1,342 research outputs found
2023-2024 Graduate School Catalog
You and your peers represent more than 67 countries and your shared scholarship spans 140 programs - from business administration and biomedical engineering to history, horticulture, musical performance, marine science, and more. Your ideas and interests will inform public health, create opportunities for art and innovation, contribute to the greater good, and positively impact economic development in Maine and beyond
Ultrafast quasiparticle dynamics and the role of screening in WS2 monolayers
Die optischen Eigenschaften von Übergangsmetall-Dichalcogeniden (TMDC) werden durch Exzitonen (exc) dominiert, was auf den Quanteneinschluss und die reduzierte Abschirmung zurückzuführen ist, die für ihre 2D-Natur charakteristisch sind. Das Coulomb-Screening spielt eine grundlegende Rolle bei der Bestimmung der stationären und dynamischen Eigenschaften solcher Materialien. Zeitaufgelöste optische Spektroskopie ist ein grundlegendes Instrument, um die Rolle der Abschirmung in der Nicht-Gleichgewichtsphysik von TMDC zu untersuchen.
Ich untersuche WS2-Monoschichten auf verschiedenen Substraten mit zeitaufgelöstem Transmissions-/Reflexionskontrast. Ich stelle einen Formalismus vor, der einen zuverlässigen Vergleich der dynamischen Reaktion der Exzitonen unabhängig von Probe, Substrat und Messtechnik ermöglicht. Mit diesem Formalismus werden die von der Pump-Photonen-Energie und der Fluenz abhängige Verschiebung und Verbreiterung des Exziton-Peaks extrahiert und mit Hilfe eines Zwei-/Drei-Niveau-Modells reproduziert. Mit Hilfe dieses Modells konnte die Konkurrenz zwischen dynamischer Abschirmung der Quasiteilchen, Streuung und thermischen Effekten entschlüsselt werden. Die Verbreiterung wird durch QFC-exc (exc-exc) Streuung bestimmt, wenn QFC (exc) im System vorhanden sind. Darüber hinaus induzieren QFC (exc) eine globale Rot-(Blau-)Verschiebung der Exzitonenresonanz, die mit einer effektiven QFC (exc) dynamischen, abschirmungsinduzierten Renormalisierung der Bandlücke (Verringerung der Bindungsenergie) reproduziert wird. Schließlich wird der Einfluss der statischen Abschirmung auf die Reaktion der Exzitonen untersucht. Die dynamische exc-Abschirmung ist bei höherer Substratpermittivität verstärkt und wird versuchsweise auf einen höheren Grad der Delokalisierung des Exzitons zurückgeführt. Letztlich trägt diese Arbeit zu einem umfassenden Bild der Nicht-Gleichgewichtsdynamik und der Rolle der Abschirmung in TMDC bei.The optical properties of transition metal dichalcogenides (TMDC) are dominated by excitons, due to quantum confinement and reduced screening characteristic of their 2D nature. Exactly the screening of the Coulomb interaction has a fundamental role in determining the steady-state and dynamic properties of such materials. Time-resolved optical spectroscopies are a fundamental tool to investigate the phenomena governing the non-equilibrium physics of TMDC materials. Nevertheless, the quantitative role of the screening in the non-equilibrium response of the TMDC is yet to be understood.
I investigate monolayers WS2 placed on various substrates with time-resolved transmittance/reflectance contrast. I report a formalism that allows the reliable comparison of the exciton dynamic response independently of sample, substrate and measurement technique. With this formalism, the pump-photon energy and fluence-dependent exciton peak shift and broadening are extracted and reproduced using a basic two/three-level model. Through this model the competition of quasiparticle dynamic screening, scattering and thermal effects was unravelled. The broadening is governed by QFC-exciton (exciton-exciton) scattering when QFC (excitons) are present in the system. Furthermore, QFC (excitons) induce a global red-(blue-)shift of the exciton resonance, reproduced with an effective QFC (excitons) dynamic screening-induced bandgap renormalization (binding energy reduction). Finally, the static screening influence on the non-equilibrium exciton response is addressed. Scattering and QFC dynamic screening are unaffected in different dielectric environments. On the contrary, the exciton dynamic screening is enhanced for higher substrate permittivity and possibly due to a higher degree of delocalization of the exciton. Ultimately, this thesis contributes to a comprehensive picture of the non-equilibrium dynamics and the role of screening in TMDC
2023- The Twenty-seventh Annual Symposium of Student Scholars
The full program book from the Twenty-seventh Annual Symposium of Student Scholars, held on April 18-21, 2023. Includes abstracts from the presentations and posters.https://digitalcommons.kennesaw.edu/sssprograms/1027/thumbnail.jp
A Review on Modular Converter Topologies Based on WBG Semiconductor Devices in Wind Energy Conversion Systems
This paper presents a comprehensive review on the employment of wide bandgap (WBG) semiconductor power devices in wind energy conversion systems (WECSs). Silicon-carbide- (SiC) and gallium-nitride (GaN)-based power devices are highlighted and studied in this review, focusing on their application in the wind energy system. This is due to their premium characteristics such as the operation at high switching frequency, which can reduce the switching losses, and the capability to operate at high temperatures compared with silicon (Si)-based devices. These advantages promote the replacement of the conventional Si-based devices with the WBG semiconductor devices in the new modular converter topologies due to the persistent demand for a more-efficient power converter topology with lower losses and smaller sizes. The main objective of this paper was to provide a comprehensive overview of the WBG power devices commercially available on the market and employed in the modular converter topologies for renewable energy systems. The paper also provides a comparison between the WBG power technologies and the traditional ones based on the Si devices. The paper starts from the conventional modular power converter topology circuits, and then, it discusses the opportunities for integrating the SiC and WBG devices in the modular power converters to improve and enhance the system’s performance. Keywords: wind energy systems; power electronic converters; wide bandgap devices; modular converters; modular multilevel converters; multicarrier PWM technique
Dynamic Nanophotonic Structures Leveraging Chalcogenide Phase-Change Materials
Chip-scale nanophotonic devices have the potential to enable next-generation imaging, computing, communication, and engineered quantum systems with very stringent performance requirements on size, power, integrability, stability, and bandwidth. The emergence of meta-optic devices with deep subwavelength features has enabled the formation of ultra-thin flat optical structures to replace bulky conventional counterparts in free-space applications. Nevertheless, progress in meta-optics has been slowed due to the passive nature of existing devices and the urgent need for a reliable, fast, low-power, and robust reconfiguration mechanism.
In this research, I devised a new material and device platform to resolve this challenge. Through detailed theoretical design, nanofabrication, and experimental demonstration, I demonstrated the unique features of my proposed platform as an essential building block of truly scalable adaptive flat optics for the active manipulation of optical wavefronts. One of the key attributes of this research is the integration of CMOS-compatible materials for the fabrication of passive devices with phase-change materials that provide the largest known modulation of the index of refraction upon stimulation with an optical or electrical signal. A unique selection of phase-change materials for operation in the near-infrared and visible wavelengths has been made, followed by developing the optimum deposition and fabrication processes for the realization of nanophotonics devices that integrate these functional materials with semiconductor and plasmonic materials. A major breakthrough in this process was the design and realization of integrated electrical stimulation circuitry with far better performance compared to existing solutions.
Using this platform, I experimentally demonstrated the first electrically tunable meta-optic structure for fast optical switching with a high contrast ratio and dynamic wavefront scanning with a large steering angle. This is a major achievement as it essentially allows the engineering of a desired optical wavefront with fast reconfigurability at low power consumption. In an independent work, I demonstrated, for the first time, a nonvolatile meta-optic structure for high-resolution, wide-gamut, and high-contrast microdisplays with added polarization controllability and the possibility of implementation on a flexible substrate. Further features of this metaphotonic display include: 1) full addressability at the microscale pixel via fast electrical pulses; 2) super-resolution pixels with controllable brightness and contrast; and 3) a wide range of colors with high saturation and purity. Lastly, for the first time, I realized a hybrid photonic-plasmonic meta-optic platform with active control over the spatial, spectral, and temporal properties of an optical wavefront. This is a major achievement as it essentially allows the engineering of a desired optical wavefront with fast reconfigurability at low power consumption. These demonstrations are now being pursued in different directions for novel systems for imaging, sensing, computing, and quantum applications, just to name a few.Ph.D
Development of laser sources and interferometric approaches for polarization-based label-free microscopy
The project developed in this thesis describes the design and the experimental realization of optical methods which can probe the anisotropy of semitransparent media. The ability to manipulate polarized light enables a label-free imaging approach that can retrieve fundamental information about the sample structure without introducing any alteration within it. Such a potential is of great importance and methods like the ones based on polarization analysis are gaining more and more popularity in the biomedical and biophysical fields. Moreover, when they are coupled with fluorescence microscopy and nanoscopy, they may provide an invaluable tool for researchers.
The optical method I developed mainly exploits the laser radiation emitted from tailored optical oscillators to dynamically generate polarization states. The realization of such states does not comprise any external active device. The resulting time-evolving polarization state once properly coupled to an optical system enables probing a sample to retrieve its anisotropies at a fast rate.
The development of two different laser sources is presented together with the characterizations of their optical properties. One of them consists of a Helium-Neon laser modified by applying an external magnetic field to trigger the Zeeman effect in its active medium. The other one is a Dual-Comb source, that is a mode-locked (ML) laser generating a pair of mutually coherent twin beams. Moreover, the thesis delivers the theoretical model and the experimental realization of the optical method to probe the optical anisotropies of specimens. Finally, the technical realization of a custom laser scanning optical microscope and its imaging results obtained with such methods are reported
Multi-layer and heterogeneous integrated photonics
Integrated photonic circuits are the optical analog to the ubiquitous electronic integrated circuits that are found in many everyday items. Much like their electronic analog, photonic integrated circuits have enabled the miniaturization of many complex optical systems and result in smaller size, less power consumption, reduced cost, and larger bandwidths. As the field of integrated photonics has matured, the complexity, desired capabilities, and library of material platforms have expanded. This expanded library of materials has allowed certain materials to be used for specific applications based on the strengths of their intrinsic properties. Such an approach inevitably leads to design trade-offs because any complex optical system will require optimal performance in a variety of optical properties.
In this thesis, I will explore heterogeneous design via multi-layer integration using mature integrated photonic material platforms. I will demonstrate that a heterogeneous platform realized through multi-layer integration enables linear and nonlinear performance that cannot be achieved using a single-layer approach through various nonlinear optical demonstrations such as high-speed optical parametric gain, ring resonator enhanced four-wave mixing, and photon-pair generation via spontaneous four-wave mixing. In the second part of this thesis, I will add to the current library of integrated photonic material platforms through the investigation of a new material platform, niobium-tantalum oxide, for integrated photonics. I will demonstrate the utility of this material for linear and nonlinear optical applications and show that it is an ideal material for heterogeneous multi-layer integration
Engineering a Low-Cost Remote Sensing Capability for Deep-Space Applications
Systems engineering (SE) has been a useful tool for providing objective processes to breaking down complex technical problems to simpler tasks, while concurrently generating metrics to provide assurance that the solution is fit-for-purpose. Tailored forms of SE have also been used by cubesat mission designers to assist in reducing risk by providing iterative feedback and key artifacts to provide managers with the evidence to adjust resources and tasking for success. Cubesat-sized spacecraft are being planned, built and in some cases, flown to provide a lower-cost entry point for deep-space exploration. This is particularly important for agencies and countries with lower space exploration budgets, where specific mission objectives can be used to develop tailored payloads within tighter constraints, while also returning useful scientific results or engineering data.
In this work, a tailored SE tradespace approach was used to help determine how a 6 unit (6U) cubesat could be built from commercial-off-the-shelf (COTS)-based components and undertake remote sensing missions near Mars or near-Earth Asteroids. The primary purpose of these missions is to carry a hyperspectral sensor sensitive to 600-800nm wavelengths (hereafter defined as “red-edge”), that will investigate mineralogy characteristics commonly associated with oxidizing and hydrating environments in red-edge. Minerals of this type remain of high interest for indicators of present or past habitability for life, or active geologic processes. Implications of operating in a deep-space environment were considered as part of engineering constraints of the design, including potential reduction of available solar energy, changes in thermal environment and background radiation, and vastly increased communications distances.
The engineering tradespace analysis identified realistic COTS options that could satisfy mission objectives for the 6U cubesat bus while also accommodating a reasonable degree of risk. The exception was the communication subsystem, in which case suitable capability was restricted to one particular option. This analysis was used to support an additional trade investigation into the type of sensors that would be most suitable for building the red-edge hyperspectral payload. This was in part constrained by ensuring not only that readily available COTS sensors were used, but that affordability, particularly during a geopolitical environment that was affecting component supply surety and access to manufacturing facilities, was optimized. It was found that a number of sensor options were available for designing a useful instrument, although the rapid development and life-of-type issues with COTS sensors restricted the ability to obtain useful metrics on their performance in the space environment.
Additional engineering testing was conducted by constructing hyperspectral sensors using sensors popular in science, technology, engineering and mathematics (STEM) contexts. Engineering and performance metrics of the payload containing the sensors was conducted; and performance of these sensors in relevant analogous environments. A selection of materials exhibiting spectral phenomenology in the red-edge portion of the spectrum was used to produce metrics on the performance of the sensors. It was found that low-cost cameras were able to distinguish between most minerals, although they required a wider spectral range to do so. Additionally, while Raspberry Pi cameras have been popular with scientific applications, a low-cost camera without a Bayer filter markedly improved spectral sensitivity. Consideration for space-environment testing was also trialed in additional experiments using high-altitude balloons to reach the near-space environment. The sensor payloads experienced conditions approximating the surface of Mars, and results were compared with Landsat 7, a heritage Earth sensing satellite, using a popular vegetation index. The selected Raspberry Pi cameras were able to provide useful results from near-space that could be compared with space imagery.
Further testing incorporated comparative analysis of custom-built sensors using readily available Raspberry Pi and astronomy cameras, and results from Mastcam and Mastcam/z instruments currently on the surface of Mars. Two sensor designs were trialed in field settings possessing Mars-analogue materials, and a subset of these materials were analysed using a laboratory-grade spectro-radiometer. Results showed the Raspberry Pi multispectral camera would be best suited for broad-scale indications of mineralogy that could be targeted by the pushbroom sensor. This sensor was found to possess a narrower spectral range than the Mastcam and Mastcam/z but was sensitive to a greater number of bands within this range. The pushbroom sensor returned data on spectral phenomenology associated with attributes of Minerals of the type found on Mars. The actual performance of the payload in appropriate conditions was important to provide critical information used to risk reduce future designs. Additionally, the successful outcomes of the trials reduced risk for their application in a deep space environment.
The SE and practical performance testing conducted in this thesis could be developed further to design, build and fly a hyperspectral sensor, sensitive to red-edge wavelengths, on a deep-space cubesat mission. Such a mission could be flown at reasonable cost yet return useful scientific and engineering data
Storing, single photons in broadband vapor cell quantum memories
Single photons are an essential resource for realizing quantum technologies. Together with compatible quantum memories granting control over when a photon arrives, they form a foundational component both of quantum communication and quantum information processing. Quality solid-state single photon sources deliver on the high bandwidths and rates required for scalable quantum technology, but require memories that match these operational parameters. In this thesis, I report on quantum memories based on electromagnetically induced transparency and built in warm rubidium vapor, with such fast and high bandwidth interfaces in mind. I also present work on a heralded single photon source based on parametric downconversion in an optical cavity, operated in a bandwidth regime of a few 100s of megahertz. The systems are characterized on their own and together in a functional interface. As the photon generation process is spontaneous, the memory is implemented as a fully reactive device, capable of storing and retrieving photons in response to an asynchronous external trigger.
The combined system is used to demonstrate the storage and retrieval of single photons in and from the quantum memory. Using polarization selection rules in the Zeeman substructure of the atoms, the read-out noise of the memory is considerably reduced from what is common in ground-state storage schemes in warm vapor. Critically, the quantum signature in the photon number statistics of the retrieved photons is successfully maintained, proving that the emission from the memory is dominated by single photons. We observe a retrieved single-photon state accuracy of for short storage times, which remains throughout the memory lifetime of ns. The end-to-end efficiency of the memory interfaced with the photon source is , which will be further improved in the future by optimizing the operating regime. With its operation bandwidth of MHz, our system opens up new possibilities for single-photon synchronization and local quantum networking experiments at high repetition rates
Liquid Metal Printing with Scanning Probe Lithography for Printed Electronics
In den letzten Jahren hat das „Internet der Dinge“ (Englisch Internet of Things, abgekürzt IoT), das auch als Internet of Everything (Deutsch frei „Internet von Allem“) bezeichnet wird, mit dem Aufkommen der „Industrie 4.0“ einen Strom innovativer und intelligenter sensorgestützter Elektronik der neuen Generation in den Alltag gebracht. Dies erfordert auch die Herstellung einer riesigen Anzahl von elektronischen Bauteilen, einschließlich Sensoren, Aktoren und anderen Komponenten. Gleichzeitig ist die herkömmliche Elektronikfertigung zu einem hochkomplexen und investitionsintensiven Prozess geworden. In dem Maße, wie die Zahl der elektronischen Bauteile und die Nachfrage nach neuen, fortschrittlicheren elektronischen Bauteilen zunimmt, steigt auch die Notwendigkeit, effizientere und nachhaltigere Wege zur Herstellung dieser Bauteile zu finden. Die gedruckte Elektronik ist ein wachsender Markt, der diese Nachfrage befriedigen und die Zukunft der Herstellung von elektronischen Geräten neu gestalten könnte. Sie erlaubt eine einfache und kostengünstige Produktion und ermöglicht die Herstellung von Geräten auf Papier- oder Kunststoffsubstraten. Für die Herstellung gibt es dabei eine Vielzahl von Methoden. Techniken auf der Grundlage der Rastersondenlithografie waren dabei schon immer Teil der gedruckten Elektronik und haben zu Innovationen in diesem Bereich geführt. Obwohl die Technologie noch jung ist und der derzeitige Stand der gedruckten Elektronik im industriellen Maßstab, wie z. B. die Herstellung kompletter integrierter Schaltkreise, stark limitiert ist, sind die potenziellen Anwendungen enorm.
Im Mittelpunkt der Entwicklung gedruckter elektronischer Schaltungen steht der Druck leitfähiger und anderer funktionaler Materialien. Die meisten der derzeit verfügbaren Arbeiten haben sich dabei auf die Verwendung von Tinten auf Nanopartikelbasis konzentriert. Die Herstellungsschritte auf der Grundlage von Tinten auf Nanopartikelbasis sind komplizierte Prozesse, da sie das Ausglühen (Englisch Annealing) und weitere Nachbearbeitungsschritte umfassen, um die gedruckten Muster leitfähig zu machen. Die Verwendung von Gallium-basierten, bei/nahe Raumtemperatur flüssigen Metallen und deren direktes Schreiben für vollständig gedruckte Elektronik ist immer noch ungewöhnlich, da die Kombination aus dem Vorhandensein einer Oxidschicht, hohen Oberflächenspannungen und Viskosität ihre Handhabung erschwert.
Zu diesem Zweck zielt diese Arbeit darauf ab, Methoden zum Drucken von Materialien, einschließlich Flüssigmetallen, zu entwickeln, die mit den verfügbaren Druckmethoden nicht oder nur schwer gedruckt werden können und diese Methoden zur Herstellung vollständig gedruckter elektronischer Bauteile zu verwenden. Weiter werden Lösungen für Probleme während des Druckprozesses untersucht, wie z. B. die Haftung der Tinte auf dem Substrat und andere abscheidungsrelevante Aspekte. Es wird auch versucht, wissenschaftliche Fragen zur Stabilität von gedruckten elektronischen Bauelementen auf Flüssigmetallbasis zu beantworten.
Im Rahmen der vorliegenden Arbeit wurde eine auf Glaskapillaren basierenden Direktschreibmethode für das Drucken von Flüssigmetallen, hier Galinstan, entwickelt. Die Methode wurde auf zwei unterschiedlichen Wegen implementiert: Einmal in einer „Hochleistungsversion“, basierend auf einem angepassten Nanolithographiegerät, aber ebenfalls in einer hochflexiblen, auf Mikromanipulatoren basierenden Version. Dieser Aufbau erlaubt einen on-the-fly („im Fluge“) kapillarbasierten Druck auf einer breiten Palette von Geometrien, wie am Beispiel von vertikalen, vertieften Oberflächen sowie gestapelten 3D-Gerüsten als schwer zugängliche Oberflächen gezeigt wird. Die Arbeit erkundet den potenziellen Einsatz dieser Methode für die Herstellung von vollständig gedruckten durch Flüssigmetall ermöglichten Bauteilen, einschließlich Widerständen, Mikroheizer, p-n-Dioden und Feldeffekttransistoren. Alle diese elektronischen Bauelemente werden ausführlich charakterisiert. Die hergestellten Mikroheizerstrukturen werden für temperaturgeschaltete Mikroventile eingesetzt, um den Flüssigkeitsstrom in einem Mikrokanal zu kontrollieren. Diese Demonstration und die einfache Herstellung zeigt, dass das Konzept auch auf andere Anwendungen, wie z.B. die bedarfsgerechte Herstellung von Mikroheizern für in-situ Rasterelektronenmikroskop-Experimente, ausgeweitet werden kann.
Darüber hinaus zeigt diese Arbeit, wie PMMA-Verkapselung als effektive Barriere gegen Sauerstoff und Feuchtigkeit fungiert und zusätzlich als brauchbarer mechanischer Schutz der auf Flüssigmetall basierenden gedruckten elektronischen Bauteile wirken kann. Insgesamt zeigen der alleinstehende, integrierte Herstellungsablauf und die Funktionalität der Geräte, dass das Potenzial des Flüssigmetall-Drucks in der gedruckten Elektronik viel größer ist als einzig die Verwendung zur Verbindung konventioneller elektronischer Bauteile.
Neben der Entwicklung von Druckverfahren und der Herstellung elektronischer Bauteile befasst sich die Arbeit auch mit der Korrosion und der zusätzlichen Legierung von konventionellen Metallelektroden in Kontakt mit Flüssigmetallen, welche die Stabilität der Bauteil beinträchtigen könnten. Zu diesem Zweck wurde eine korrelierte Materialinteraktionsstudie von gedruckten Galinstan- und Goldelektroden durchgeführt. Durch die kombinierte Anwendung von optischer Mikroskopie, vertikaler Rasterinterferometrie, Rasterelektronenmikroskopie, Röntgenphotonenspektroskopie und Rasterkraftmikroskopie konnte der Ausbreitungsprozess von Flüssigmetalllinien auf Goldfilmen eingehend charakterisiert werden. Diese Studie zeigt eine unterschiedliche Ausbreitung der verschiedenen Komponenten des Flüssigmetalls sowie die Bildung von intermetallischen Nanostrukturen auf der umgebenden Goldfilmoberfläche. Auf der Grundlage der erhaltenen zeitabhängigen, korrelierten Charakterisierungsergebnisse wird ein Modell für den Ausbreitungsprozess vorgeschlagen, das auf dem Eindringen des Flüssigmetalls in den Goldfilm basiert. Um eine ergänzende Perspektive auf die interne Nanostruktur zu erhalten, wurde die Röntgen-Nanotomographie eingesetzt, um die Verteilung von Gold, Galinstan und intermetallischen Phasen in einem in das Flüssigmetall getauchten Golddraht zu untersuchen. Schlussendlich werden Langzeitmessungen des Widerstands an Flüssigmetallleitungen, die Goldelektroden verbinden, durchgeführt, was dazu beiträgt, die Auswirkungen von Materialwechselwirkungen auf elektronische Anwendungen zu bewerten
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