galaxies at high redshift, with 2 of the 14 objects showing significant emission below the Lyman limit. We also measured the ratio of emergent flux density at 1500 Å to that in the Lyman continuum region, for the individual detections (C49 and D3) and the sample average. If a correction for the average IGM opacity is applied to the spectra of the objects C49 and D3, we find f_(1500)/f_(900,corr,C49) = 4.5 and f_(1500)/f_(900,corr,D3) = 2.9. The average emergent flux density ratio in our sample is = 22, implying an escape fraction ~4.5 times lower than inferred from the composite spectrum from Steidel and coworkers. If this new estimate is representative of LBGs, their contribution to the metagalactic ionizing radiation field is J_ν(900) ~ 2.6 × 10^(-22) ergs s^(-1) cm^(-2) Hz^(-1) sr^(-1), comparable to the contribution of optically selected quasars at the same redshift. The sum of the contributions from galaxies and quasars is consistent with recent estimates of the level of the ionizing background at z ~ 3, inferred from the H I Lyα forest optical depth. There is significant variance among the emergent far-UV spectra in our sample, yet the factors controlling the detection or nondetection of Lyman continuum emission from galaxies are not well determined. Because we do not yet understand the source of this variance, significantly larger samples will be required to obtain robust constraints on the galaxy contribution to the ionizing background at z ~ 3 and beyond

The Ti/c-Si solid state reaction : III. The low-temperature reaction kinetics

Thin Ti layers (≈10nm) are grown on top of a clean Si(111) substrate. Heating these layers initiates a solid state reaction, yielding a monosilicide phase at ≈350°C and a C49 disilicide at ≈450°C. The present study concerns the growth kinetics of both phases by means of ellipsometry. A diffusion-limited growth kinetics is found for the monosilicide formation. However, two growth rates are observed, a fast initial one and a slow terminal growth rate. An enhanced Si diffusion in atomically disordered regions as compared to well ordered regions (grains or clusters) could be an explanation. From the measurements we have found a value of 2×10-15 cm2/s for the diffusion coefficient at ≈370°C and an activation energy of 0.62 ± 0.1 eV. Both values correspond to the fast process. Subsequently increasing the temperature to ≈450°C permits the growth of the homogeneous C49 TiSi2 phase. For this process, both planar layer growth and intermixing are observed, however, quantitative results could not be derived from the present study

A high-throughput ab initio review of platinum-group alloy systems

We report a comprehensive study of the binary systems of the platinum group metals with the transition metals, using high-throughput first-principles calculations. These computations predict stability of new compounds in 38 binary systems where no compounds have been reported in the literature experimentally, and a few dozen of as yet unreported compounds in additional systems. Our calculations also identify stable structures at compound compositions that have been previously reported without detailed structural data and indicate that some experimentally reported compounds may actually be unstable at low temperatures. With these results we construct enhanced structure maps for the binary alloys of platinum group metals. These are much more complete, systematic and predictive than those based on empirical results alone.Comment: 24 pages, 12 figure

Structure maps for hcp metals from first principles calculations

The ability to predict the existence and crystal type of ordered structures of materials from their components is a major challenge of current materials research. Empirical methods use experimental data to construct structure maps and make predictions based on clustering of simple physical parameters. Their usefulness depends on the availability of reliable data over the entire parameter space. Recent development of high throughput methods opens the possibility to enhance these empirical structure maps by {\it ab initio} calculations in regions of the parameter space where the experimental evidence is lacking or not well characterized. In this paper we construct enhanced maps for the binary alloys of hcp metals, where the experimental data leaves large regions of poorly characterized systems believed to be phase-separating. In these enhanced maps, the clusters of non-compound forming systems are much smaller than indicated by the empirical results alone.Comment: 7 pages, 4 figures, 1 tabl