Magic wavelengths for the 6s2 1S0−6s6p 3P1o6s^2\,^1S_0-6s6p\,^3P_1^o transition in ytterbium atom

The static and dynamic electric-dipole polarizabilities of the $6s^2\,^1S_0$ and $6s6p\,^3P_1^o$ states of Yb are calculated by using the relativistic ab initio method. Focusing on the red detuning region to the $6s^2\,^1S_0-6s6p\,^3P_1^o$ transition, we find two magic wavelengths at 1035.7(2) nm and 612.9(2) nm for the $6s^2\,^1S_0-6s6p\,^3P_1^o, M_J=0$ transition and three magic wavelengthes at 1517.68(6) nm, 1036.0(3) nm and 858(12) nm for the $6s^2\,^1S_0-6s6p\,^3P_1^o, M_J=\pm1$ transitions. Such magic wavelengths are of particular interest for attaining the state-insensitive cooling, trapping, and quantum manipulation of neutral Yb atom.Comment: 13 pages, 3 figure

Dynamic polarizabilities and related properties of clock states of ytterbium atom

We carry out relativistic many-body calculations of the static and dynamic dipole polarizabilities of the ground 6s^2 ^1S_0 and the first excited $6s6p ^3P^o_0$ states of Yb. With these polarizabilities, we compute several properties of Yb relevant to optical lattice clocks operating on the 6s^2 ^1S_0 - 6s6p ^3P^o_0 transition. We determine (i) the first four {\em magic} wavelengths of the laser field for which the frequency of the clock transition is insensitive to the laser intensity. While the first magic wavelength is known, we predict the second, the third and the forth magic wavelengths to be 551 nm, 465 nm, and 413 nm. (ii) We reevaluate the effect of black-body radiation on the frequency of the clock transition, the resulting clock shift at $T=300 \mathrm{K}$ being $-1.41(17)$ Hz. (iii) We compute long-range interatomic van der Waals coefficients (in a.u.) C_6(6s^2 ^1S_0 +6s^2 ^1S_0) = 1909(160), C_6(6s^2 ^1S_0 + 6s6p ^3P_0) =2709(338) , and $C_6(6s6p ^3P_0 + 6s6p ^3P_0) =3886(360)$. Finally, we determine the atom-wall interaction coefficients (in a.u.), C_3 (6s^2 ^1S_0) =3.34 and $C_3 (6s6p ^3P_0) =3.68$. We also address and resolve a disagreement between previous calculations of the static polarizability of the ground state.Comment: 11 pages, 1 figur

Breit Interaction and Parity Non-conservation in Many-Electron Atoms

We present accurate {\em ab initio} non-perturbative calculations of the Breit correction to the parity non-conserving (PNC) amplitudes of the $6s-7s$ and $6s-5d_{3/2}$ transitions in Cs, $7s-8s$ and $7s-6d_{3/2}$ transitions in Fr, $6s-5d_{3/2}$ transition in Ba$^+$, $7s-6d_{3/2}$ transition in Ra$^+$, and $6p_{1/2} - 6p_{3/2}$ transition in Tl. The results for the $6s-7s$ transition in Cs and $7s-8s$ transition in Fr are in good agreement with other calculations while calculations for other atoms/transitions are presented for the first time. We demonstrate that higher-orders many-body corrections to the Breit interaction are especially important for the $s-d$ PNC amplitudes. We confirm good agreement of the PNC measurements for cesium and thallium with the standard model .Comment: 9 pages, 1 figur

Tuning the scattering length on the ground triplet state of Cs_2

We develop two schemes for tuning the scattering length on the ground triplet state of Cs_2. First, an absolute value of the triplet scattering length of ^{133}Cs_2 is determined using the experimental data (Fioretti et al, Eur.Phys.J. 5, 389 (1999)). We demonstrate that the large scattering length can be made small and positive by coupling of the ^3\Sigma_u^+ (6S + 6S) potential to the ^3\Pi_g state by strong off-resonant radiation. A weaker laser field coupling the ^3\Sigma_u^+ (6S + 6S) continuum to the lowest bound level of the excited ^3\Sigma_g^+ (6S + 6P) also leads to a small positive scattering length. In addition, the scattering length of the ^{135}Cs isotope is found to be positive. The method used solves the Schroedinger equation for two electronic states coupled by an electromagnetic field with approximations employed. The scattering length is determined from calculated continuum wavefunctions of low energy.Comment: 4 figures, a discussion of influence of the C_6 coeficient on the scattering length of different isotopes is adde

Lifetime Measurement of the 6s Level of Rubidium

We present a lifetime measurements of the 6s level of rubidium. We use a time-correlated single-photon counting technique on two different samples of rubidium atoms. A vapor cell with variable rubidium density and a sample of atoms confined and cooled in a magneto-optical trap. The 5P_{1/2} level serves as the resonant intermediate step for the two step excitation to the 6s level. We detect the decay of the 6s level through the cascade fluorescence of the 5P_{3/2} level at 780 nm. The two samples have different systematic effects, but we obtain consistent results that averaged give a lifetime of 45.57 +- 0.17 ns.Comment: 10 pages, 9 figure

Leptonic and Digamma decay Properties of S-wave quarkonia states

Based on Martin like potential, the S-wave masses of quarkonia have been reviewed. Resultant wave functions at zero inter quark separation are employed to compute the hyperfine splitting of the nS states and the leptonic and digamma decay widths of $n{^3S_1}$ and $n{^1S_0}$ states of quarkonia respectively. Analysis on the level differences of S-wave excited states of quantum mechanical bound systems show a systematic behaviour as n-increases. In view of such systematic behaviour expected for quarkonia, we observe that Y(4263) and X(4630) $1^{--}$ states are closer to the 4S and 6S states while $\psi(4415)$ and Z(4430) are closer to the 5S state of $c\bar{c}$ systems. Similarly we find $\Upsilon (10865)$ is not fit to be the 5S state of $b\bar{b}$ system. while $Y_b (10880)$ observed by Belle or (10996) observed by Babar fit to be the 6S state of bottonia. Our predicted leptonic width, 0.242 keV of $\Upsilon (10579, 4S)$ is in good agreement with the experimental value of 0.272 $\pm$ 0.029 keV. We predict the leptonic widths of the pure 5S and 6S states of upsilon states as 0.191 keV and 0.157 keV respectively. In the case of charmonia, we predict the leptonic widths of the 4S, 5S and 6S states as 0.654 keV, 0.489 keV and 0.387 keV respectively.Comment: 4 pages, 2 figure

Electronic correlations and crystal structure distortions in BaBiO3

BaBiO3 is a material where formally Bi4+ ions with the half-filled 6s-states form the alternating set of Bi3+ and Bi5+ ions resulting in a charge ordered insulator. The charge ordering is accompanied by the breathing distortion of the BiO6 octahedra (extension and contraction of the Bi-O bond lengths). Standard Density Functional Theory (DFT) calculations fail to obtain the crystal structure instability caused by the pure breathing distortions. Combining effects of the breathing distortions and tilting of the BiO6 octahedra allows DFT to reproduce qualitatively experimentally observed insulator with monoclinic crystal structure but gives strongly underestimate breathing distortion parameter and energy gap values. In the present work we reexamine the BaBiO3 problem within the GGA+U method using a Wannier functions basis set for the Bi 6s-band. Due to high oxidation state of bismuth in this material the Bi 6s-symmetry Wannier function is predominantly extended spatially on surrounding oxygen ions and hence differs strongly from a pure atomic 6s-orbital. That is in sharp contrast to transition metal oxides (with exclusion of high oxidation state compounds) where the major part a of d-band Wannier function is concentrated on metal ion and a pure atomic d-orbital can serve as a good approximation. The GGA+U calculation results agree well with experimental data, in particular with experimental crystal structure parameters and energy gap values. Moreover, the GGA+U method allows one to reproduce the crystal structure instability due to the pure breathing distortions without octahedra tilting