Biodegradable and compostable alternatives to conventional plastics

This article is available open access through the publisher’s website at the link below. Copyright @ 2009 The Royal Society.Packaging waste forms a significant part of municipal solid waste and has caused increasing environmental concerns, resulting in a strengthening of various regulations aimed at reducing the amounts generated. Among other materials, a wide range of oil-based polymers is currently used in packaging applications. These are virtually all non-biodegradable, and some are difficult to recycle or reuse due to being complex composites having varying levels of contamination. Recently, significant progress has been made in the development of biodegradable plastics, largely from renewable natural resources, to produce biodegradable materials with similar functionality to that of oil-based polymers. The expansion in these bio-based materials has several potential benefits for greenhouse gas balances and other environmental impacts over whole life cycles and in the use of renewable, rather than finite resources. It is intended that use of biodegradable materials will contribute to sustainability and reduction in the environmental impact associated with disposal of oil-based polymers. The diversity of biodegradable materials and their varying properties makes it difficult to make simple, generic assessments such as biodegradable products are all ‘good’ or petrochemical-based products are all ‘bad’. This paper discusses the potential impacts of biodegradable packaging materials and their waste management, particularly via composting. It presents the key issues that inform judgements of the benefits these materials have in relation to conventional, petrochemical-based counterparts. Specific examples are given from new research on biodegradability in simulated ‘home’ composting systems. It is the view of the authors that biodegradable packaging materials are most suitable for single-use disposable applications where the post-consumer waste can be locally composted.EPSR

PREPARATION PRELIMINARY STUDY OF BIODEGRADABLE PLASTICS BASED OF CASSAVA COMPOUNDS WITH ADDITIVES LIMONENE EXTRACTION OF ORANGE LEATHER

Biodegradable plastic is a plastic material that is environmentally friendly because it is able to return to nature. In general, biodegradable packaging films is defined as packaging that is recyclable and can be destroyed by nature. Cassava starch can be an alternative biodegradable plastic raw materials. The manufacturing process is similar to the process of making plastics with the raw material of synthetic polymers. Biodegradable plastics are new breakthroughs to deliver maximum results, with the base material of cassava and the addition compound limonene, the thickness of relatively thin plastic, the stronger the attraction, elasticity longer. The purpose of this study was to determine the optimum conditions to produce biodegradable plastics with the compound limonene (additive) from the extraction of orange peel. Research conducted through three stages: (1) extraction of orange peel, (2) extraction of cassava starch, and (3) the manufacture of biodegradable plastics. Variable is an experiment conducted on susceptible starch concentration of 4-6% and 5-7% concentration of sorbitol. While the cooking temperature between 70-80oC and the addition of an additive compound of orange peel extract as much as 15%. Of research can be seen that the concentration of cassava starch, sorbitol concentration and the concentration of limonene compounds influencing parameters tested. Percent extension treatment with the highest concentrations found in cassava starch 6%, 7% sorbitol concentration, and concentration of the compound limonene 15%. Relatively good condition or optimum in the manufacture of biodegradable plastics at 80 oC. Keywords: biodegradable plastic, cassava starch, limonene, orange pee

Antimicrobial Activity of Biodegradable Polysaccharide and Protein-Based Films Containing Active Agents

Significant interest has emerged in the introduction of food packaging materials manufactured from biodegradable polymers that have the potential to reduce the environmental impacts associated with conventional packaging materials. Current technologies in active packaging enable effective antimicrobial (AM) packaging films to be prepared from biodegradable materials that have been modified and/or blended with different compatible materials and/or plasticisers. A wide range of AM films prepared from modified biodegradable materials have the potential to be used for packaging of various food products. This review examines biodegradable polymers derived from polysaccharides and protein-based materials for their potential use in packaging systems designed for the protection of food products from microbial contamination. A comprehensive table that systematically analyses and categorizes much of the current literature in this area is included in the review

Biodegradable nanocomposite for food packaging application

Biodegradable poly(lactic) acid (PLA)/clay nanocomposites were investigated to be used as food packaging material. Several techniques were used, rheology, mechanical, gel permeation chromatography (GPC), contact and biodegradability tests, to characterize the developed materials. The addition of organoclay improved PLA mechanical and biodegradable properties. Food contact test showed that the nanocomposites are able to be used as food packaging materials

Characterisation of untreated and treated biodegradable wastes

As part of a Defra sponsored project (WRT220), approximately 40 biodegradable wastes were characterised according to biodegradability (DR4 and BM100), total PTE content, C:N ratio and biochemical composition. Two leaching tests were employed; upflow percolation test and a one step LS10 test; eluates were analysed for TOC, pH, electrical conductivity, PTEs and a range of cations and anions. This paper contains a limited set of data for a selection of untreated and treated waste types representing four waste treatment processes (composting, MBT, MHT, anaerobic digestion). The DR4 and BM100 tests were found to be appropriate for a wide range of waste types but where possible they should be used in conjunction with other related tests. Longer-term MBT composting processes appeared to produce compost material with reduced ammonium concentrations and extractability of some PTEs. Carbon content (carbon analyzer - LECO) could be estimated as C = LOI/1.9 which is a routine operation. N LECO values were approximately 12% greater than the equivalent N Kjeldahl values

Cellulosic materials as natural fillers in starch-containing matrix-based films: a review

In this work, the different cellulosic materials, namely cellulose and lignin are analyzed. In addition, the starch-containing matrices (isolated starch and flour) reinforced with cellulosic materials to be used in packaging applications are described. Many efforts have been exerted to develop biopackaging based on renewable polymers, since these could reduce the environmental impact caused by petrochemical resources. Special attention has had the starch as macromolecule for forming biodegradable packaging. For these reasons, shall also be subject of this review the effect of each type of cellulosic material on the starch-containing matrix-based thermoplastic materials. In this manner, this review contains a description of films based on starch-containing matrices and biocomposites, and then has a review of cellulosic material-based fillers. In the same way, this review contains an analysis of the works carried out on starch-containing matrices reinforced with cellulose and lignin. Finally, the manufacturing processes of starch/cellulose composites are provided as well as the conclusions and the outlook for future works.Fil: Gutiérrez Carmona, Tomy José. Universidad Central de Venezuela; Venezuela. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; ArgentinaFil: Alvarez, Vera Alejandra. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentin

Editorial: biodegradable materials

This Special Issue “Biodegradable Materials” features research and review papers concerning recent advances on the development, synthesis, testing and characterisation of biomaterials. These biomaterials, derived from natural and renewable sources, offer a potential alternative to existing non-biodegradable materials with application to the food and biomedical industries amongst many others. In this Special Issue, the work is expanded to include the combined use of fillers that can enhance the properties of biomaterials prepared as films. The future application of these biomaterials could have an impact not only at the economic level, but also for the improvement of the environment

Lignocellulosic Recycled Materials to Design Molded Products: Optimization of Physical and Mechanical Properties

The object is to contribute to the reduction of environmental pollution, by reusing a fraction of urban solid waste, forestry and agroindustrial waste: newspaper (ONP), office paper (OWP), corrugated cardboard (OCC), pine sawdust, eucalyptus sawdust and sugar cane bagasse as raw material to design biocontainers suitable for growing plants, by applying pulp molding technology. The purpose is to evaluate the effects of the combination of these lignocellulosic materials on the physical-mechanical properties and optimize responses in order to select an ideal mixture on basis the product?s necessities. An experimental design of type mixture of extreme vertices was followed, considering secondary fibers as base material, in a 0-100% proportion, and pine sawdust, eucalyptus sawdust and bagasse fibers as reinforcement, in a 0-40% proportion. An experimental matrix by each reinforcing material was proposed. Properties were evaluated: density, tensile, bursting, tearing, compression, stiffness, wet tensile, permeability and water retention, testing handsheets weighing 150 g/m2. Responses were optimized using a statistical program. It was found that OWP pulps increase strength properties; OCC pulps increases tear and wet tensile; ONP pulps increase stiffness and reinforcement materials increase permeability. Factors that allow reaching the objectives are a mixture of pulp OWP/OCC in a 50/50 proportion.Fil: Aguerre, Yanina Susel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Nordeste. Instituto de Materiales de Misiones. Universidad Nacional de Misiones. Facultad de Ciencias Exactas Químicas y Naturales. Instituto de Materiales de Misiones; ArgentinaFil: Gavazzo, Graciela Beatriz. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Nordeste. Instituto de Materiales de Misiones. Universidad Nacional de Misiones. Facultad de Ciencias Exactas Químicas y Naturales. Instituto de Materiales de Misiones; Argentin

Amylose-lipid complex as a measure of variations in physical, mechanical and barrier attributes of rice starch- ι -carrageenan biodegradable edible film

Improvements in the hygroscopic properties of starch based films are important to strengthen their mechanical properties. The effects of different hydrophobic components-butyric acid (BA, C4:0), lauric acid (LA, C12:0), palmitic acid (PA, C16:0), oleic acid (OA, C18:1), stearic acid (SA, C18:0) and sucrose fatty acid ester (FAEs) on the rice starch (RS)-ι-carrageenan (ι-car) composite films were investigated. Scanning electron microscopy (SEM), differential scanning calorimetry (DSC), thermogravimetric analysis (TGA) in combination with amylose-lipid complexing index (CI) were used to characterise the changes in structure and properties of edible films. The SEM results showed that the surface of films became smoother after the incorporation of fatty acids. Carbon-chain length was a major determinant of CI formation which further influenced the attributes of RS-ι-car films. The addition of FAEs to RS-ι-car improved film thickness, permeability, transparency, tensile properties (TS) and could be used to tailor biodegradable edible films with enhanced properties and future fruit coating applications