A terminal molybdenum carbide prepared by methylidyne deprotonation

The carbide anion [CMo{N(R)Ar}_3]– [R = C(CD_3)_2CH_3, Ar = C_6H_3Me_2-3,5], is obtained by deprotonation of the corresponding methylidyne compound, [HCMo{N(R)Ar}_3], and is characterized by X-ray diffraction as its {K(benzo-15-crown-5)_2}+ salt, thereby providing precedent for the carbon atom as a terminal substituent in transition-metal chemistry

Analysis of the joint kinematics of the 5 iron golf swing

The purpose of this study was to identify the performance determining factors of the 5-iron golf swing. Joint kinematics were obtained from thirty male golfers using a twelve camera motion analysis system. Participants were divided into two groups, based on their ball launch speed (high vs. low). Those in the high ball speed group were deemed to be the more skillful group. Statistical analysis was used to identify the variables which differed significantly between the two groups, and could therefore be classified as the performance determining factors. The following factors were important to performance success: (i) the ability of the golfer to maintain a large X Factor angle and generate large X Factor angular velocity throughout the downswing, (ii) maintain the left arm as straight as possible throughout the swing, (iii) utilise greater movement of the hips in the direction of the target and a greater extension of the right hip during the downswing and (iv) greater flexion of both shoulders and less left shoulder internal rotation during the backswing

Development of Cranberry Girdler, \u3ci\u3eChrysoteuchia Topiaria\u3c/i\u3e (Lepidoptera: Pyraliadae) in Relation to Temperature

The development of Chrysoteuchia topiaria was studied in controlled-temperature chambers. Estimates of the threshold temperatures for the egg, larval, and prepupal-pupal stages were 9.4,6.8, and 9.8°C, respectively. An overall threshold temperature for egg to adult development was estimated to be 8.8°C. Degree-day summations above thresholds averaged 107, 484, and 388 for the egg, larval, and prepupal-pupal stages, respectively

Vermont Food Grade Soybean Performance Trial Results

In 2009, the University of Vermont Extension continued their evaluation of organic food grade soybean varieties at two locations. The purpose of the program was to provide yield comparisons, growth characteristic observations, and bean quality evaluations of food grade soybeans in Vermont’s climate. Performance trials were established as replicated research trials in northern Vermont

The Effect of the Nature of Surfaces on Resistance as Tested on Struts

The chief concern was to measure the variations of resistance brought about by the nature of the surface of the struts. The struts were spanned with aviation linen, and then covered with one coat of varnish. The top surface was not perfectly smooth after this treatment, being slightly rough owing to the threads and raised fibers of the fabric. The results of the measurements of the surfaces are shown by the dotted lines of the curves plotted in several figures. The resistance is given in terms of the characteristic value. Next, the surface was altered by the removal of any roughness on it by means of filing with sandpaper. The measurements of surfaces thus treated gave values represented by extended lines. The increase of resistance with increasing characteristic value, more or less marked in the first series of measurements, was no longer observable. Resistance always decreases with the increase of characteristic value, excepting in the case of strut 7, which shows a slight tendency to rise again. The reasons for this phenomenon have not yet been fully explained

Geostatistical approach for the assessment of the water reservoir capacity in arid regions: a case study of the Akdarya reservoir, Uzbekistan

International audienceThe paper presents the results of a new geostatistical approach to generate bathymetric surface models from point measurement converted into continuous contour surfaces of reservoir bottoms in Uzbekistan. Sedimentation of reservoirs raises engineering, environmental and economical issues for the communities around the world in areas affected by a strong water deficit. Because of Uzbekistan's arid climatic conditions, and uneven spatial and temporal water resources distribution, responsive and innovative water availability assessment surveys of all major water reservoirs are required. Bathymetric surveying is a traditional method that is carried out for the estimation of reservoir volumes and surface areas of the corresponding reservoir stages in order to assess the water availability. Volume and surface area differences derived from multiple surveys of a reservoir provide storage loss estimates over time due to sedimentation. However, two main factors, such as intensive field data measurement and post data-processing, often limit the frequency of these surveys. Alternatively, innovative depth measurement technologies coupled with contouring and surface mapping programs provide automated reservoir volume and surface area calculations. This significantly reduces time, workload and financial burdens for reservoir sedimentation projects. This research proposes the use of geostatistical approach to assess the reservoir sedimentation in the Akdarya reservoir of Uzbekistan. The geostatistical approach includes (semi-) variogram analysis and interpolation (kriging and simulations--turning bands) techniques predicting values at unsampled locations for generating digital bathymetric surface models of reservoir bottom conditions in order to calculate the volume and surface area at a given water elevation. The simulation enables to have range of reservoir volumes and surface areas with the same probability, in comparison to the kriging and traditional methods. This gives a real estimation of the resource availability for water operators to manage natural resources and hydraulic infrastructure in a sustainable manner

Absence of ferroelectricity in BiMnO3 ceramics

We performed factor-group analysis of all phonons in possible monoclinic C2/c and C2 structures of BiMnO3 and compared it with our experimental infrared and Raman spectra. We conclude that the crystal structure is centrosymmetric C2/c in the whole investigated temperature range from 10 to 550 K, therefore BiMnO3 cannot be ferroelectric. We revealed a dielectric relaxation in THz spectra above the structural phase transition taking place at T_C1=475 K giving evidence in strong lattice anharmonicity and a large dynamical disorder of Bi cations above T_C1. Step-like dielectric anomaly observed at T_C1 in THz permittivity reminds antiferroelectric phase transition. Nevertheless, the low-temperature dielectric studies did not reveal any antiferroelectric or ferroelectric hysteresis loop. Our experimental results support theoretical paper of P. Baettig et al. (J. Am. Chem. Soc. 129, 9854 (2007)) claiming that BiMnO3 is not multiferroic, but only antipolar ferromagnet.Comment: accepted to JA

Studying unquenching effects in QCD with Dyson-Schwinger equations

We summarise recent results on the properties of gluons, quarks and light mesons from the Green's functions approach to QCD. We discuss a self-consistent, infrared power law solution for the Schwinger-Dyson equations of the 1PI-Greens functions of Yang-Mills theory. The corresponding running coupling has a universal fixed point at zero momentum. Based on these analytical results a truncation scheme for the coupled system of Schwinger-Dyson equations for the propagators of QCD and the Bethe-Salpeter equation for light mesons has been formulated. We compare numerical results for charge eigenstate vector and pseudoscalar meson observables with corresponding lattice data. The effects of unquenching the system are found to be small but not negligible.Comment: 8 pages, 8 figures. Invited talk given by C.S.F. at the 'Workshop on computational hadron physics', Sept. 13 - 17, Nikosia, Cypru