Applications of a wireless chloride sensor in environmental monitoring

There is an established need to measure soil salinity, and wireless sensor networks offer the potential to achieve this, coupled with a suitable sensor. However, suitable sensors, up until very recently, have not been available. In this paper we report on the fabrication and calibration of a new low-cost, robust, screen-printed sensor for detecting chloride ions. We also report on two experiments using this sensor. The first is a laboratory-based experiment that shows how sensors can be used to validate modeling results by installing several sensors in a soil column and tracking the vertical migration of a chloride pulse in real time. The second is a trial of multiple sensors installed in a fluvarium (stream simulator) showing that distributed sensors are able to monitor real time changes in horizontal chloride flux in an emulated natural environment. We report on results from both surface flows as well as from sensors at a depth of a few mm in the fluvarium sediment, and differences and trends between the two are discussed. As an example of how such sensors are useful, we note that for the flow regime and sediment type tested, penetration of surface chloride into the river bed is unexpectedly slow and raises questions regarding the dynamics of pollutants in such systems. We conclude that such sensors, coupled with a distributed network, offer a new paradigm in hydrological monitoring and will enable new applications, such as irrigation using mixtures of potable and brackish water with significant cost and resource saving

The impact of agricultural activities on water quality: a case for collaborative catchment-scale management using integrated wireless sensor networks

The challenge of improving water quality is a growing global concern, typified by the European Commission Water Framework Directive and the United States Clean Water Act. The main drivers of poor water quality are economics, poor water management, agricultural practices and urban development. This paper reviews the extensive role of non-point sources, in particular the outdated agricultural practices, with respect to nutrient and contaminant contributions. Water quality monitoring (WQM) is currently undertaken through a number of data acquisition methods from grab sampling to satellite based remote sensing of water bodies. Based on the surveyed sampling methods and their numerous limitations, it is proposed that wireless sensor networks (WSNs), despite their own limitations, are still very attractive and effective for real-time spatio-temporal data collection for WQM applications. WSNs have been employed for WQM of surface and ground water and catchments, and have been fundamental in advancing the knowledge of contaminants trends through their high resolution observations. However, these applications have yet to explore the implementation and impact of this technology for management and control decisions, to minimize and prevent individual stakeholder’s contributions, in an autonomous and dynamic manner. Here, the potential of WSN-controlled agricultural activities and different environmental compartments for integrated water quality management is presented and limitations of WSN in agriculture and WQM are identified. Finally, a case for collaborative networks at catchment scale is proposed for enabling cooperation among individually networked activities/stakeholders (farming activities, water bodies) for integrated water quality monitoring, control and management

Bridges Structural Health Monitoring and Deterioration Detection Synthesis of Knowledge and Technology

INE/AUTC 10.0

Fibers and fabrics for chemical and biological sensing

Wearable sensors can be used to monitor many interesting parameters about the wearer’s physiology and environment, with important applications in personal health and well-being, sports performance and personal safety. Wearable chemical sensors can monitor the status of the wearer by accessing body fluids, such as sweat, in an unobtrusive manner. They can also be used to protect the wearer from hazards in the environment by sampling potentially harmful gas emissions such as carbon monoxide. Integrating chemical sensors into textile structures is a challenging and complex task. Issues which must be considered include sample collection, calibration, waste handling, fouling and reliability. Sensors must also be durable and comfortable to wear. Here we present examples of wearable chemical sensors that monitor the person and also their environment. We also discuss the issues involved in developing wearable chemical sensors and strategies for sensor design and textile integration

Distributed environmental monitoring

With increasingly ubiquitous use of web-based technologies in society today, autonomous sensor networks represent the future in large-scale information acquisition for applications ranging from environmental monitoring to in vivo sensing. This chapter presents a range of on-going projects with an emphasis on environmental sensing; relevant literature pertaining to sensor networks is reviewed, validated sensing applications are described and the contribution of high-resolution temporal data to better decision-making is discussed

Screen-printed potentiometric Ag/AgCl chloride sensors: Lifetime performance and their use in soil salt measurements

Silver – silver chloride electrodes (Ag/AgCl) for the detection of chloride ions were fabricated using thick-film technology. Five different formulations were prepared and chloride responses were investigated over time. Almost identical and near Nernstian responses were observed over the first 162 days with an average chloride sensitivity for all formulations of -51.12 mV ± 0.45 mV per decade change in chloride concentration compared with a value of -50.59 mV ± 0.01 mV over 388 days for the best two formulations. After 6-months continuous immersion in tap water, pastes formulated with a glass binder began to exhibit a loss in sensitivity whilst those formulated from a commercial thick-film dielectric paste remained functional for the best part of a year. This difference in lifetime performance is attributed to the inclusion of proprietary additives in the commercial paste aiding adhesion and minimising AgCl leaching. The mechanical and chemical robustness of these electrodes has been demonstrated through their ability to detect changing levels of chloride when immersed in soil columns. This particular capacity will make them an invaluable tool in the fields of hydrology, agricultural science, soil science and environmental science

Opportunities and challenges of using ion-selective electrodes in environmental monitoring and wearable sensors

Great opportunities exist for Ion-Selective Electrodes (ISEs) in the fields of environmental monitoring and of wearable applications for example as the sensing part in wireless networks. In this review special attention is given to the recent results obtained with Solid Contact Ion-Selective Electrodes and Solid Contact Reference Electrodes. Their combination as disposable sensing platform may offer the best solution to eliminate issues commonly experienced with ISEs and lead in a short term to their commercialization. Future research will likely focus on the miniaturization of the current devices and on the further development of non conventional potentiometric methods, e.g., controlled potential thin-layer coulometry

Application of Distributed Wireless Chloride Sensors to Environmental Monitoring: Initial Results

Over the next 30 years, it is anticipated that the world will need to source 70% more food to provide for the growing population, and it is likely that a significant amount of this will have to come from irrigated land. However, the quality of irrigation water is also important, and measuring the quality of this water will allow management decisions to be made. Soil salinity is an important parameter in crop yield, and in this paper, we describe a chloride sensor system based on a low-cost robust screen-printed chloride ion sensor, suitable for use in distributed sensor networks. Previously, this sensor has been used in controlled laboratory-based experiments, but here we provide evidence that the sensor will find application outside of the laboratory in field deployments. We report on three experiments using this sensor; one with a soil column, one using a fluvarium, and finally on an experiment in a greenhouse. All these give an insight into the movement of chloride over small distances with high temporal resolution. These initial experiments illustrate that the new sensors are viable and usable with relatively simple electronics, and although subject to ongoing development, they are currently capable of providing new scientific data at high spatial and temporal resolutions. Therefore, we conclude that such chloride sensors, coupled with a distributed wireless network, offer a new paradigm in hydrological monitoring and will enable new applications, such as irrigation using mixtures of potable and brackish water, with significant cost and resource saving