Potential Energy Landscape of the Apparent First-Order Phase Transition between Low-Density and High-Density Amorphous Ice

The potential energy landscape (PEL) formalism is a valuable approach within statistical mechanics for describing supercooled liquids and glasses. Here we use the PEL formalism and computer simulations to study the pressure-induced transformations between low-density amorphous ice (LDA) and high-density amorphous ice (HDA) at different temperatures. We employ the ST2 water model for which the LDA-HDA transformations are remarkably sharp, similar to what is observed in experiments, and reminiscent of a first-order phase transition. Our results are consistent with the view that LDA and HDA configurations are associated with two distinct regions (megabasins) of the PEL that are separated by a potential energy barrier. At higher temperature, we find that low-density liquid (LDL) configurations are located in the same megabasin as LDA, and that high-density liquid (HDL) configurations are located in the same megabasin as HDA. We show that the pressure-induced LDL-HDL and LDA-HDA transformations occur along paths that interconnect these two megabasins, but that the path followed by the liquid is different than the path followed by the amorphous solid. At higher pressure, we also study the liquid-to-ice-VII first-order phase transition, and find that the behavior of the PEL properties across this transition are qualitatively similar to the changes found during the LDA-HDA transformation. This similarity supports the interpretation that the LDA-HDA transformation is a first-order-like phase transition between out-of-equilibrium states.Comment: 29 pages, 8 figure

Proper motion and apparent contraction in J0650+6001

We present a multi-epoch and multi-frequency VLBI study of the compact radio source J0650+6001. In VLBI images the source is resolved into three components. The central component shows a flat spectrum, suggesting the presence of the core, while the two outer regions, with a steeper spectral index, display a highly asymmetric flux density. The time baseline of the observations considered to derive the source expansion covers about 15 years. During this time interval, the distance between the two outer components has increased by 0.28+/-0.13 mas, that corresponds to an apparent separation velocity of 0.39c+/-0.18c and a kinematic age of 360+/-170 years. On the other hand, a multi-epoch monitoring of the separation between the central and the southern components points out an apparent contraction of about 0.29+/-0.02 mas, corresponding to an apparent contraction velocity of 0.37c+/-0.02c. Assuming that the radio structure is intrinsically symmetric, the high flux density ratio between the outer components can be explained in terms of Doppler beaming effects where the mildly relativistic jets are separating with an intrinsic velocity of 0.43c+/-0.04c at an angle between 12 and 28 degrees to the line of sight. In this context, the apparent contraction may be interpreted as a knot in the jet that is moving towards the southern component with an intrinsic velocity of 0.66c+/-0.03c, and its flux density is boosted by a Doppler factor of 2.0.Comment: 7 pages, 5 pages. Accepted for publication in MNRA

Cumulative gravitational lensing in Newtonian perturbations of Friedman-Robertson-Walker cosmologies

It is a common assumption amongst astronomers that, in the determination of the distances of remote sources from their apparent brightness, the cumulative gravitational lensing due to the matter in all the galaxies is the same, on average, as if the matter were uniformly distributed throughout the cosmos. The validity of this assumption is considered here by way of general Newtonian perturbations of Friedman-Robertson-Walker (FRW) cosmologies. The analysis is carried out in synchronous gauge, with particular attention to an additional gauge condition that must be imposed. The mean correction to the apparent magnitude-redshift relation is obtained for an arbitrary mean density perturbation. In the case of a zero mean density perturbation, when the intergalactic matter has a dust equation of state, then there is indeed a zero-mean first order correction to the apparent magnitude-redshift relation for all redshifts. Point particle and Swiss cheese models are considered as particular cases.Comment: 28 pages. LaTeX2e. Uses the following packages: amsmath, amsthm, amssymb, amsfonts, mathrsf

Fluctuations of the intergalactic UV background towards two lines of sight

We present a reanalysis of the HeII Lyman alpha absorption towards the quasars HS1700+6416 and HE2347-4342 using new high S/N, optical observations. An alternative analysis method is applied, which fits the high quality, optical HI data directly to the HeII spectrum. The results are compared to those inferred from standard line profile analyses. This new method enables us to derive redshift scales characterizing the fluctuations of the column density ratio eta. We find eta changing smoothly with redshift on typical scales of Delta z ~ 0.01-0.03 corresponding to 8-24 h^-1 Mpc comoving. The real length scales of variations of the column density ratio might be even larger, since part of the fluctuations may be caused by noise in the HeII data and by effects due to the applied method. However, eta variations on small scales of a few Mpc with an amplitude of about +/- 1.5 dex cannot be ruled out completely. The data shows an apparent correlation between low eta regions and the presence of metal line absorbers, which corresponds to the more general correlation of low eta and strong HI absorption. Thermal line broadening is suggested as a probable explanation for this apparent correlation, since both fit methods would severely underestimate eta for absorbers with log N(HI) > 13 if the line width was dominated by thermal broadening. Indeed, lines located close to the cut-off of the b(N) distribution yield lower column density ratios compared to the whole sample, in particular if high density absorbers are considered. We argue that the apparent correlation of eta with the strength of the HI absorption is caused by insufficient consideration of thermal broadened lines by the standard analysis. As unbiased value of the column density ratio, we find eta ~80 in agreement with previous estimates.Comment: 15 pages, 11 figures, recommended for publication in A&

A connection between γ\gamma-ray and parsec-scale radio flares in the blazar 3C 273

We present a comprehensive 5-43 GHz VLBA study of the blazar 3C 273 initiated after an onset of a strong $\gamma$-ray flare in this source. We have analyzed the kinematics of new-born components, light curves, and position of the apparent core to pinpoint the location of the $\gamma$-ray emission. Estimated location of the $\gamma$-ray emission zone is close to the jet apex, 2 pc to 7 pc upstream from the observed 7 mm core. This is supported by ejection of a new component. The apparent core position was found to be inversely proportional to frequency. The brightness temperature in the 7 mm core reached values up to at least $10^{13}$ K during the flare. This supports the dominance of particle energy density over that of magnetic field in the 7 mm core. Particle density increased during the radio flare at the apparent jet base, affecting synchrotron opacity. This manifested itself as an apparent core shuttle along the jet during the 7 mm flare. It is also shown that a region where optical depth decreases from $\tau\sim1$ to $\tau<<1$ spans over several parsecs along the jet. The jet bulk flow speed estimated at the level of 12c on the basis of time lags between 7 mm light curves of stationary jet features is 1.5 times higher than that derived from VLBI apparent kinematics analysis.Comment: Accepted for publication in MNRAS. 17 pages, 15 figures, 10 tables, with supplementary materials attache

Spectral asymmetries in nucleon sum rules at finite density

Apparent inconsistencies between different formulations of nucleon sum rules at finite density are resolved through a proper accounting of asymmetries in the spectral functions between positive- and negative-energy states.Comment: 10 pages in RevTeX, OSU-090

Apparent Scarcity of Low-Density Polymorphs of Inorganic Solids

For most inorganic solids, very few dense polymorphs and no low-density polymorphs are observed. Taking a wide range of tetrahedrally-coordinated binary solids (e.g., ZnO, GaN) as a prototypical system, we show that the apparent scarcity of low-density polymorphs is not due to significant structural or energetic limitations. Using databases of periodic networks as sources of novel crystal structures, followed by ab initio energy minimization, we predict a dense spectrum of low-density low-energy polymorphs. The diverse range of materials considered indicates that this is likely to be a general phenomenon